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21.
22.
Taming the topology of calix[4]arene-based 2D-covalent organic frameworks : interpenetrated vs noninterpenetrated frameworks and their selective removal of cationic dyes
Bikash Garai, Dinesh Shetty, Tina Škorjanc, Felipe Gándara, Nawavi Naleem, Sabu Varghese, Sudhir Kumar Sharma, Maria Baias, Ramesh Jagannathan, Mark Anthony Olson, 2021, original scientific article

Abstract: A bowl-shaped calix[4]arene with its exciting host–guest chemistry is a versatile supramolecular building block for the synthesis of distinct coordination cages or metal–organic frameworks. However, its utility in the synthesis of crystalline covalent organic frameworks (COFs) remains challenging, presumably due to its conformational flexibility. Here, we report the synthesis of a periodic 2D extended organic network of calix[4]arenes joined by a linear benzidine linker via dynamic imine bonds. By tuning the interaction among neighboring calixarene units through varying the concentration in the reaction mixture, we show the selective formation of interpenetrated (CX4-BD-1) and non-interpenetrated (CX4-BD-2) frameworks. The cone-shaped calixarene moiety in the structural backbone allows for the interweaving of two neighboring layers in CX4-BD-1, making it a unique example of interpenetrated 2D layers. Due to the high negative surface charge from calixarene units, both COFs have shown high performance in charge-selective dye removal and an exceptional selectivity for cationic dyes irrespective of their molecular size. The charge distribution of the COFs and the resulting selectivity for the cationic dyes were further investigated using computational methods.
Keywords: dyes and pigments, covalent organic frameworks, adsorption, layers, chemical structure
Published in RUNG: 16.03.2021; Views: 2186; Downloads: 0
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23.
24.
Structural basis of human PCNA sliding on DNA
Matteo De March, Nekane Merino, Susana Barrera-Vilarmau, Ramon Crehuet, Silvia Onesti, Francisco J. Blanco-Silva, Alfredo De Biasio, 2017, original scientific article

Keywords: structure, sliding, PCNA
Published in RUNG: 03.03.2021; Views: 1949; Downloads: 15
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25.
26.
The dark side of the ring: role of the DNA sliding surface of PCNA
Matteo De March, Alfredo De Biasio, 2017, original scientific article

Keywords: diffucio, PCNA, structure, biology, replication
Published in RUNG: 03.03.2021; Views: 2008; Downloads: 0
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27.
Reply to: "Does PCNA diffusion on DNA follow a rotation-coupled translation mechanism?"
Matteo De March, Silvia Onesti, Alfredo De Biasio, 2020, review article

Keywords: PCNA, replication, diffusion, structure
Published in RUNG: 01.03.2021; Views: 2018; Downloads: 38
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29.
In-situ Fe K-edge XAS analysis of ionic species in the highly-concentrated FeCl2 aqueous solutions for Power-to-Solid energy storage technology
Uroš Luin, Iztok Arčon, Matjaž Valant, unpublished conference contribution

Keywords: In situ Fe K-edge XAS, highly-concentrated FeCl2 aqueous solutions, local structure, coordination number, Power-to-Solid, energy storage technology
Published in RUNG: 28.01.2021; Views: 2745; Downloads: 66  (1 vote)
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30.
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