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2. Determination of iron in natural waters using DGT technique coupled to phototermal beam deflection spectroscopyHanna Budasheva, Arne Bratkič, Dorota Korte, Mladen Franko, 2018, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Povzetek najdenega: ...deflection spectroscopy, diffusive gradients in thin-films, iron species, photothermal techniques, natural waters....
Ključne besede: Beam deflection spectroscopy, diffusive gradients in thin-films, iron species, photothermal techniques, natural waters.
Objavljeno: 09.11.2018; Ogledov: 819; Prenosov: 0
 Polno besedilo (40,53 KB) |
3. Optimization of DGT technique for determination of iron species in natural water and sediments by photothermal beam deflection spectroscopyMladen Franko, Dorota Korte, Arne Bratkič, Hanna Budasheva, 2018, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Ključne besede: beam deflection spectroscopy, diffusive gradients in thin-film technique, iron redox species, photothermal techniques, natural water, sediments
Objavljeno: 23.11.2018; Ogledov: 890; Prenosov: 0
Polno besedilo (386,02 KB) |
4. Determination of Dissolved Iron Redox Species in Freshwater Sediment using DGT Technique Coupled to BDSYue Gao, Arne Bratkič, Dorota Korte, Aleksander Kravos, Hanna Budasheva, Mladen Franko, 2019, izvirni znanstveni članek Opis: In this work we have developed a novel method for determination of iron redox species by the use of diffusive gradients in thin-film (DGT) technique coupled to photothermal beam deflection spectroscopy (BDS). The combination of both methods achieved low limit of detection (LOD) of 0.14 μM for Fe (II) ions. The total Fe concentration determined in the Vrtojbica river sediment (Slovenia, Rožna Dolina, 5000 Nova Gorica) was 49.3 μgL–1. The Fe (II) and Fe (III) concentra- tion amounted to 12.8 μgL–1 and 39.9 μgL–1, respectively. Such an approach opens new opportunities for monitoring the content of iron species in natural waters and sediments and provides highly sensitive chemical analysis and an accurate qualitative and quantitative characteristic of the materials under study.
Najdeno v: ključnih besedah
Ključne besede: Beam deflection spectroscopy, diffusive gradients in thin-film technique, iron redox species, photothermal techniques, sediment
Objavljeno: 26.02.2019; Ogledov: 905; Prenosov: 45
Polno besedilo (452,58 KB) |
5. Determination of bioavailable Fe redox fractions of sediment pore waters by DGT passive sampling and BDS detectionMladen Franko, Arne Bratkič, Dorota Korte, Hanna Budasheva, 2019, objavljeni povzetek znanstvenega prispevka na konferenci Opis: The bioavailability and toxicity of contaminants in sediments to benthic organisms depend on the speciation of the contaminant [1]. The level of iron supply to sediments creates contrasting chemical pathways, each producing distinctive mineral assemblag- es. Reliable measurement of Fe redox species (Fe2+ and Fe3+) in sediments is essential for studies of pollutants or trace-element cycling. This is, however, a difficult task, because the distribution of chemical species often changes during sampling and storage.
In this work the Diffusive Gradients in Thin-films technique (DGT) is investigated as a passive sampling approach used in combination with photothermal beam deflection spectroscopy (BDS) as a detection method for determination of labile Fe-redox species in sediments and natural waters. DGT offers the advantage of pre-concentration of labile (i.e. bioavailable) Fe species from the total dissolved Fe pool in sediment pore waters [2]. The advantage of using BDS [3-4] is also in avoiding contamination by using additional steps as extraction or pre-concentration. Furthermore, combined DGT-BDS provides 2D information about distribution of Fe2+ and the total Fe content in the resin hydrogels [5].
The goal of this research is to show the repeatability of this technique for determining trace amounts of Fe redox species in environmental samples.
Najdeno v: ključnih besedah
Povzetek najdenega: ...of the contaminant [1]. The level of iron supply to sediments creates contrasting chemical pathways,... ...assemblag- es. Reliable measurement of Fe redox species (Fe2+ and Fe3+) in sediments is essential...
Ključne besede: beam deflection spectrometry, diffusive gradients in thin-films, iron species
Objavljeno: 16.07.2019; Ogledov: 619; Prenosov: 0
Polno besedilo (29,60 MB) |
6. Effect of bead size in Chelex-based resin hydrogels in DGT on detection of Fe redox species by beam deflection spectroscopyDorota Korte, Arne Bratkič, Hanna Budasheva, Mladen Franko, 2019, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Povzetek najdenega: ...Gradients in Thin Films, Beam Deflection Spectrometry, iron species, resin hydrogels...
Ključne besede: Diffusive Gradients in Thin Films, Beam Deflection Spectrometry, iron species, resin hydrogels
Objavljeno: 25.09.2019; Ogledov: 541; Prenosov: 0
Polno besedilo (1,28 MB) |
7. Developing DGT technique for determination of iron redox species by photothermal beam deflection spectrometryYue Gao, Dorota Korte, Chang Zhou, Arne Bratkič, Hanna Budasheva, Mladen Franko, Bruno Delille, 2019, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Ključne besede: Diffusive Gradients in Thin Films, Beam Deflection Spectrometry, iron redox species
Objavljeno: 25.09.2019; Ogledov: 594; Prenosov: 0
Polno besedilo (1,28 MB) |
8. Determination of Fe(III) and Fe(II) in natural waters using passive DGT samplers and non-destructive BDS analysisArne Bratkič, Dorota Korte, Hanna Budasheva, Mladen Franko, 2019, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Povzetek najdenega: ...Beam Deflection Spectrometry, iron species, Diffusive Gradients in Thin-films, frequency scanning...
Ključne besede: Beam Deflection Spectrometry, iron species, Diffusive Gradients in Thin-films, frequency scanning
Objavljeno: 30.09.2019; Ogledov: 637; Prenosov: 0
Polno besedilo (19,45 MB) |
