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ORR stability of Mn–Co/polypyrrole nanocomposite electrocatalysts studied by quasi in-situ identical-location photoelectron microspectroscopy
Maya Kiskinova, Claudio Mele, Hikmet Sezen, Benedetto Bozzini, Mattia Fanetti, Andrea Goldoni, Luca Gregoratti, Belen Aleman, Matteo Amati, Patrizia Bocchetta, 2016, original scientific article

Abstract: The stability of pyrolyzed Mn–Co/polypyrrole (PPy) nanocomposites towards the Oxygen Reduction Reaction (ORR) in alkaline solution, was studied with a close-knit group of complementary microscopic and space-resolved spectroscopic approaches: Atomic Force Microscopy (AFM), Scanning and High-Resolution Transmission Electron Microscopy (SEM, HRTEM) and identical-location Scanning PhotoElectron Microscopy (SPEM). Tracking quasi-in situ the morphochemical evolution of the Mn–Co/PPy catalyst upon electrochemical aging under ORR conditions by this multi-technique approach, has allowed to clarify the key physico-chemical processes underlying the dramatic impact of Co additions to stability improvement.
Found in: ključnih besedah
Keywords: Mixed manganese oxides, Polypyrrole, Oxygen reduction, Electrocatalysis, Nanocomposites, X-ray photoelectron microspectroscopy
Published: 25.07.2016; Views: 2118; Downloads: 0
.pdf Fulltext (1,36 MB)

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