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Naslov:Spin and orbital configuration of metal phthalocyanine chains assembled on the Au(110) surface
Avtorji:ID Pierluigi, Gargiani (Avtor)
ID Rossi, Giorgio (Avtor)
ID Biagi, Roberto (Avtor)
ID Corradini, Valdis (Avtor)
ID Pedio, Maddalena (Avtor)
ID Fortuna, Sara (Avtor)
ID Calzolari, Arrigo (Avtor)
ID Fabris, Stefano (Avtor)
ID Cezar, Julio Criginski (Avtor)
ID Brookes, N. B. (Avtor)
ID Betti, Maria Grazia (Avtor)
Datoteke: Gradivo nima datotek, ki so prostodostopne za javnost. Gradivo je morda fizično dosegljivo v knjižnici fakultete, zalogo lahko preverite v COBISS-u. Povezava se odpre v novem oknu
Jezik:Angleški jezik
Vrsta gradiva:Delo ni kategorizirano
Tipologija:1.01 - Izvirni znanstveni članek
Organizacija:UNG - Univerza v Novi Gorici
Opis:The spin and orbital configuration of magnetic metal phthalocyanines (MPcs) deposited on metallic substrates are strongly influenced by the rehybridization of the molecular states with the underlying metal. FePc, CoPc, and CuPc isolated molecules are archetypal systems to investigate the interrelationship between magnetic moments and orbital symmetry after deposition on a metallic substrate. MPcs form long-range ordered chains self-assembled along the reconstructed channels of the Au(110) surface. X-ray magnetic circular dichroism from the L2,3 absorption edges of Fe, Co, and Cu shows that the orbital and spin configuration are strongly modified upon adsorption on the Au(110) surface if the orbitals responsible of the magnetic moment are involved in the interaction process. The magnetic moment for a single layer of molecular chains is completely quenched for the CoPc molecules, fully preserved for the CuPc and reduced for the FePc ones. The modified magnetic configuration is confined to the very interface layer, i.e., to the MPc molecules bound to the metal substrate up to the compact packing of the single layer. The different response can be rationalized in terms of the symmetry/orientation of the metal-ion d states interacting with the substrate states, as indicated by density functional theory calculations in agreement with experimental findings.
Ključne besede:phthalocyanine, Au(110), gold, self-assembly, pattern, configuration, density functional theory, DFT, CuPc, FePc
Leto izida:2013
Št. strani:11
Številčenje:87
PID:20.500.12556/RUNG-2673 Novo okno
COBISS.SI-ID:4540923 Novo okno
DOI:10.1103/PhysRevB.87.165407 Novo okno
NUK URN:URN:SI:UNG:REP:S5XJV6KE
Datum objave v RUNG:12.10.2016
Število ogledov:6108
Število prenosov:0
Metapodatki:XML DC-XML DC-RDF
:
PIERLUIGI, Gargiani, ROSSI, Giorgio, BIAGI, Roberto, CORRADINI, Valdis, PEDIO, Maddalena, FORTUNA, Sara, CALZOLARI, Arrigo, FABRIS, Stefano, CEZAR, Julio Criginski, BROOKES, N. B. in BETTI, Maria Grazia, 2013, Spin and orbital configuration of metal phthalocyanine chains assembled on the Au(110) surface. Physical Review B [na spletu]. 2013. Vol. 87. [Dostopano 7 april 2025]. DOI 10.1103/PhysRevB.87.165407. Pridobljeno s: https://repozitorij.ung.si/IzpisGradiva.php?lang=slv&id=2673
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Gradivo je del revije

Naslov:Physical Review B
Skrajšan naslov:Phys. Rev. B
Založnik:American Physical Society
Leto izida:2013
ISSN:2469-9950

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