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1.
SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY
Jacopo Segato, 2016, master's thesis

Abstract: The thesis describes the synthesis of novel yttrium(III), europium(III) and ytterbium(III) complexes with polydentate ligands containing the ferrocenyl moiety. In particular, a chelating beta-diketonate ligand having formula [FcCOCHCOCH3]- has been used for the preparation of homo- and heteroleptic complexes, these last having N-donor ligands such as 1,10-phenanthroline or tris(3,5-dimethylpyrazol-1-yl)borate in their coordination sphere. Further complexes were obtained by reacting bis(diphenylphosphino)ferrocene dioxide with proper Group 3 and lanthanide precursors, having nitromalonaldehyde or bromomalonaldehyde as supporting ligands. In all the cases, the characterizations were corroborated by electrochemical measurements and diffusion spectroscopy. Reversible or quasi-reversible one-electron oxidation of the ferrocenyl moiety was detected for the new complexes, even if the corresponding ferricinium-based compounds resulted quite strong oxidants.
Found in: ključnih besedah
Keywords: lanthanides, ferrocene, heteropolymetallic complexes, beta-diketonate, cyclovoltammetry
Published: 16.12.2016; Views: 4262; Downloads: 314
.pdf Fulltext (4,17 MB)

2.
Topological properties and self-energy effects in elemental Yb
L. Petaccia, D. Ceresoli, S. Iacobucci, A. Ruocco, Giovanni Stefani, Luka Novinec, M. I. Trioni, Sandra Gardonio, F. Offi, P. M. Sheverdyaeva, 2021, original scientific article

Found in: ključnih besedah
Summary of found: ...electronic structure, topological materials, lanthanides, angle-resolved photoemission spectroscopy...
Keywords: electronic structure, topological materials, lanthanides, angle-resolved photoemission spectroscopy
Published: 03.12.2021; Views: 447; Downloads: 11
.pdf Fulltext (1,94 MB)
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