Repository of University of Nova Gorica

Search the repository
A+ | A- | Help | SLO | ENG

Query: search in
search in
search in
search in
* old and bologna study programme

Options:
  Reset


1 - 2 / 2
First pagePrevious page1Next pageLast page
1.
Photoelectrochemical conversion of biomass alcohols using in-situ Sn-doped ▫$\alpha-Fe_2O_3$▫ thin films
Manel Machreki, Artem Badasyan, Dušan Žigon, Georgi Tyuliev, Saim Emin, 2025, original scientific article

Abstract: Transformation of biomass into value-added chemicals and fuels is considered an upcycling process that is beneficial to resource utilization. In this study, we used a photoelectrochemical (PEC) approach for selective oxidation of propane-1,2,3-triol to dihydroxyacetone (DHA) with high efficiency and selectivity (99%) using Sn-doped -Fe2O3 (Sn:-Fe2O3) thin films with intrinsic oxygen vacancies (OVs). DHA is an essential compound utilized in the cosmetic industry. In a similar manner, we conducted the first study of the PEC oxidation of 4-hydroxy-3-methoxybenzyl alcohol under visible light. A kinetic model has been formulated and solved to find the time-dependent generation of the products. Electrochemical impedance analyses and PEC experiments demonstrated a correlation between the concentration of molecules and the catalytic performance of Sn:-Fe2O3. Studies using scavengers indicate that the photogenerated holes (h+), singlet oxygen (1O2), hydroxyl radicals (•OH), and superoxide radicals (•O2–) play key roles in achieving high PEC activity. This work provided a new perspective on designing efficient PEC systems for biomass conversion into energy and value-added chemicals.
Keywords: Sn-doped alpha-Fe2O3, oxygen vacancies, photoelectrochemical oxidation, propane-1, 2, 3-triol, 4-hydroxy-3-methoxybenzyl alcohol
Published in RUNG: 08.01.2025; Views: 204; Downloads: 3
URL Link to file
This document has many files! More...

2.
Disinfection of wastewater using porous Fe2O3 thin film : master's thesis
Ranin M. D. Ismail, 2024, master's thesis

Abstract: The contamination of water bodies by microorganisms is seen as a highly significant issue that poses a threat to human and animal well-being. The primary objective of this master thesis is to develop and evaluate an environmentally friendly photoelectrochemical (PEC) method using porous Fe₂O₃ thin films for the disinfection of wastewater. This thesis presents the novel application of porous Fe₂O₃ thin films, which were produced using a cost-effective spin-coating technique, to improve the process of PEC disinfection. The PEC approach has been demonstrated to be highly effective in disinfection of wastewaters deliberately contaminated with E. coli bacteria. The crystallinity of the Fe₂O₃ porous thin films was confirmed using X-ray diffraction (XRD), while the film morphology was studied using scanning electron microscopy (SEM). The PEC disinfection procedures were conducted in the presence of two separate electrolytes, sodium sulfite (Na₂SO₃) and sodium chloride (NaCl), which were chosen for their specific roles in improving the effectiveness of disinfection. The PEC method shown efficacy in inactivating E. coli, with 45% of the bacteria being inactivated in the presence of 2 mM Na₂SO₃ and complete inactivation achieved with 20 mM NaCl. The findings suggest that the PEC disinfection process is a highly efficient and eco-friendly technology that can be used as a practical substitute for traditional disinfection methods. As a result, it has potential applications in ensuring public safety and safeguarding the environment, particularly in relation to wastewater treatment.
Keywords: Treated wastewater, Disinfection, Escherichia coli, Photoelectrochemical oxidation, Fe2O3 thin films, Sodium sulfite and Sodium chloride.
Published in RUNG: 09.09.2024; Views: 1073; Downloads: 16
.pdf Full text (2,23 MB)
Search done in 0.01 sec.
Back to top