11. THERMOCHEMICAL CONVERSION OF MARINE LITTER INTO FUELS AND CHEMICALSGian Claudio Paolo Faussone, 2023, doktorska disertacija Opis: Plastic waste is steadily polluting oceans and environments. Even when collected, it is still predominantly dumped or incinerated for energy recovery at the cost of CO2. However, no simple solution exists to deal with marine litter (ML). Overcoming limitations in collection, and in the environmentally, technically and economically acceptable use of the collected material, is of paramount importance. Chemical recycling can contribute to the transition towards a circular economy but the high variety and contamination of real waste remains the biggest challenge. In my research more than 100 kg of actual benthic ML from the North Adriatic Sea, including polyolefins packaging and polyamides fishing nets, were successfully processed “as-is” without pretreatment and converted into standardized marine gas oil (MGO) compliant with the ISO8217 via the pyrolysis and the distillation process; with 8 potential harmful emissions linked to the pyrolysis process monitored and curbed to safe levels. Approximately 45 wt% yield of raw pyrolysis oil (RPO) was obtained of which 50% (v/v) being MGO. RPO and its distillates were chemically characterized via GC-MS. For all samples, more than 30% of the detected compounds were identified. 2,4-dimethyl-1-heptene, a marker of PP pyrolysis, is the most represented peak in the chemical signature of all the marine litter samples, and it differentiates commercial and pyrolysis marine gasoil. Besides, I studied the detailed composition and the steam cracking performance of distilled pyrolysis oil fractions in the naphtha-range of ML and mixed municipal plastic waste (MPW) considered unsuitable for mechanical recycling. Advanced analytical techniques including comprehensive two-dimensional gas chromatography (GC × GC) coupled with various detectors and inductively coupled plasma – mass spectrometry (ICP-MS) was applied to characterize the feedstocks and to understand how their properties affect the steam cracking performance. Both waste-derived naphtha fractions were rich in olefins and aromatics (~70% in MPW naphtha and ~51% in ML naphtha) next to traces of nitrogen, oxygen, chlorine and metals. ICP-MS analyses showed that sodium, potassium, silicon and iron were the most crucial metals that should be removed in further upgrading steps. Steam cracking of the waste-derived naphtha fractions resulted in lower light olefin yields compared to fossil naphtha used as benchmark, due to secondary reactions of aromatics and olefins. Coke formation of ML naphtha was slightly increased compared to fossil naphtha (~50%), while that of MPW naphtha was more than ~180% higher. It was concluded that mild upgrading of the waste-derived naphtha fractions or dilution with fossil feedstocks is sufficient to provide feedstocks suitable for industrial steam cracking. Waste plastics oil (WPO) obtained from a relatively large-scale batch rotary kiln pyrolysis reactor was collected and stored for 60 months in dark at 10 °C, periodically thoroughly characterized and finally tested as the drop-in fuel in internal combustion engine. It was evaluated by investigation of combustion process and emission formation phenomena under a wide range of operating parameters. The results were compared with those obtained with diesel fuel at the same injection and gas path parameters to provide a comprehensive basis for further development of control strategies. Finally, the solid residue from the pyrolysis process was evaluated for material recovery or safe disposal, thus closing the mass balance of the whole process. Due to the great contamination of the original feedstock, stabilization of solid residue is required to attain not hazardous waste criteria, but once stabilized with Portland concrete, it could even be employed as construction material, therefore transforming a problem into an opportunity.
Ključne besede: marine litter, marine fuel, pyrolysis, circular economy, environmental impact, chemical recycling, steam-cracking, pyrolysis char
Objavljeno v RUNG: 12.05.2023; Ogledov: 2293; Prenosov: 33
 Celotno besedilo (14,33 MB) |
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13. Observation of the Cumbre Vieja volcano plume above the Observatorio del Roque de los Muchachos with the Barcelona Raman LIDARMiha Živec, Otger Ballester, Oscar Blanch, Juan Boix, Paolo G. Calisse, Anna Campoy Ordaz, Michele Doro, Lluis Font, Rafael Garcia, Markus Gaug, Roger Grau, Manel Martinez, David Roman, Samo Stanič, Santiago Ubach Ramírez, Marko Zavrtanik, 2022, objavljeni znanstveni prispevek na konferenci Ključne besede: lidar, remote sensing, CTA, CTAO, Cumbre Vieja, atmospheric monitoring, volcano
Objavljeno v RUNG: 13.02.2023; Ogledov: 1643; Prenosov: 18
Celotno besedilo (3,49 MB) |
14. Dark matter search in dwarf irregular galaxies with the Fermi Large Area TelescopeViviana Gammaldi, Judit Pérez Romero, Javier Coronado-Blázquez, Mattia di Mauro, Ekaterina Karukes, Miguel Sánchez-Conde, Paolo Salucci, 2021, izvirni znanstveni članek Opis: We analyze 11 years of Fermi-Large Area Telescope (LAT) data corresponding to the sky regions of seven dwarf irregular (dIrr) galaxies. DIrrs are dark matter (DM)-dominated systems, proposed as interesting targets for the indirect search of DM with gamma rays. The galaxies represent interesting cases with a strong disagreement between the density profiles (core versus cusp) inferred from observations and numerical simulations. In this work, we addressed the problem by considering two different DM profiles, based on both the fit to the rotation curve (in this case, a Burkert cored profile) and results from N-body cosmological simulations (i.e., Navarro-Frenk-White cuspy profile). We also include halo substructure in our analysis, which is expected to boost the DM signal by a factor of 10 in halos such as those of dIrrs. For each DM model and dIrr, we create a spatial template of the expected DM-induced gamma-ray signal to be used in the analysis of Fermi-LAT data. No significant emission is detected from any of the targets in our sample. Thus, we compute upper limits on the DM annihilation cross section versus mass parameter space.
Among the seven dIrrs, we find IC10 and NGC6822 to yield the most stringent individual constraints, independently of the adopted DM profile. We also produce combined DM limits for all objects in the sample, which turn out to be dominated by IC10 for all DM models and annihilation channels, i.e., b¯b, τ+τ−, and W+W−. The strongest constraints are obtained for b¯b and are at the level of <σv>∼7×10−26 cm3 s−1 at mχ ∼ 6 GeV. Though these limits are a factor of ∼3 higher than the thermal relic cross section at low weakly interacting massive particles masses, they are independent from and complementary to those obtained by means of other targets.
Ključne besede: Dark matter, gamma-ray astronomy, galaxies, astronomical masses and mass distributions
Objavljeno v RUNG: 26.01.2023; Ogledov: 1544; Prenosov: 0
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15. On the cost of scalar implicatures : an eye-tracking studyGreta Mazzaggio, Anne Colette Reboul, Jean-Baptiste van der Henst, Anne Cheylus, Paolo Lorusso, Penka Stateva, 2022, objavljeni povzetek znanstvenega prispevka na konferenci Ključne besede: scalar implicatures, experimental pragamtics, eye-tracker, quantifiers
Objavljeno v RUNG: 08.08.2022; Ogledov: 1787; Prenosov: 25
 Povezava na celotno besedilo
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16. High spatial heterogeneity of water stress levels in Refošk grapevines cultivated in Classical KarstFrancesco Petruzzellis, Sara Natale, Luca Bariviera, Alberto Calderan, Alenka Mihelčič, Jan Reščič, Paolo Sivilotti, Katja Šuklje, Klemen Lisjak, Andreja Vanzo, Andrea Nardini, 2022, izvirni znanstveni članek Ključne besede: Classical Karst, water status, drought stress, grape quality, phenolic profile, vitis vinifera
Objavljeno v RUNG: 11.11.2021; Ogledov: 2733; Prenosov: 0
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17. FR-0 jetted active galaxies : extending the zoo of candidate sites for UHECR accelerationLukas Merten, Margot Boughelilba, Anita Reimer, Paolo Da Vela, Serguei Vorobiov, Fabrizio Tavecchio, Giacomo Bonnoli, Jon Paul Lundquist, Chiara Righi, 2021, objavljeni znanstveni prispevek na konferenci Opis: Fanaroff-Riley (FR) 0 radio galaxies form a low-luminosity extension to the well-established ultra-high-energy cosmic-ray (UHECR) candidate accelerators FR-1 and FR-2 galaxies. Their much higher number density — up to a factor five times more numerous than FR-1 with z ≤ 0.05 — makes them good candidate sources for an isotropic contribution to the observed UHECR flux.
Here, the acceleration and survival of UHECR in prevailing conditions of the FR-0 environment are discussed.
First, an average spectral energy distribution (SED) is compiled based on the FR0CAT. These photon fields, composed of a jet and a host galaxy component, form a minimal target photon field for the UHECR, which will suffer from electromagnetic pair production, photo-disintegration, photo-meson production losses, and synchrotron radiation. The two most promising acceleration scenarios based on Fermi-I order and gradual shear acceleration are discussed as well as different
escape scenarios.
When an efficient acceleration mechanism precedes gradual shear acceleration, e.g., Fermi-I orothers, FR-0 galaxies are likely UHECR accelerators. Gradual shear acceleration requires a jet
Lorentz factor of Gamma>1.6, to be faster than the corresponding escape. In less optimistic models, a contribution to the cosmic-ray flux between the knee and ankle is expected to be relatively independent of the realized turbulence and acceleration.
Ključne besede: jetted active galaxies, FR-0 radiogalaxies, ultra-high energy cosmic rays, cosmic ray acceleration, cosmic ray energy losses
Objavljeno v RUNG: 16.08.2021; Ogledov: 2622; Prenosov: 5
Celotno besedilo (1,13 MB) |
18. Extrapolating FR-0 radio galaxy source properties from propagation of multi-messenger ultra-high energy cosmic raysJon Paul Lundquist, Lukas Merten, Serguei Vorobiov, Margot Boughelilba, Anita Reimer, Paolo Da Vela, Fabrizio Tavecchio, Giacomo Bonnoli, Chiara Righi, 2021, objavljeni znanstveni prispevek na konferenci Opis: Recently, it has been shown that relatively low luminosity Fanaroff-Riley type 0 (FR-0) radio galaxies are a good candidate source class for a predominant fraction of cosmic rays (CR) accelerated to ultra-high energies (UHE, E>10[sup]18 eV). FR-0s can potentially provide a significant fraction
of the UHECR energy density as they are much more numerous in the local universe than more energetic radio galaxies such as FR-1s or FR-2s (up to a factor of ∼5 with z≤0.05 compared to
FR-1s).
In the present work, UHECR mass composition and energy spectra at the FR-0 sources are estimated by fitting simulation results to the published Pierre Auger Observatory data. This fitting is done using a simulated isotropic sky distribution extrapolated from the measured FR-0 galaxy properties and propagating CRs in plausible extragalactic magnetic field configurations using the CRPropa3 framework. In addition, we present estimates of the fluxes of secondary photons and neutrinos created in UHECR interactions with cosmic photon backgrounds during
CR propagation. With this approach, we aim to investigate the properties of the sources with the help of observational multi-messenger data.
Ključne besede: jetted active galaxies, FR-0 radiogalaxies, ultra-high energy cosmic rays, extragalactic magnetic fields, UHECR propagation, UHECR interactions, cosmogenic photons, cosmogenic neutrinos
Objavljeno v RUNG: 16.08.2021; Ogledov: 2510; Prenosov: 5
Celotno besedilo (2,04 MB) |
19. Determination of Aethalometer multiple-scattering enhancement parameters and impact on source apportionment during the winter 2017/18 EMEP/ACTRIS/COLOSSAL campaign in MilanVera Bernardoni, Luca Ferrero, Ezio Bolzacchini, Alice Corina Forello, Asta Gregorič, Dario Massabo, Griša Močnik, Paolo Prati, Martin Rigler, Luca Santagostini, 2021, izvirni znanstveni članek Opis: In the frame of the EMEP/ACTRIS/COLOSSAL campaign in Milan during winter 2018, equivalent black carbon measurements using the Aethalometer 31 (AE31), the Aethalometer 33 (AE33), and a Multi-Angle Absorption Photometer (MAAP) were carried out together with levoglucosan analyses on 12 h resolved PM2.5 samples collected in parallel.
From AE31 and AE33 data, the loading-corrected aerosol attenuation coefficients (bATN) were calculated at seven wavelengths (λ, where λ values are 370, 470, 520, 590, 660, 880, and 950 nm). The aerosol absorption coefficient at 637 nm (babs_MAAP) was determined by MAAP measurements. Furthermore, babs was also measured at four wavelengths (405, 532, 635, 780 nm) on the 12 h resolved PM2.5 samples by a polar photometer (PP_UniMI).
After comparing PP_UniMI and MAAP results, we exploited PP_UniMI data to evaluate the filter multiple-scattering enhancement parameter at different wavelengths for AE31 and AE33. We obtained instrument- and wavelength-dependent multiple-scattering enhancement parameters by linear regression of the Aethalometer bATN against the babs measured by PP_UniMI. We found significant dependence of the multiple-scattering enhancement parameter on filter material, hence on the instrument, with a difference of up to 30 % between the AE31 and the AE33 tapes. The wavelength dependence and day–night variations were small – the difference between the smallest and largest value was up to 6 %.
Data from the different instruments were used as input to the so-called “Aethalometer model” for optical source apportionment, and instrument dependence of the results was investigated. Inconsistencies among the source apportionment were found fixing the AE31 and AE33 multiple-scattering enhancement parameters to their usual values. In contrast, optimised multiple-scattering enhancement parameters led to a 5 % agreement among the approaches.
Also, the component apportionment “MWAA model” (Multi-Wavelength Absorption Analyzer model) was applied to the dataset. It was less sensitive to the instrument and the number of wavelengths, whereas significant differences in the determination of the absorption Ångström exponent for brown carbon were found (up to 22 %).
Ključne besede: black carbon, filter photometer, Aethalometer, source apportionment
Objavljeno v RUNG: 16.04.2021; Ogledov: 2844; Prenosov: 0
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20. The impact of cloudiness and cloud type on the atmospheric heating rate of black and brown carbon in the Po ValleyLuca Ferrero, Asta Gregorič, Griša Močnik, Martin Rigler, Sergio Cogliati, Francesca Barnaba, Luca Di Liberto, Gian Paolo Gobbi, Niccolò Losi, Ezio Bolzacchini, 2021, izvirni znanstveni članek Opis: We experimentally quantified the impact of cloud fraction and cloud type on the heating rate (HR) of black and brown carbon (HRBC and HRBrC). In particular, we examined in more detail the cloud effect on the HR detected in a previous study (Ferrero et al., 2018). High-time-resolution measurements of the aerosol absorption coefficient at multiple wavelengths were coupled with spectral measurements of the direct, diffuse and surface reflected irradiance and with lidar–ceilometer data during a field campaign in Milan, Po Valley (Italy). The experimental set-up allowed for a direct determination of the total HR (and its speciation: HRBC and HRBrC) in all-sky conditions (from clear-sky conditions to cloudy). The highest total HR values were found in the middle of winter (1.43 ± 0.05 K d−1), and the lowest were in spring (0.54 ± 0.02 K d−1). Overall, the HRBrC accounted for 13.7 ± 0.2 % of the total HR, with the BrC being characterized by an absorption Ångström exponent (AAE) of 3.49 ± 0.01. To investigate the role of clouds, sky conditions were classified in terms of cloudiness (fraction of the sky covered by clouds: oktas) and cloud type (stratus, St; cumulus, Cu; stratocumulus, Sc; altostratus, As; altocumulus, Ac; cirrus, Ci; and cirrocumulus–cirrostratus, Cc–Cs). During the campaign, clear-sky conditions were present 23 % of the time, with the remaining time (77 %) being characterized by cloudy conditions. The average cloudiness was 3.58 ± 0.04 oktas (highest in February at 4.56 ± 0.07 oktas and lowest in November at 2.91 ± 0.06 oktas). St clouds were mostly responsible for overcast conditions (7–8 oktas, frequency of 87 % and 96 %); Sc clouds dominated the intermediate cloudiness conditions (5–6 oktas, frequency of 47 % and 66 %); and the transition from Cc–Cs to Sc determined moderate cloudiness (3–4 oktas); finally, low cloudiness (1–2 oktas) was mostly dominated by Ci and Cu (frequency of 59 % and 40 %, respectively).
HR measurements showed a constant decrease with increasing cloudiness of the atmosphere, enabling us to quantify for the first time the bias (in %) of the aerosol HR introduced by the simplified assumption of clear-sky conditions in radiative-transfer model calculations. Our results showed that the HR of light-absorbing aerosol was ∼ 20 %–30 % lower in low cloudiness (1–2 oktas) and up to 80 % lower in completely overcast conditions (i.e. 7–8 oktas) compared to clear-sky ones. This means that, in the simplified assumption of clear-sky conditions, the HR of light-absorbing aerosol can be largely overestimated (by 50 % in low cloudiness, 1–2 oktas, and up to 500 % in completely overcast conditions, 7–8 oktas).
The impact of different cloud types on the HR was also investigated. Cirrus clouds were found to have a modest impact, decreasing the HRBC and HRBrC by −5 % at most. Cumulus clouds decreased the HRBC and HRBrC by −31 ± 12 % and −26 ± 7 %, respectively; cirrocumulus–cirrostratus clouds decreased the HRBC and HRBrC by −60 ± 8 % and −54 ± 4 %, which was comparable to the impact of altocumulus (−60 ± 6 % and −46 ± 4 %). A higher impact on the HRBC and HRBrC suppression was found for stratocumulus (−63 ± 6 % and −58 ± 4 %, respectively) and altostratus (−78 ± 5 % and −73 ± 4 %, respectively). The highest impact was associated with stratus, suppressing the HRBC and HRBrC by −85 ± 5 % and −83 ± 3 %, respectively. The presence of clouds caused a decrease of both the HRBC and HRBrC (normalized to the absorption coefficient of the respective species) of −11.8 ± 1.2 % and −12.6 ± 1.4 % per okta. This study highlights the need to take into account the role of both cloudiness and different cloud types when estimating the HR caused by both BC and BrC and in turn decrease the uncertainties associated with the quantification of their impact on the climate.
Ključne besede: black carbon, brown carbon, cloud, atmospheric heating rate, climate change
Objavljeno v RUNG: 29.03.2021; Ogledov: 2982; Prenosov: 0
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