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Title:Determination of Trace Cr(VI) with Diphenylcarbazide by μFIA–Thermal Lens Microscopy
Authors:Gor’kova, Tatyana (Author)
Proskurnina, Michail (Author)
Liu, Mingqiang (Author)
Franko, Mladen (Author)
Files:This document has no files. This document may have a phisical copy in the library of the organization, check the status via COBISS. Link is opened in a new window
Work type:Not categorized (r6)
Tipology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:The optimum reaction parameters for the interaction of hexavalent chromium [Cr(VI)] with diphenylcarbazide in microfluidic chips (μFIA) with thermal-lens microscopic detection were selected. The characteristic feature of the applied flow scheme is the injection of the reagent into the stream containing the test metal, which enables in-field and real-time monitoring of Cr(VI) simply by flowing the sample continuously through the microchip. The limit of detection of Cr(VI) under the selected conditions (signal generating wavelength, 514.5 nm; excitation power, 100 mW; detection position, 10 cm downstream from the mixing zone of the microchip; flow rate 10 μL min–1; injection volume, 1.4 μL) is 15 ng mL–1 (2.9 × 10–7 mol L–1). The linear range is 40 ng mL–1 – 10 μg mL–1 with a relative standard deviation no higher than 10% in the concentration range 0.1–1 μg mL–1. The online monitoring by this scheme provides the possibility of up to 360 analyses per hour.
Keywords:Photothermal lensing, thermal-lens microscopic detection, microfluidic applications, μFIA, hexavalent chromium, diphenylcarbazide
Year of publishing:2016
Number of pages:772-780
COBISS_ID:4602875 Link is opened in a new window
DOI:10.17344/acsi.2016.2549 Link is opened in a new window
License:CC BY-NC-ND 4.0
This work is available under this license: Creative Commons Attribution Non-Commercial No Derivatives 4.0 International
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Record is a part of a journal

Title:Acta Chimica Slovenica
Shortened title:Acta Chim. Slov.
Publisher:Slovenian Chemical Society
Year of publishing:2016

Secondary language

Title:Določevanje sledov Cr(VI) z difenilkarbazidom in μFIA–TLS mikroskopijo
Abstract:Za dolo~anje {estvalentnega kroma [Cr(VI)] s preto~no injekcijsko analizo v mikrofluidnem sistemu (μFIA) in detekcijo z mikroskopijo na osnovi toplotnih le~, smo izbrali optimalne reakcijske pogoje za interakcijo Cr(VI) s kolorimetri~nim reagentom difenilkarbazidom. Glavna zna~ilnost uporabljenega preto~nega sistema je injiciranje reagenta v nosilni tok, ki vsebuje analit. To, ob stalnem pretoku vzorca skozi mikro~ip, v praksi omogo~a kontinuirni monitoring Cr(VI) v realnem ~asu. Pri izbranih pogojih (vzbujevalna valovna dol`ina 514,5 nm, mo~ vzbujanja 100 mW, to~ka detekcije 10 cm po to~ki me{anja, pretok 10 μL min–1, injicirani volumen 1,4 μL) smo dosegli mejo zaznave 15 ng mL–1 (2,9 × 10–7 mol L–1). Pri tem je bilo obmo~je linearnosti 40 ng mL–1 – 10 μg mL–1, relativni standardni odmik v koncentracijskem obmo~ju 0.1–1 μg mL–1 pa manj{i od 10 %. Opisani sistem omogo~a kontinuirno merjenje koncentracije Cr(VI) s 360 analizami na uro.