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Ključne besede: analitska kemija, kemijska analiza, instrumentacija, matematične metode, ravnotežje, fizika, kemijska tehnologija, materiali, ekološke znanosti, aplikacije, raziskave
Objavljeno v RUNG: 28.02.2022; Ogledov: 1917; Prenosov: 0
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Ključne besede: EAM DEFLECTION SPECTROMETRY, BIOCOMPOSITE MATERIALS, porosity
Objavljeno v RUNG: 02.12.2021; Ogledov: 1842; Prenosov: 0
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Opis: Sea-ice borne iron has been found to be an important factor controlling Southern Ocean phytoplankton growth [1]. Knowing the amount and chemical speciation of its labile fraction in sea ice would advance our understanding of the involved processes. Unfortunately, it is rather difficult to perform their measurement because of limited access to the Antarctic. Thus there is a strong need for the development of a quick, simple and reliable technique for determination of iron and its speciation in sea-ice that ensures also low enough limits of detection. Recently, diffusive gradients in thin films (DGT) have been widely used as passive samplers for collecting time-averaged data on the concentrations of transition metals in different media [2]. DGTs are further coupled to an analytical technique that in case of detecting metals in passive sampler films primarily requires their extraction [3], which may potentially lead to changes of the metal specification. In the present study, the beam deflection spectrometry (BDS) is coupled to DGT and used to determine the average concentration of iron in the sea ice samples collected at the Davis Station in the Antarctic. Such a combined technique has been already successfully applied for detecting labile iron species in freshwater sediments [4]. The obtained BDS data were validated by thermal lens spectrometry (TLS) and UV-Vis spectrophotometry (SPEC). The distribution of iron species over a given ice surface area using the DGT-BDS technique revealed total iron concentrations in the range of 0.6 – 5.3 μgL-1, whereas the Fe2+ content was found to be in the range of 0.1 – 1.5 μgL-1. The range taking into account all of the measurement points (5×4), the precision of a single measured point is 0.2 μgL-1. The calculated 24 h-average concentration of total Fe labile species in the ice by using BDS is 2.3 ± 0.5 μgL-1, which coincides with data obtained by SPEC (2.5 ± 0.4 μgL-1) and TLS (2.39 ± 0.02 μgL-1). Our results indicate that it is possible to develop a robust, contamination-resilient detection method for measuring the labile iron species concentration in the sea ice. In opposite to TLS and SPEC, BDS-DGT provides reliable information not only about the speciation of iron but also about their distribution on the ice surface.
Ključne besede: beam deflection spectrometry, diffusive gradients, thin films, iron species, photothermal techniques, Antarctic sea ice
Objavljeno v RUNG: 30.11.2021; Ogledov: 2269; Prenosov: 0
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Ključne besede: photocatalysts, TiO2, Cu/Zr, photodegradation, material characterization, photothermal spectrometry
Objavljeno v RUNG: 23.11.2021; Ogledov: 1716; Prenosov: 96
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Opis: Pseudopartitive constructions are constructions of the form DP-of-NP, where the quantificational, collective or container DP head is interpreted as measuring the embedded NP. A verb can agree either with the head (Head Agreement) or with the embedded NP (Embedded Agreement). We argue that agreement alternations with pseudopartitives form part of lin- guistic competence. Specifically, we account for them in terms of a dual la- belling option open to of -DP/NP constituents, as either PPs (of projecting) or as NPs (of not projecting). Thus, we reject the conclusion that pseudopar- titives are to be accounted for in processing terms, and wholly subsumed un- der agreement attraction. In two studies, we investigate subject-verb num- ber agreement (Study 1, N = 103) and gender agreement (Study 2, N = 87), in an acceptability task with pseudopartitive constructions involving either a collective noun or an approximate quantifier, controlling for the nature of the head. Results show that Italian pseudopartitives allows embedded agree- ment, depending on the speaker and on the nature of the head (quantifiers better than collective Ns).
Ključne besede: pseudopartitives, agreement, number, gender, agreement at- traction
Objavljeno v RUNG: 17.09.2021; Ogledov: 1618; Prenosov: 0
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