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Naslov: SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY Avtorji: ID Bortoluzzi, Marco (Mentor) Več o mentorju... ID Lavrencic Stangar, Urska (Mentor) Več o mentorju... ID Segato, Jacopo (Avtor) Datoteke: Jacopo_Segato.pdf (4,17 MB) MD5: 3E2A420C0CA71A0A185A5022A90811C9   Jezik: Angleški jezik Vrsta gradiva: Magistrsko delo/naloga Tipologija: 2.09 - Magistrsko delo Organizacija: FZO - Fakulteta za znanosti o okolju Opis: The thesis describes the synthesis of novel yttrium(III), europium(III) and ytterbium(III) complexes with polydentate ligands containing the ferrocenyl moiety. In particular, a chelating beta-diketonate ligand having formula [FcCOCHCOCH3]- has been used for the preparation of homo- and heteroleptic complexes, these last having N-donor ligands such as 1,10-phenanthroline or tris(3,5-dimethylpyrazol-1-yl)borate in their coordination sphere. Further complexes were obtained by reacting bis(diphenylphosphino)ferrocene dioxide with proper Group 3 and lanthanide precursors, having nitromalonaldehyde or bromomalonaldehyde as supporting ligands. In all the cases, the characterizations were corroborated by electrochemical measurements and diffusion spectroscopy. Reversible or quasi-reversible one-electron oxidation of the ferrocenyl moiety was detected for the new complexes, even if the corresponding ferricinium-based compounds resulted quite strong oxidants. Ključne besede: lanthanides, ferrocene, heteropolymetallic complexes, beta-diketonate, cyclovoltammetry Kraj izida: Nova Gorica Leto izida: 2016 PID: 20.500.12556/RUNG-2832-aeb3f4c1-bcc6-905a-52d1-306781ec28f4  COBISS.SI-ID: 4611067  NUK URN: URN:SI:UNG:REP:LWRYRNHT Datum objave v RUNG: 16.12.2016 Število ogledov: 7501 Število prenosov: 351 Metapodatki:    Citiraj gradivo Navadno besedilo BibTeX EndNote XML EndNote/Refer RIS ABNT ACM Ref AMA APA Chicago 17th Author-Date Harvard IEEE ISO 690 MLA Vancouver : SEGATO, Jacopo, 2016, SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY [na spletu]. Magistrsko delo. Nova Gorica. [Dostopano 31 marec 2025]. Pridobljeno s: https://repozitorij.ung.si/IzpisGradiva.php?lang=slv&id=2832 Kopiraj citat

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