1. A multi-thermal-lens approach to evaluation of multi-pass probe beam configuration in thermal lens spectrometryHumberto Cabrera, Leja Goljat, Dorota Korte, Ernesto Marin, Mladen Franko, izvirni znanstveni članek Opis: In this work, a recently proposed thermal lens instrument based on multi-pass probe beam concept is investigated and described as a multi-thermal-lens equivalent system. A simulation of the photothermal lens signal formation in a multi-thermal-lens equivalent configuration of the system is performed and validated by comparing the experimental signals of single, dual and ten-pass configurations to theoretically calculated values. The theoretically predicted enhancement of the signal is 9 to 10-fold for a weak thermal lens when comparing the ten-pass configuration with the conventional single-pass thermal lens system. Experimentally achieved signal enhancement in the ten-pass system is 8.3 for pure ethanol sample and between 8 and 9 for solutions with different concentrations of the Fe(II) - 1,10-Phenanthroline complex. Additionally, a value of 9.1 was calculated as the ratio of the slopes of the calibration lines obtained using the ten-pass and single-pass configurations. The achieved limit of detection for determination of Fe(II), in the ten-pass configuration, was 0.4 µgL-1, with a relative standard deviation around 4.5%, which compares favorably with previously reported results for TLS determination of Fe(II) in thin samples using low excitation power. For the multi-pass configuration the linear range of measurement is reduced when compared to the single-pass configuration. This is explained by the theoretical analysis of the photothermal signal under multi-pass condition, which shows the important contribution of the nonlinear term in the theoretical expression for the photothermal signal. The ten-pass configuration, which is presented and validated experimentally for the first time, offers important signal enhancement needed in recently developed TLS instruments with tunable, low power excitation sources. Ključne besede: Thermal lens spectrometry, Photothermal detection, Trace determination, Chemical sensor Objavljeno: 10.12.2019; Ogledov: 1; Prenosov: 0
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3. Learning from Nature: Charge Transfer and Carbon Dioxide Activation at Single, Biomimetic Fe Sites in Tetrapyrroles on GrapheneErik Vesselli, Nicola Seriani, Maria Peressi, Cinzia Cepek, Matteo Rinaldi, Erika Tomsič, Fatema Mohamed, Manuel Corva, 2019, izvirni znanstveni članek Ključne besede: carbon dioxide, phthalocyanines, graphene, oxygen, Dirac cones Objavljeno: 03.12.2019; Ogledov: 66; Prenosov: 0
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4. Substrate- to Laterally-Driven Self-Assembly Steered by Cu Nanoclusters: The Case of FePcs on an Ultrathin Alumina FilmMaria Peressi, Nicola Seriani, Giovanni Comelli, Tomas Skala, Zhijing Feng, Fatema Mohamed, Erika Tomsič, Manuel Corva, Erik Vesselli, 2018, izvirni znanstveni članek Ključne besede: copper, nanoclusters, alumina, iron phthalocyanine, Ni3Al Objavljeno: 03.12.2019; Ogledov: 64; Prenosov: 0
Polno besedilo (9,93 MB) |
5. WEAK CLOSURE OPERATIONS WITH SPECIAL TYPES IN LOWER BCK-SEMILATTICESHashem Bordbar, Young Bae Jun, 2017, izvirni znanstveni članek Opis: The notions of (strong) quasi prime mapping on the set of all ideals, t- type weak closure operation, and tender (resp., naive, sheer, feeble tender) weak closure operation are introduced, and their relations and properties are investigated. Conditions for a weak closure operation to be of t-type are provided. Given a weak closure operation, conditions for the new weak closure operation to be of t-type and to be a naive (sheer, feeble tender) weak closure operation are considered. We show that the new weak closure operation is the smallest tender weak closure operation containing the given weak closure operation. Ključne besede: (strong) quasi prime mapping, t-type weak closure operation, naive (sheer, tender, feeble tender) weak closure operation. Objavljeno: 02.12.2019; Ogledov: 44; Prenosov: 0
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8. IDEALS OF IS-ALGEBRAS BASED ON N-STRUCTURESHashem Bordbar, Mohammad Mehdi Zahedi, Young Bae Jun, 2018, izvirni znanstveni članek Opis: The notion of a left (resp., right) NI-ideal is introduced, and related properties are investigated. Characterizations of a left (resp., right) NI-ideal are considered. Translations of a left (resp., right) NI-ideal are studied. We show that the homomorphic image (preimage) of a left (resp., right) NI-ideal is a left (resp., right) NI-ideal. The notion of retrenched left (resp., right) NI-ideals is introduced, and their properties are investigated. Ključne besede: Left (resp., right) NI-ideal, translation, closed support, retrenched left (resp., right) NI-ideal. Objavljeno: 02.12.2019; Ogledov: 39; Prenosov: 0
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9. Neutrosophic Permeable Values and Energetic Subsets with Applications in BCK/BCI-AlgebrasHashem Bordbar, Young Bae Jun, Florentin Smarandache, Seok Zun Song, 2018, izvirni znanstveni članek Opis: The concept of a (∈, ∈)-neutrosophic ideal is introduced, and its characterizations are established. The notions of neutrosophic permeable values are introduced, and related properties are investigated. Conditions for the neutrosophic level sets to be energetic, right stable, and right vanished are discussed. Relations between neutrosophic permeable S- and I-values are considered. Ključne besede: (∈, ∈)-neutrosophic subalgebra, (∈, ∈)-neutrosophic ideal, neutrosophic (anti-)permeable S-value, neutrosophic (anti-)permeable I-value, S-energetic set, I-energetic set Objavljeno: 02.12.2019; Ogledov: 28; Prenosov: 0
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10. Neutrosophic falling shadows applied to subalgebras and ideals in BCK/BCI-algebrasHashem Bordbar, Florentin Smarandache, Young Bae Jun, 2018, izvirni znanstveni članek Opis: As a combination of neutrosophic set and falling shadow, neutrosophic falling shadow is introduced, and applied to BCK/BCI- algebras. Falling neutrosophic subalgebra and falling neutrosophic ideal in BCK/BCI-algebras are introduced, and related properties are investi- gated. Relations between falling neutrosophic subalgebra and falling neu- trosophic ideal are discussed. A characterization of falling neutrosophic ideal is established. Ključne besede: (∈, ∈)-neutrosophic subalgebra, (∈, ∈)-neutrosophic ideal, Neutro- sophic random set, Neutrosophic falling shadow, Falling neutrosophic subalgebra, Falling neutrosophic ideal. Objavljeno: 02.12.2019; Ogledov: 32; Prenosov: 0
Polno besedilo (324,41 KB) |