1. Determination of iron in natural waters using DGT technique coupled to phototermal beam deflection spectroscopyHanna Budasheva, Arne Bratkič, Dorota Korte, Mladen Franko, 2018, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Povzetek najdenega: ...spectroscopy, diffusive gradients in thin-films, iron species, photothermal techniques, natural waters....
Ključne besede: Beam deflection spectroscopy, diffusive gradients in thin-films, iron species, photothermal techniques, natural waters.
Objavljeno: 09.11.2018; Ogledov: 2231; Prenosov: 0
 Polno besedilo (40,53 KB) |
2. Optimization of DGT technique for determination of iron species in natural water and sediments by photothermal beam deflection spectroscopyMladen Franko, Dorota Korte, Arne Bratkič, Hanna Budasheva, 2018, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: ključnih besedah
Povzetek najdenega: ...in thin-film technique, iron redox species, photothermal techniques, natural water, sediments...
Ključne besede: beam deflection spectroscopy, diffusive gradients in thin-film technique, iron redox species, photothermal techniques, natural water, sediments
Objavljeno: 23.11.2018; Ogledov: 2351; Prenosov: 0
Polno besedilo (386,02 KB) |
3. Determination of Dissolved Iron Redox Species in Freshwater Sediment using DGT Technique Coupled to BDSYue Gao, Arne Bratkič, Dorota Korte, Aleksander Kravos, Hanna Budasheva, Mladen Franko, 2019, izvirni znanstveni članek Opis: In this work we have developed a novel method for determination of iron redox species by the use of diffusive gradients in thin-film (DGT) technique coupled to photothermal beam deflection spectroscopy (BDS). The combination of both methods achieved low limit of detection (LOD) of 0.14 μM for Fe (II) ions. The total Fe concentration determined in the Vrtojbica river sediment (Slovenia, Rožna Dolina, 5000 Nova Gorica) was 49.3 μgL–1. The Fe (II) and Fe (III) concentra- tion amounted to 12.8 μgL–1 and 39.9 μgL–1, respectively. Such an approach opens new opportunities for monitoring the content of iron species in natural waters and sediments and provides highly sensitive chemical analysis and an accurate qualitative and quantitative characteristic of the materials under study.
Najdeno v: ključnih besedah
Povzetek najdenega: ...gradients in thin-film (DGT) technique coupled to photothermal beam deflection spectroscopy (BDS). The combination of... ...in thin-film technique, iron redox species, photothermal techniques, sediment...
Ključne besede: Beam deflection spectroscopy, diffusive gradients in thin-film technique, iron redox species, photothermal techniques, sediment
Objavljeno: 26.02.2019; Ogledov: 2318; Prenosov: 85
Polno besedilo (452,58 KB) |
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6. Towards a novel method for iron species determination in Antarctic sea iceHanna Budasheva, Arne Bratkič, Dorota Korte, Mladen Franko, 2021, objavljeni povzetek znanstvenega prispevka na konferenci Opis: Sea-ice borne iron has been found to be an important factor controlling Southern Ocean phytoplankton growth [1]. Knowing the amount and chemical speciation of its labile fraction in sea ice would advance our understanding of the involved processes. Unfortunately, it is rather difficult to perform their measurement because of limited access to the Antarctic. Thus there is a strong need for the development of a quick, simple and reliable technique for determination of iron and its speciation in sea-ice that ensures also low enough limits of detection. Recently, diffusive gradients in thin films (DGT) have been widely used as passive samplers for collecting time-averaged data on the concentrations of transition metals in different media [2]. DGTs are further coupled to an analytical technique that in case of detecting metals in passive sampler films primarily requires their extraction [3], which may potentially lead to changes of the metal specification. In the present study, the beam deflection spectrometry (BDS) is coupled to DGT and used to determine the average concentration of iron in the sea ice samples collected at the Davis Station in the Antarctic. Such a combined technique has been already successfully applied for detecting labile iron species in freshwater sediments [4]. The obtained BDS data were validated by thermal lens spectrometry (TLS) and UV-Vis spectrophotometry (SPEC). The distribution of iron species over a given ice surface area using the DGT-BDS technique revealed total iron concentrations in the range of 0.6 – 5.3 μgL-1, whereas the Fe2+ content was found to be in the range of 0.1 – 1.5 μgL-1. The range taking into account all of the measurement points (5×4), the precision of a single measured point is 0.2 μgL-1. The calculated 24 h-average concentration of total Fe labile species in the ice by using BDS is 2.3 ± 0.5 μgL-1, which coincides with data obtained by SPEC (2.5 ± 0.4 μgL-1) and TLS (2.39 ± 0.02 μgL-1). Our results indicate that it is possible to develop a robust, contamination-resilient detection method for measuring the labile iron species concentration in the sea ice. In opposite to TLS and SPEC, BDS-DGT provides reliable information not only about the speciation of iron but also about their distribution on the ice surface.
Najdeno v: ključnih besedah
Povzetek najdenega: ...spectrometry, diffusive gradients, thin films, iron species, photothermal techniques, Antarctic sea ice...
Ključne besede: beam deflection spectrometry, diffusive gradients, thin films, iron species, photothermal techniques, Antarctic sea ice
Objavljeno: 30.11.2021; Ogledov: 496; Prenosov: 0
Polno besedilo (216,61 KB)
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