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1.
Chemical and structural investigation of the cobalt phthalocyanine
Matija Stupar, 2015, magistrsko delo

Opis: In the last two decades, studies on organic molecules mimicking substances of fundamental importance in nature, like chlorophyll or hemoglobin, have attracted researchers’ attention. These molecules are building blocks for a family of materials also referred to as “organic semiconductors”. Such compounds can be implemented in numerous applications, ranging from data-storage to light harvesting. Some of their fundamental advantages include low cost, light weight, relatively easy engineering and mechanical flexibility, compatible with bending plastic substrates. In this thesis work we investigated the chemical, structural and electronic properties of cobalt phthalocyanines (CoPc). These molecules have promising applications in the field of magnetic data storage and spintronics in general, due to the ferromagnetic properties of the cobalt atom. Several techniques like photoemission core-level spectroscopy and valence band spectroscopy, together with X-ray absorption, have been used in order to determine the CoPc properties in gaseous phase, i.e. in the absence of interaction with the surrounding environment. Another set of experiments was devoted to the commissioning of the CITIUS time-resolved photoemission setup, that will be used in future studies of CoPc molecules on surfaces.
Najdeno v: ključnih besedah
Povzetek najdenega: ...photoemission spectroscopy (PES), X-ray absorption spectroscopy (XAS), synchrotron radiation, laser, high order harmonic generation (HHG),...
Ključne besede: Cobalt phthalocyanine (CoPc), photoemission spectroscopy (PES), X-ray absorption spectroscopy (XAS), synchrotron radiation, laser, high order harmonic generation (HHG), time resolved spectroscopy
Objavljeno: 29.09.2015; Ogledov: 1646; Prenosov: 65
.pdf Polno besedilo (2,96 MB)

2.
Atomic-level mechanisms of magnesium oxidation
Dmytro Orlov, Matjaž Valant, Sandra Gardonio, Mattia Fanetti, 2016, objavljeni znanstveni prispevek na konferenci

Opis: Magnesium has been recently becoming an increasingly popular material for various applications. However, excessive chemical reactivity, and oxidation rate in particular, is a major obstruction on the way of Mg to become widely adopted. A significant problem causing the lack of Mg reactivity control is insufficient understanding of mechanisms involved in the oxidation of magnesium surface. Herewith we present the investigation of atomic-level mechanisms of oxidation initiation and propagation in pure Mg. Namely, X-ray photoelectron spectroscopy at synchrotron Elettra was used as a surface sensitive direct method to determine the valence of Mg and O and the valence band states at the early stage of oxide formation over a principal, most densely packed, crystallographic plane (0001) in pure Mg. The mechanisms of oxygen adsorption on magnesium free surface followed by oxidation (i.e. initiation and kinetics of MgO formation) are clarified. Copyright © 2016 by The Minerals, Metals & Materials Society. All rights reserved.
Najdeno v: ključnih besedah
Povzetek najdenega: ...pure Mg. Namely, X-ray photoelectron spectroscopy at synchrotron Elettra was used as a surface sensitive... ...Magnesium, Oxidation, Synchrotron radiation, X-ray photoelectron spectroscopy...
Ključne besede: Magnesium, Oxidation, Synchrotron radiation, X-ray photoelectron spectroscopy
Objavljeno: 25.08.2017; Ogledov: 309; Prenosov: 0
.pdf Polno besedilo (2,91 MB)

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