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2. Learning from Nature: Charge Transfer and Carbon Dioxide Activation at Single, Biomimetic Fe Sites in Tetrapyrroles on GrapheneErik Vesselli, Nicola Seriani, Maria Peressi, Cinzia Cepek, Matteo Rinaldi, Erika Tomsič, Fatema Mohamed, Manuel Corva, 2019, izvirni znanstveni članek Ključne besede: carbon dioxide, phthalocyanines, graphene, oxygen, Dirac cones Objavljeno: 03.12.2019; Ogledov: 45; Prenosov: 0
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3. Substrate- to Laterally-Driven Self-Assembly Steered by Cu Nanoclusters: The Case of FePcs on an Ultrathin Alumina FilmMaria Peressi, Nicola Seriani, Giovanni Comelli, Tomas Skala, Zhijing Feng, Fatema Mohamed, Erika Tomsič, Manuel Corva, Erik Vesselli, 2018, izvirni znanstveni članek Ključne besede: copper, nanoclusters, alumina, iron phthalocyanine, Ni3Al Objavljeno: 03.12.2019; Ogledov: 41; Prenosov: 0
Polno besedilo (9,93 MB) |
4. Zr/Cu-TiO2 CATALYSTS FOR PHOTOCATALYTIC WATER TREATMENTOlena Pliekhova, doktorska disertacija Opis: This work entitled «Zr/Cu-TiO2 catalysts for photocatalytic water treatment» tackles a problem of tons of dyes discharged everyday mainly from textile industries. This is a huge concern because of dyes persistence, toxicity and potential to the bioaccumulation in living organisms. Here, a small contribution to overall problem is presented.
The research work consists of three main parts: Theoretical background, Experimental and Results and discussion. In the Theoretical background chapter the overall problem is identified and discussed. The main water treatment techniques are presented briefly with their advantages and drawbacks. Photocatalysis assisted with TiO2 is shown as an alternative additional technique with its own pros and cons. Further, a cursory overview of TiO2 modification techniques is made and advantages in using copper and zirconium oxides for TiO2 modification are presented. The reason and possible positive effect of using of two oxides simultaneously for TiO2 modification is indicated. Additionally, a positive impact of solar light for overall rate of dyes degradation assisted with TiO2 is discussed. Within the framework of photosensitization effect, the problem of using dyes for assessment of photocatalytic properties of materials under the visible light is touched on. Photothermal methods as possible beneficial techniques for this purpose are proposed.
In the Experimental chapter, all experimental techniques used in current research work with the technical details specific for the research work are presented. There are methods of materials preparation, photocatalytic tests under different conditions and varying model pollutants, and physico-chemical characterization techniques.
The Results and discussion chapter is divided by three subchapters. Each chapter is dedicated to one hypothesis, which was checked and confirmed or disproved. The first hypothesis is about beneficial loading of copper and zirconium oxides to TiO2. After numerous experiments held, it was concluded that the pair of copper and zirconium oxides is beneficial for simultaneous application on TiO2 surface to promote its performance.
The second subchapter is about zirconium distribution and its impact on the activity of studied materials towards the antraquinone dye Reactive Blue 19. Different techniques such as XRD, TEM, EXAFS and many others were used in order to characterize the materials and to understand the details of the processes taking place. The existence of upper limit of copper oxide loading for its beneficial effect on TiO2 performance was demonstrated. It was observed that zirconium species loading leads to improvement in performance of materials with higher copper loading, which otherwise lowers activity of TiO2 – this is in case when copper only above its optimal level is present. It was concluded that zirconium oxide containing species occupy rutile surface sites in mixed phase TiO2 and this way beneficially influence the material performance towards the dye removal.
The third subchapter is about the visible light TiO2 assisted dye degradation. It is well known that photosensitization mechanism of dye degradation appears under the visible and as a consequence under the solar light irradiation. This leads to the overall enhancement of dyes degradation, which is positive and may be used as a benefit for faster pollutant destruction. However, this fact leads to mishmash in the determination of real photocatalytic activity of materials towards the dye. It was hypothesized that the impact of photosensitization mechanism on the overall material performance against Reactive blue 19 dye (RB19) descends with the dye concentration lowering. Thermal lens spectrometry (TLS) which is sensitive to chemicals at low concentrations was used for hypothesis evaluation.
To summarize the research work achievements, the conclusions of the thesis are given at the end. Ključne besede: titanium dioxide, photocatalysis, zirconium/copper, surface modification, water treatment, dyes Objavljeno: 03.12.2019; Ogledov: 32; Prenosov: 1
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5. WEAK CLOSURE OPERATIONS WITH SPECIAL TYPES IN LOWER BCK-SEMILATTICESHashem Bordbar, Young Bae Jun, 2017, izvirni znanstveni članek Opis: The notions of (strong) quasi prime mapping on the set of all ideals, t- type weak closure operation, and tender (resp., naive, sheer, feeble tender) weak closure operation are introduced, and their relations and properties are investigated. Conditions for a weak closure operation to be of t-type are provided. Given a weak closure operation, conditions for the new weak closure operation to be of t-type and to be a naive (sheer, feeble tender) weak closure operation are considered. We show that the new weak closure operation is the smallest tender weak closure operation containing the given weak closure operation. Ključne besede: (strong) quasi prime mapping, t-type weak closure operation, naive (sheer, tender, feeble tender) weak closure operation. Objavljeno: 02.12.2019; Ogledov: 24; Prenosov: 0
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8. IDEALS OF IS-ALGEBRAS BASED ON N-STRUCTURESHashem Bordbar, Mohammad Mehdi Zahedi, Young Bae Jun, 2018, izvirni znanstveni članek Opis: The notion of a left (resp., right) NI-ideal is introduced, and related properties are investigated. Characterizations of a left (resp., right) NI-ideal are considered. Translations of a left (resp., right) NI-ideal are studied. We show that the homomorphic image (preimage) of a left (resp., right) NI-ideal is a left (resp., right) NI-ideal. The notion of retrenched left (resp., right) NI-ideals is introduced, and their properties are investigated. Ključne besede: Left (resp., right) NI-ideal, translation, closed support, retrenched left (resp., right) NI-ideal. Objavljeno: 02.12.2019; Ogledov: 17; Prenosov: 0
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9. Neutrosophic Permeable Values and Energetic Subsets with Applications in BCK/BCI-AlgebrasHashem Bordbar, Young Bae Jun, Florentin Smarandache, Seok Zun Song, 2018, izvirni znanstveni članek Opis: The concept of a (∈, ∈)-neutrosophic ideal is introduced, and its characterizations are established. The notions of neutrosophic permeable values are introduced, and related properties are investigated. Conditions for the neutrosophic level sets to be energetic, right stable, and right vanished are discussed. Relations between neutrosophic permeable S- and I-values are considered. Ključne besede: (∈, ∈)-neutrosophic subalgebra, (∈, ∈)-neutrosophic ideal, neutrosophic (anti-)permeable S-value, neutrosophic (anti-)permeable I-value, S-energetic set, I-energetic set Objavljeno: 02.12.2019; Ogledov: 13; Prenosov: 0
Polno besedilo (297,13 KB) |
10. Neutrosophic falling shadows applied to subalgebras and ideals in BCK/BCI-algebrasHashem Bordbar, Florentin Smarandache, Young Bae Jun, 2018, izvirni znanstveni članek Opis: As a combination of neutrosophic set and falling shadow, neutrosophic falling shadow is introduced, and applied to BCK/BCI- algebras. Falling neutrosophic subalgebra and falling neutrosophic ideal in BCK/BCI-algebras are introduced, and related properties are investi- gated. Relations between falling neutrosophic subalgebra and falling neu- trosophic ideal are discussed. A characterization of falling neutrosophic ideal is established. Ključne besede: (∈, ∈)-neutrosophic subalgebra, (∈, ∈)-neutrosophic ideal, Neutro- sophic random set, Neutrosophic falling shadow, Falling neutrosophic subalgebra, Falling neutrosophic ideal. Objavljeno: 02.12.2019; Ogledov: 11; Prenosov: 0
Polno besedilo (324,41 KB) |