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Opis: The present work employs time series analysis, a proven powerful mathematical tool, for investigating the complex molecular dynamics of the thermal lens (TL) system induced by the duty cycle (C) variation. For intensity modulation, TL spectroscopy commonly uses optical choppers. The TL formation involves complex molecular dynamics that vary with the input photothermal energy, which is implemented by varying the duty cycle of the chopper. The molecular dynamics is studied from the fractal dimension (D), phase portrait, sample entropy (S), and Hurst exponent (H) for different duty cycles. The increasing value of C is found to increase D and S, indicating that the system is becoming complex and less deterministic, as evidenced by the phase portrait analysis. The value of H less than 0.5 conforms the evolution of the TL system to more antipersistent nature with C. The increasing value of C increases the enthalpy of the system that appears as an increase in full width at half maximum of the refractive index profile. Thus the study establishes that the sample entropy and thermodynamic entropy are directly related.
Ključne besede: Time series analysis Fractal analysis Photothermal lens spectroscopy Fractal dimension Hurst exponent Sample entropy
Objavljeno: 05.07.2022; Ogledov: 92; Prenosov: 0
Polno besedilo (1,30 MB)

Opis: This paper proposes a novel surrogate method of classification of breath sound signals for auscultation through the principal component analysis (PCA), extracting the features of a phase portrait. The nonlinear parameters of the phase portrait like the Lyapunov exponent, the sample entropy, the fractal dimension, and the Hurst exponent help in understanding the degree of complexity arising due to the turbulence of air molecules in the airways of the lungs. Thirty-nine breath sound signals of bronchial breath (BB) and pleural rub (PR) are studied through spectral, fractal, and phase portrait analyses. The fast Fourier transform and wavelet analyses show a lesser number of high-intense, low-frequency components in PR, unlike BB. The fractal dimension and sample entropy values for PR are, respectively, 1.772 and 1.041, while those for BB are 1.801 and 1.331, respectively. This study reveals that the BB signal is more complex and random, as evidenced by the fractal dimension and sample entropy values. The signals are classified by PCA based on the features extracted from the power spectral density (PSD) data and the features of the phase portrait. The PCA based on the features of the phase portrait considers the temporal correlation of the signal amplitudes and that based on the PSD data considers only the signal amplitudes, suggesting that the former method is better than the latter as it reflects the multidimensional aspects of the signal. This appears in the PCA-based classification as 89.6% for BB, a higher variance than the 80.5% for the PR signal, suggesting the higher fidelity of the phase portrait-based classification.
Ključne besede: Phase Portrait, time series, feature extraction, pleural rub
Objavljeno: 05.07.2022; Ogledov: 102; Prenosov: 0
Polno besedilo (2,47 MB)

Opis: The manuscript attempts to explore the periodicity in the distribution of galaxies in the recently reported Saraswati supercluster and the Stripe 82 region containing it as an example. The report of 120 Mpc periodicity in the Abell galaxy clusters by power spectrum analysis is the motivation behind the study. The power spectral analysis across the central part of the Stripe 82 region shows a periodic variation of 3.09° or 71 Mpc in fractal dimension whereas an average angular periodicity of 3.45° or 94 Mpc is observed across the Stripe 82 region. This refers to the periodicity of complexity or cluster density of galaxy distribution. The texture of the distribution pattern understood through lacunarity analysis indicates a near symmetric distribution. Fractal dimensions like box-counting dimension, information dimension and correlation dimension are also found through multifractal analysis. While the information dimension tells about the distribution density of galactic points, the correlation dimension details the distribution of galaxies in the neighbourhood
Ključne besede: galaxy distribution, fractal analysis, multifractals, lacunarity, Saraswati supercluster, Stripe 82
Objavljeno: 04.07.2022; Ogledov: 113; Prenosov: 0
Polno besedilo (928,89 KB)

Opis: he mode mismatch dual-beam thermal lens technique is a sensitive tool for studying the nanofuids’ thermal difusivity in thermal engineering. The work reports the low-temperature green synthesis of hafnium carbide (HfC) using rice four as a natural carbon precursor and its potential in heat transfer nanofuids by studying the concentration-dependent thermal difusivity. The structure characterisations confrm the formation of HfC, whose refractory nature is revealed through the high thermal stability observed in the thermogravimetric analysis. The Tauc plot analysis shows direct bandgap energy of 2.92 eV. The fuorescence study suggests bluish-pink emission with CIE coordinates (0.271, 0.263). The existence of the critical concentration of HfC in the nanofuid decides its suitability for heat transfer or heat trap applications indicating a concentration-dependent thermal duality. Thus, the study is signifcant as it overcomes the major drawbacks of the existing methods of the synthesis of refractory HfC, using toxic chemical and costly equipment for heat transfer applications.
Ključne besede: hafnium carbide, hydrothermal synthesis, rice flour, thermal lens spectroscopy
Objavljeno: 04.07.2022; Ogledov: 84; Prenosov: 0
Polno besedilo (1,50 MB)

Opis: The paper reports the preparation of thin film with MoO3 nanowires (NWs) by the doctor blade method and the study of its thermal diffusivity (α) by the sensitive photothermal beam deflection (PTD) method. When the Field Emission Scanning Electron Microscopic and Atomic Force Microscopic analysis unveil its morphology as NW bundles, the X-ray diffraction analysis reveals the structure to be orthorhombic. The NWs formed are of diameter ~ 20 nm and length up to 5 μm. The standardization of the transverse PTD setup is done by determining the value of α of iron, which agrees well with literature reports. The thermal diffusivity of MoO3 NW film is obtained as 0.0036 cm2 /s, which is 9.48% of its bulk counterpart. The reduction in the thermal diffusivity of NW makes it a suitable candidate for thermoelectric applications.
Ključne besede: Nanowires Molybdenum oxide Photothermal beam deflection Thermal diffusivity
Objavljeno: 04.07.2022; Ogledov: 110; Prenosov: 0
Polno besedilo (3,64 MB)