1. International Conference on Functional Nanomaterials and NanodevicesPolina Mladenova, Dominik Eder, Saim Emin, 2018, druge monografije in druga zaključena dela Najdeno v: ključnih besedah
Povzetek najdenega: ...energy conversion, catalysis, nanomaterials, nanobiotechnologies...
Ključne besede: energy conversion, catalysis, nanomaterials, nanobiotechnologies
Objavljeno: 17.09.2018; Ogledov: 1194; Prenosov: 0
 Polno besedilo (3,62 MB) |
2. Alternative Recovery and Valorization of Metals from Exhausted Catalytic Converters in a New Smart Polymetallic CatalystOreste Piccolo, Laura Sperni, Michele Gallo, Katarina Vogel-Mikuš, Iztok Arčon, Franco Baldi, Sebastiano Tieuli, Stefano Paganelli, 2019, izvirni znanstveni članek Opis: A new metals-polymeric composite, Metx-EPS (I), was prepared
to be used as catalyst in water or in two-phase aqueous
conditions. The metals source was an exhausted catalytic
converter that was grinded and treated with an acidic solution at room temperature. After filtration, the solution was concentrated, neutralized and added to a broth of Klebsiella oxytoca DSM 29614 to produce (I) where metals are embedded in a peculiar polysaccharide structure (EPS). The composite was easily recovered from the fermentation broth and purified. The process protocol was verified many times and was shown to be reproducible satisfactorily. The % recovery of metals, originally present in the converter, was good as determined by atomic
absorption. The morphology and the chemical state of main
metals in (I) were investigated by X-ray absorption spectroscopy
methods (XANES and EXAFS). No metallic alloy seems to
be evident. The catalytic activity and a possible synergic effect due to the presence of the different metals was valuated in the hydrogenation of some substrates, valuable precursors for theproduction of fine chemicals.
Najdeno v: ključnih besedah
Povzetek najdenega: ...Biogenerated polymetallic exopolysaccharide,
biphasic catalysis, hydrogenation, metals-polymeric
composite, new catalyst from metallic wastes,...
Ključne besede: Biogenerated polymetallic exopolysaccharide, biphasic catalysis, hydrogenation, metals-polymeric
composite, new catalyst from metallic wastes, EXAFS, XANES
Objavljeno: 06.05.2019; Ogledov: 742; Prenosov: 0
Polno besedilo (2,87 MB) |
3. Synthesis of a Cu/ZnO Nanocomposite by Electroless Plating for the Catalytic Conversion of CO2 to MethanolMaja Pori, Iztok Arčon, Marjan Marinšek, Goran Dražić, Blaž Likozar, Zorica Crnjak Orel, Damjan Lašič Jurković, 2019, izvirni znanstveni članek Opis: The process of methanol synthesis based on the hydrogenation of CO2
was investigated over binary Cu/ZnO catalyst materials,
prepared by applying a novel electroless plating fabrication method. The activity of the produced catalytic samples
was determined at temperature range between 200 and 300 °C and the feedstock conversion data were supplemented with
a detailed microstructure analysis using high-resolution transmission electron microscopy (HRTEM), X-ray powder diffraction
(XRD) and Cu and Zn K-edge, X-ray absorption near-edge structure (XANES) measurements and extended X-ray
absorption fine-structure (EXAFS) measurements. It was confirmed that the disorder in the Cu crystallites created unique
geometrical situations, which acted as the additional reactive centres for the adsorption of the reactant molecule species.
Copper and zinc structural synergy (spill-over) was also demonstrated as being crucial for the carbon dioxide’s activation.
EXAFS and XANES results provide strong evidence for surface alloying between copper and zinc and thus the present results
demonstrate new approach applicable for explaining metal–support interactions.
Najdeno v: ključnih besedah
Ključne besede: EXAFS, CuZn alloy, Spillover mechanism, CO2 valorization, Electroless deposition method, Heterogeneous
catalysis
Objavljeno: 12.04.2019; Ogledov: 1010; Prenosov: 0
Polno besedilo (1,92 MB) |
