1. Designing atomic interface in ▫$Sb_2S_3/CdS$▫ heterojunction for efficient solar water splittingMinji Yang, Zeyu Fan, Jinyan Du, Chao Feng, Ronghua Li, Beibei Zhang, Nadiia Pastukhova, Matjaž Valant, Matjaž Finšgar, Andraž Mavrič, Yanbo Li, 2024, original scientific article Abstract: In the emerging Sb2S3‐based solar energy conversion devices, a CdS buffer layer prepared by chemical bath deposition is commonly used to improve the separation of photogenerated electron‐hole pairs. However, the cation diffusion at the Sb2S3/CdS interface induces detrimental defects but is often overlooked. Designing a stable interface in the Sb2S3/CdS heterojunction is essential to achieve high solar energy conversion efficiency. As a proof of concept, this study reports that the modification of the Sb2S3/CdS heterojunction with an ultrathin Al2O3 interlayer effectively suppresses the interfacial defects by preventing the diffusion of Cd2+ cations into the Sb2S3 layer. As a result, a water‐splitting photocathode based on Ag:Sb2S3/Al2O3/CdS heterojunction achieves a significantly improved half‐cell solar‐to‐hydrogen efficiency of 2.78% in a neutral electrolyte, as compared to 1.66% for the control Ag:Sb2S3/CdS device. This work demonstrates the importance of designing atomic interfaces and may provide a guideline for the fabrication of high‐performance stibnite‐type semiconductor‐based solar energy conversion devices.
Keywords: alumina, defect passivation, interface engineering, photoelectrochemical water splitting
Published in RUNG: 11.03.2024; Views: 258; Downloads: 2
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2. Radio interferometry applied to air showers recorded by the Auger engineering radio arrayH. Schoorlemmer, Andrej Filipčič, Jon Paul Lundquist, Shima Ujjani Shivashankara, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, 2023, published scientific conference contribution Abstract: A new radio interferometric technique was recently developed that takes into account time lags caused by the three-dimensional dependency of the refractive index in the atmosphere. It enables us to track the extensive air shower while it propagates through the atmosphere. Using this technique, properties of the air shower can be estimated, like the depth of maximum and the axis of propagation. In order to apply this method, strict constraints on the time-synchronisation between radio antennas in an array must be satisfied. In this contribution, we show that the Auger Engineering Radio Array can meet these timing criteria by operating a time reference beacon. We will show how this enables us to reconstruct air shower properties using the radio interferometric technique.
Keywords: ultra-high energy cosmic rays, Pierre Auger Observatory, Auger engineering radio array, radio interferometry
Published in RUNG: 23.01.2024; Views: 342; Downloads: 4
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3. Long-term calibration and stability of the Auger Engineering Radio Array using the diffuse Galactic radio emissionR. M. de Almeida, Andrej Filipčič, Jonathan Paul Lundquist, Shima Ujjani Shivashankara, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, 2023, published scientific conference contribution Abstract: The Auger Engineering Radio Array (AERA), part of the Pierre Auger Observatory, is currently the largest facility to measure radio emissions from ultra-high energy extensive air showers. It comprises 153 autonomous radio-detector stations, covering an area of 17 km^2, and measures radio waves in the frequency range from 30 to 80 MHz. An accurate description of the detector response is necessary to interpret the data collected by the stations correctly. Previously, this was achieved by measuring the analog chain in the laboratory and simulating and measuring the directional response of the antenna. In this work, we perform an absolute calibration using the continuously monitored sidereal modulation of the diffuse Galactic radio emission. The calibration is performed by comparing the average spectra recorded by the stations with a model of the full radio sky propagated through the system response, including the antenna, filters, and amplifiers. We describe the method to determine the calibration constants for each antenna and present the corresponding results. Furthermore, the behavior of the calibration constants is studied as a function of time. There is no relevant aging effect over a timescale of a decade, which shows that radio detectors could help monitor possible aging effects of other detector systems during
long-term operations, stressing their importance in determining an absolute energy scale.
Keywords: pierre auger observatory, auger engineering radio array, ultra-high energy cosmic rays, radio detectors
Published in RUNG: 22.01.2024; Views: 420; Downloads: 6
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5. Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineeringAbdul Khayum Mohammed, Safa Gaber, Jesus Raya, Tina Škorjanc, Nada Elmerhi, Sasi Stephen, Pilar Pena-Sánchez, Felipe Gándara, Steven Hinder, Mark A. Baker, Kyriaki Polychronopoulou, Dinesh Shetty, 2023, original scientific article Abstract: The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated and covalent linkages. Meanwhile, the inter-structural transition between each class of these porous materials is an under-explored research area. However, such altered frameworks are expected to have exciting features compared to their pristine versions. Herein, we have demonstrated a chemical-induction phase-engineering strategy to transform a two dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). The structural phase transition offered in-situ pore size engineering from 1.1 nm to 1.5–2.0 nm. Moreover, the Cu-TpCOFs showed uniform and low percentage-doped (~ 1–1.5%) metal distribution and improved crystallinity, porosity, and stability compared to the parent Cu-Tp MOF. The construction of a framework from another framework with new linkages opens interesting opportunities for phase-engineering.
Keywords: metal organic framework, covalent organic framework, phase engineering, chemical transformation, porous materials
Published in RUNG: 10.11.2023; Views: 703; Downloads: 5
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9. CDR1 composition can affect nanobody recombinant expression yieldsMarco Orlando, Sara Fortuna, Sandra Oloketuyi, Gregor Bajc, Adi Goldenzweig, Ario De Marco, 2021, original scientific article Keywords: nanobodies, in silico engineering, mutagenesis
Published in RUNG: 15.09.2021; Views: 1689; Downloads: 42
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