Repozitorij Univerze v Novi Gorici

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Naslov:SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY
Avtorji:Segato, Jacopo (Avtor)
Lavrencic Stangar, Urska (Mentor) Več o mentorju... Novo okno
Bortoluzzi, Marco (Mentor) Več o mentorju... Novo okno
Datoteke:.pdf Jacopo_Segato.pdf (4,17 MB)
 
Jezik:Angleški jezik
Vrsta gradiva:Magistrsko delo/naloga (mb22)
Tipologija:2.09 - Magistrsko delo
Organizacija:FZO - Fakulteta za znanosti o okolju
Opis:The thesis describes the synthesis of novel yttrium(III), europium(III) and ytterbium(III) complexes with polydentate ligands containing the ferrocenyl moiety. In particular, a chelating beta-diketonate ligand having formula [FcCOCHCOCH3]- has been used for the preparation of homo- and heteroleptic complexes, these last having N-donor ligands such as 1,10-phenanthroline or tris(3,5-dimethylpyrazol-1-yl)borate in their coordination sphere. Further complexes were obtained by reacting bis(diphenylphosphino)ferrocene dioxide with proper Group 3 and lanthanide precursors, having nitromalonaldehyde or bromomalonaldehyde as supporting ligands. In all the cases, the characterizations were corroborated by electrochemical measurements and diffusion spectroscopy. Reversible or quasi-reversible one-electron oxidation of the ferrocenyl moiety was detected for the new complexes, even if the corresponding ferricinium-based compounds resulted quite strong oxidants.
Ključne besede:lanthanides, ferrocene, heteropolymetallic complexes, beta-diketonate, cyclovoltammetry
Leto izida:2016
Izvor:Nova Gorica
COBISS_ID:4611067 Povezava se odpre v novem oknu
URN:URN:SI:UNG:REP:LWRYRNHT
Število ogledov:749
Število prenosov:46
Metapodatki:XML RDF-CHPDL DC-XML DC-RDF
Področja:Gradivo ni uvrščeno v področja.
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Skupna ocena:(0 glasov)
Vaša ocena:Ocenjevanje je dovoljeno samo prijavljenim uporabnikom.

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