20.500.12556/RUNG-7912
Electrocatalytic Hydrogen Evolution with Transition Metal Based Compounds
abstract
Electrocatalytic water splitting is one of the cleanest and sustainable way to generate hydrogen. Transition metal based electrocatalysts like iron phosphides (Fe2P, FeP), molybdenum diselenides (MoSe2), and tungsten carbides (W2C, WC) have unique advantages including competitive cost compared to platinum, controllable active sites, and electronic structures that could significantly enhance the hydrogen evolution reaction (HER). Here, we present a combination of approaches for preparing catalyst materials. As an elegant technique, colloidal synthesis was used to synthesize Mo and W nanoparticles. Combined with selenization and carbidation approaches at elevated temperature, it allowed to synthesize MoSe2, W2C, and WC thin films. The syntheses of Fe2P and FeP catalyst were achieved in one-stage using triphenylphosphine precursor. The obtained catalysts were applied in electrocatalytic HER studies.
iron phosphides
molybdenum diselenide
tungtsen carbides
electrocatalysis
hydrogen evolution
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Angleški jezik
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2023-02-05 16:07:21
2023-02-06 13:07:56
2023-06-10 03:03:16
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2021
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2021
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140820227
URN:SI:UNG:REP:MJIEFFRO
Univerza v Novi Gorici
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