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1.
Recent progress and applications of thermal lens spectrometry and photothermal beam deflection techniques in environmental sensing
Mladen Franko, Leja Goljat, Mingqiang Liu, Hanna Budasheva, Mojca Žorž, Dorota Korte, 2023, original scientific article

Abstract: This paper presents recent development and applications of thermal lens microscopy (TLM) and beam deflection spectrometry (BDS) for the analysis of water samples and sea ice. Coupling of TLM detection to a microfluidic system for flow injection analysis (µFIA) enables the detection of microcystin-LR in waters with a four samples/min throughput (in triplicate injections) and provides an LOD of 0.08 µg/L which is 12-times lower than the MCL for microcystin-LR in water. µFIA-TLM was also applied for the determination of total Fe and Fe(II) in 3 µL samples of synthetic cloudwater. The LODs were found to be 100 nM for Fe(II) and 70 nM for total Fe. The application of µFIA-TLM for the determination of ammonium in water resulted in an LOD of 2.3 µM for injection of a 5 µL sample and TLM detection in a 100 µm deep microfluidic channel. For the determination of iron species in sea ice, the BDS was coupled to a diffusive gradient in the thin film technique (DGT). The 2D distribution of Fe(II) and total Fe on DGT gels provided by the BDS (LOD of 50 nM) reflected the distribution of Fe species in sea ice put in contact with DGT gels.
Keywords: thermal lens microscopy, beam deflection spectrometry, microfluidic system, microcystin-LR detection, iron species determination, ammonium detection
Published in RUNG: 03.01.2023; Views: 1198; Downloads: 24
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2.
Plastic Waste Precursor-Derived Fluorescent Carbon and Construction of Ternary FCs@CuO@TiO2 Hybrid Photocatalyst for Hydrogen Production and Sensing Application
Akansha Metha, Rayees Ahmad Rather, Blaž Belec, Sandra Gardonio, Ming Fang, Matjaž Valant, 2022, original scientific article

Abstract: A sustainable nexus between renewable energy production and plastic abatement is imperative for overall sustainable development. In this regard, this study aims to develop a cheaper and environmentally friendly nexus between plastic waste management, wastewater treatment, and renewable hydrogen production. Fluorescent carbon (FCs) were synthesized from commonly used LDPE (low-density polyethylene) by a facile hydrothermal approach. Optical absorption study revealed an absorption edge around 300 nm and two emission bands at 430 and 470 nm. The morphological analysis showed two different patterns of FCs, a thin sheet with 2D morphology and elongated particles. The sheet-shaped particles are 0.5 μm in size, while as for elongated structures, the size varies from 0.5 to 1 μm. The as-synthesized FCs were used for the detection of metal ions (reference as Cu2+ ions) in water. The fluorescence intensity of FCs versus Cu2+ ions depicts its upright analytical ability with a limit of detection (LOD) reaching 86.5 nM, which is considerably lesser than earlier reported fluorescence probes derived from waste. After the sensing of Cu2+, the as-obtained FCs@Cu2+ was mixed with TiO2 to form a ternary FCs@CuO@TiO2 composite. This ternary composite was utilized for photocatalytic hydrogen production from water under 1.5 AM solar light irradiation. The H2 evolution rate was found to be ~1800 μmolg−1, which is many folds compared to the bare FCs. Moreover, the optimized FCs@CuO@TiO2 ternary composite showed a photocurrent density of ~2.40 mA/cm2 at 1 V vs. Ag/AgCl, in 1 M Na2SO4 solution under the illumination of simulated solar light. The achieved photocurrent density corresponds to the solar-to-hydrogen (STH) efficiency of ~0.95%. The efficiency is due to the fluorescence nature of FCs and the synergistic effect of CuO embedded in TiO2, which enhances the optical absorption of the composite by reaching the bandgap of 2.44 eV, apparently reducing the recombination rate, which was confirmed by optoelectronic, structural, and spectroscopic characterizations.
Keywords: plastic waste, fluorescent carbo, sensing of metal ions, photocatalytic hydrogen production
Published in RUNG: 25.02.2022; Views: 1529; Downloads: 42
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3.
Method of Regularized Sources for Stokes Flow Problems with Improved Calculation of Velocity Derivatives at the Boundary
Božidar Šarler, wen shiting, li ming, published scientific conference contribution abstract

Abstract: The solution of Stokes flow problems with Dirichlet and Neumann boundary conditions is performed by a non-singular Method of Fundamental Solutions which does not require artificial boundary, i.e. source points of fundamental solution coincide with the collocation points on the boundary. Instead of Dirac delta force, an exponential function, called blob, with a free parameter epsilon is employed, which limits to Dirac delta function when epsilon limits to zero. The solution of the problem is sought as a linear combination of the fields due to the regularized sources that coincide with the boundary and with their intensities chosen in such a way that the solution complies with the boundary conditions. A two-dimensional flow between parallel plates is chosen to assess the properties of the method. The results of the method are accurate except for the derivatives at the boundary. A correction of the method is proposed which can be used to properly assess also the derivatives at the boundary
Keywords: stokes flow, method of regularized sources, meshless method
Published in RUNG: 28.06.2016; Views: 4150; Downloads: 0
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Thermal lens microscopy : characterization and optimization
Mingqiang Liu, Mladen Franko, 2014, published scientific conference contribution

Keywords: mikroskopija, TLS, karakterizacija, optimizacija
Published in RUNG: 16.06.2016; Views: 4649; Downloads: 144
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7.
Thermal Lens Spectrometry: Still a Technique on the Horizon
Mingqiang Liu, Mladen Franko, 2016, published scientific conference contribution

Abstract: In this article the historical development of thermal lens spectrometry (TLS) is briefly reviewed for introduction. In continuation, the emphasis is on the recent progresses of TLS for measurements in ensembled sample cells and in microfluidic flow injection systems. Novel theories, instrumentations and their applications for high sample throughput environmental, chemical and biomedical analysis, particularly in micro space, are presented. Discussions are given on the limitations of present TLS systems, that open new horizons for future progress of this technique, which has already found place among routine techniques for chemical analysis. In the last part, proposals for the future development of TLS toward advanced applications in new research fields are presented.
Keywords: Thermal lens spectrometry, Microfluidic chip, Chemical analysis, Environmental monitoring, Biomedical assay
Published in RUNG: 17.05.2016; Views: 4879; Downloads: 0
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