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Covalent organic frameworks for fluorescent imaging of hypoxia
Tina Škorjanc, Dinesh Shetty, Gregor Mali, Damjan Makuc, Martina Bergant Marušič, Matjaž Valant, 2023, published scientific conference contribution abstract

Keywords: hypoxia, covalent organic frameworks, imaging, fluorescence, post-synthetic modification
Published in RUNG: 06.06.2023; Views: 2695; Downloads: 4
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13.
Structural disorder of AlMg-oxide phase supporting Cu/ZnO catalyst improves efficiency and selectivity for ▫$CO_2$▫ hydrogenation to methanol
Andraž Mavrič, Gregor Žerjav, Blaž Belec, Matevž Roškarič, Matjaž Finšgar, Albin Pintar, Matjaž Valant, 2023, original scientific article

Abstract: The performance of the Cu/ZnO catalyst system with the AlMg-oxide phase is studied for CO2 hydrogenation to methanol. The catalyst is prepared by thermal treatment of the hydrotalcite phase containing intimately mixed metal cations in the hydroxide form. CuO in the presence of ZnO and disordered AlMg-oxide phase gets easily reduced to Cu during the hydrogenation reaction. Its catalytic activity at relatively low Cu metal content (∼14 at.%) remains stable during 100 hours on stream at 260 °C with constant space-time yield for methanol (∼1.8 gMeOH gcat−1 h−1) and high methanol selectivity (>85 %) The improved performance is attributed to the neutralization of surface acidity, increased number of weak basic sites in the disordered phase, and lower tendency for coke formation.
Keywords: carbon dioxide hydrogenation, heterogenous catalysis, methanol, reducibility
Published in RUNG: 02.06.2023; Views: 2401; Downloads: 23
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A comparative study of nanolaminate CrN/Mo2N and CrN/W2N as hard and corrosion resistant coatings
Marco Beltrami, Andraž Mavrič, Simone Dal Zilio, Mattia Fanetti, Gregor Kapun, Marco Lazzarino, Orfeo Sbaizero, Miha Čekada, 2013, original scientific article

Abstract: Nanolaminate coatings (NLC) consisting of alternated CrN coupled with either cubic tungsten nitride (β-W2N) or molybdenum nitride (γ-Mo2N) were deposited on cold worked tool steel substrates using reactive DC reactive magnetron sputtering for improved mechanical and corrosion resistance. The CrN/γ-Mo2N and CrN/β-W2N nanolaminate systems were found to perform better than the corresponding single-layer systems, with both mechanical and electrochemical properties improving by decreasing the individual layer thickness from 100 to 5 nm. The CrN/β-W2N NLC combined the high hardness value of W2N with the low corrosion current of CrN. The CrN/γ-Mo2N NLC showed synergistic improvements consisting of both higher hardness and lower corrosion currents with respect to the constituent materials alone. The dependence of mechanical and corrosion properties on the bilayer period is discussed in terms of the grain size, residual stresses and texture of the constituent materials and the nanostructured character of the multilayer architecture.
Keywords: Nanolayered coatings, Transition metal nitrides, Sputtering, Nanoindentation, Corrosion resistance, Mechanical properties
Published in RUNG: 12.01.2023; Views: 2528; Downloads: 0
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Covalent polymer thin films for biosensor applications
Tina Skorjanc, Andraž Mavrič, Mads Nybo Sorensen, Gregor Mali, Changzhu Wu, Matjaž Valant, 2022, published scientific conference contribution abstract

Keywords: bacteria, sensing, electrochemical impedance spectroscopy, electrophoresis, electrode preparation, Menshutkin reaction
Published in RUNG: 26.09.2022; Views: 2646; Downloads: 0
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