61. Bi-magnetic composite nanoplatelets combining hard-magnetic barium hexaferrite core covered with soft magnetic iron oxide layerBlaž Belec, Darko Makovec, Goran Dražić, Benjamin Podmiljšak, Tanja Goršak, Sašo Gyergek, Matej Komelj, Josep Nogues, vabljeno predavanje na konferenci brez natisa Ključne besede: bi-magnetic nanoparticles, composite nanoparticles, exchange coupling
Objavljeno v RUNG: 05.06.2018; Ogledov: 3809; Prenosov: 0
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63. Speciation and Determination of Ionic and Trace-Level Colloidal Silver in Selected Personal Care Products by Thermal Lens SpectrometryDorota Korte, Ales Grahovac, Andrej Jerkic, Olga Vajdle, Jasmina Anojčić, Valeria Guzsvány, Bojan Budič, Mladen Franko, 2018, izvirni znanstveni članek Ključne besede: Silver nanoparticles, Colloidal silver, Personal care
products, Thermal lens spectrometric determination, Flow injection
analysis
Objavljeno v RUNG: 26.02.2018; Ogledov: 4229; Prenosov: 0
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64. Reconstructed properties of the sources of UHECR and their dependence on the extragalactic magnetic fieldDavid Wittkowski, Andrej Filipčič, Gašper Kukec Mezek, Ahmed Saleh, Samo Stanič, Marta Trini, Darko Veberič, Serguei Vorobiov, Lili Yang, Danilo Zavrtanik, Marko Zavrtanik, 2017, objavljeni znanstveni prispevek na konferenci Ključne besede: extragalactic magnetic field, Pierre Auger Observatory, sources of UHECR
Objavljeno v RUNG: 16.02.2018; Ogledov: 3382; Prenosov: 161
 Celotno besedilo (356,61 KB) |
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66. Photoelectrochemical Water Splitting Studies with nanostructured n and p-type semiconductor electrodesSaim Emin, Matjaž Valant, 2017, objavljeni povzetek znanstvenega prispevka na konferenci (vabljeno predavanje) Opis: Photoelectrochemical water splitting has been demonstrated as a promising way to efficiently split water. Currently, solar-to-hydrogen conversion efficiency using state-of-the-art material combinations in PEC system is in the order of 7%. Fabrication of nanostructured materials with unique morphologies and compositions is an important factor to fully utilize the possibilities in this field. We will present different strategies for the preparation of nanostructured metal oxide thin films by using electrodeposition and wet-chemistry techniques. Focus will be given on the preparation of ZnO and CuO thin films where intermediate phases like Zn(OH)8Cl2.H2O and CuX (X=Br, Cl) were electrodeposited. Wet-chemistry synthesis techniques will be also explored for the preparation of nanostructured WO3 and a-Fe2O3 thin films. Especially, the hot-pyrolysis technique for the preparation of colloidal W and Fe/Fe-oxide nanoparticles will be shown. Spin-coating of W and Fe/Fe-oxide NPs onto optically conductive substrates and subsequent heat treatment of the obtained films was found to be a convenient way for the preparation of nanostructured WO3 and a-Fe2O3 thin films.
Ključne besede: photoelectrochemical water splitting, colloidal nanoparticles, semiconductor
Objavljeno v RUNG: 24.10.2017; Ogledov: 4440; Prenosov: 0
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67. Metal oxide and metal carbides thin films for photo/electrochemical water splitting studiesSaim Emin, 2017, objavljeni povzetek znanstvenega prispevka na konferenci Opis: We used wet-chemistry techniques to prepare colloidal tungsten (W) nanoparticles (NPs). The synthesis of W NPs was conducted using the so called hot-matrix method in 1-octadecene [1]. The sizes of obtained W NPs are in the order of 2 - 5 nm. These W NPs are coated with hydrophobic molecules which allow their dispersion in organic solvents like choloroform (CHCl3). It was found that the colloidal stability of the dispersions is exceptionally high exceeding several years. The stability of W NPs which prevents coagulation allows the preparation of thin films with uniform thicknesses by spin-coating, inkjet-printing and spray coating.
We have prepared both tungsten trioxide (WO3) and tungsten carbide (W2C, WC) thin films. The preparation of WO3 thin films was achieved by spin-coating of W NPs on fluorine doped tin oxide (FTO) glass substrates and following thermal treatment in air at 500°C. The preparation of W2C and WC were done after spin-coating of W NPs on graphite substrate and following heat treatment under Ar atmosphere at 1000 and 1450°C.
The obtained WO3 and W2C (e.g WC) films were used both in photo/electrochemical water splitting studies. In conclusion, we have developed a procedure for the synthesis of W NPs which can be used for the preparation of different class of materials for water splitting studies.
Ključne besede: metal oxides, metal carbides, tungsten nanoparticles
Objavljeno v RUNG: 09.10.2017; Ogledov: 5282; Prenosov: 0
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68. Tungsten carbide thin films for electrochemical water splitting studiesSaim Emin, Cesur Altinkaya, Ali Semerci, Matjaž Valant, Hasan Okuyucu, Abdullah Yildiz, 2017, objavljeni povzetek znanstvenega prispevka na konferenci Opis: We used wet-chemistry techniques to prepare colloidal tungsten (W) nanoparticles (NPs). The synthesis of W NPs was conducted using the so called hot-matrix method in 1-octadecene [1]. The sizes of obtained W NPs are in the order of 2 - 5 nm. These W NPs are coated with hydrophobic molecules which allow their dispersion in organic solvents like choloroform (CHCl3). It was found that the colloidal stability of the dispersions is exceptionally high exceeding several years. The stability of W NPs which prevents coagulation allows the preparation of thin films with uniform thicknesses by spin-coating, inkjet-printing and spray coating.
We have prepared tungsten carbide (W2C, WC) thin films. The preparation of W2C and WC was achieved by spin-coating of pre-synthesized W NPs on graphite substrate and following heat treatment under Ar atmosphere at 1000 and 1450°C.
The obtained W2C and WC films were used both in electrochemical water splitting studies. We also made a composite W2C-Pt films where we used only 5 at.% of Pt. The W2C-Pt composite has shown similar performance as pure Pt-C for hydrogen (H2) evolution. In conclusion, we have developed a procedure for the synthesis of W NPs which can be applied for the preparation of tungsten carbides films and their use for electrochemical water splitting.
Ključne besede: water splitting, nanoparticles, hot-matrix
Objavljeno v RUNG: 09.10.2017; Ogledov: 5998; Prenosov: 0
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69. Facile synthesis, structure, biocompatibility and antimicrobial property of gold nanoparticle composites from cellulose and keratinChieu D. Tran, Franja Prosenc, Mladen Franko, 2018, izvirni znanstveni članek Opis: A novel, one-pot method was developed to synthesize gold nanoparticle composite from cellulose (CEL), wool keratin (KER) and chloroauric acid. Two ionic liquids, butylmethylimmidazolium chloride and ethylmethylimmidazolium bis(trifluoromethylsulfonyl)imide were used to dissolve CEL, KER and HAuCl4. X-ray diffraction and X-ray photoelectron results show that Au3+ was completely reduced to Au0NPs with size of (5.5 ± 1) nm directly in the composite with NaBH4. Spectroscopy and imaging results indicate that CEL and KER remained chemically intact and were homogeneously distributed in the com- posites with Au0NPs. Encapsulating Au0NPs into [CEL+KER] composite made the composite fully biocom- patible and their bactericidal capabilities were increased by the antibacterial activity of Au0NPs. Specifically, the [CEL+KER+Au0NPs] composite exhibited up to 97% and 98% reduction in growth of antibi- otic resistant bacteria such as vancomycin resistant Enterococcus faecalis and methicillin resistant Staphylococcus aureus, and was not cytotoxic to human fibroblasts. While [CEL+KER] composite is known to possess some antibacterial activity, the enhanced antibacterial observed here was due solely to added Au0NPs. These results together with our previous finding that [CEL+KER] composites can be used for con- trolled delivery of drugs clearly indicate that the [CEL+KER+Au0NPs] composites possess all required properties for successful use as dressing to treat chronic ulcerous infected wounds.
Ključne besede: Ionic liquid
Green
Sustainable
Polysaccharide
Keratin
Wound dressing
Gold nanoparticles Antibiotic-resistant bacteria
Objavljeno v RUNG: 27.09.2017; Ogledov: 4400; Prenosov: 0
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70. Biotransformation of copper oxide nanoparticles by the pathogenic fungus Botrytis cinereaEva Kovačec, Marjana Regvar, Johannes Teun van Elteren, Iztok Arčon, Tamás Papp, Darko Makovec, Katarina Vogel-Mikuš, 2017, izvirni znanstveni članek Opis: Two plant pathogenic fungi, Botrytis cinerea and Alternaria alternata, isolated from crop plants, were
exposed to Cu in ionic (Cu2þ), microparticulate (MP, CuO) or nanoparticulate (NP, Cu or CuO) form, in
solid and liquid culturing media in order to test fungal response and toxic effects of the mentioned
compounds for the potential use as fungicides. B. cinerea has shown pronounced growth and lower levels
of lipid peroxidation compared to A. alternata. Its higher resistance/tolerance is attributed mainly to
biotransformation of CuO and Cu NPs and CuO MPs into a blue compound at the fungal/culturing media
interface, recognized by Cu K-edge EXAFS analysis as Cu-oxalate complex. The pronounced activity of
catechol-type siderophores and organic acid secretion in B. cinerea induce leaching and mobilization of
Cu ions from the particles and their further complexation with extracellularly secreted oxalic acid. The
ability of pathogenic fungus to biotransform CuO MPs and NPs hampers their use as fungicides. However
the results show that B. cinerea has a potential to be used in degradation of Cu(O) nanoparticles in
environment, copper extraction and purification techniques.
Ključne besede: copper, metal oxide nanoparticles, detoxification mechanisms, metal pollution, Cu-oxalate
Objavljeno v RUNG: 23.08.2017; Ogledov: 4361; Prenosov: 0
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