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Title:Molecular alignment on graphene surface determines transport properties of graphene/organic semiconductor transistors
Authors:Tkachuk, Vadym (Author)
Pavlica, Egon (Author)
Bratina, Gvido (Author)
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Language:English
Work type:Not categorized (r6)
Tipology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:Graphene field-effect transistor structures were used to investigate the role of molecular alignment on charge transport properties of heterostructures comprising a single-layer graphene and variable thickness of N,N′-bis(n-octyl)-(1,7&1,6)-dicyanoperylene-3,4:9,10-bisdicarboximide (PDI8-CN2) - an n-type organic semiconductor. Our atomic force microscopy data show that under selected growth conditions PDI8-CN2 grows in a layer-by-layer fashion up to a second monolayer. The first layer comprises flat-lying molecules, whereas the molecules in the second layer orient themselves in an upright orientation. Transconductance measurements show that the flat-lying molecules have little effect on the position of the Fermi level in graphene. Upright oriented molecules in the second layer instead, have a strong effect as to neutralize native p-type doping of graphene and cause a shift of charge-neutrality level towards the Dirac point. We interpret such behavior in terms of different orientation of the surface dipole on layers with different molecular orientations. At the same time the overall mobility of the charge carriers reaches values exceeding 3000 cm2/Vs.
Keywords:organski polprevodniki, grafen, transport električnega naboja
Year of publishing:2020
Number of pages:7
Numbering:105933, 87
COBISS_ID:32240131  Link is opened in a new window
URN:URN:SI:UNG:REP:RPMDSL39
DOI:10.1016/j.orgel.2020.105933 Link is opened in a new window
License:CC BY-NC-ND 4.0
This work is available under this license: Creative Commons Attribution Non-Commercial No Derivatives 4.0 International
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Title:Organic Electronics
Year of publishing:2020

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