1. Light-Assisted Catalysis and the Dynamic Nature of Surface Species in the Reverse Water Gas Shift Reaction over Cu/γ-Al2O3Kristijan Lorber, Iztok Arčon, Matej Huš, Janez Zavašnik, Jordi Sancho-Parramon, Anže Prašnikar, Blaž Likozar, Nataša Novak Tušar, Petar Djinović, original scientific article Abstract: The reverse water gas shift (RWGS) reaction converts CO2 and H2 into CO and water. We investigated Cu/γ-Al2O3 catalysts in both thermally driven and light-assisted RWGS reactions using visible light. When driven by combined visible light and thermal energy, the CO2 conversion rates were lower than in the dark. Light-assisted reactions showed an increase in the apparent activation energy from 68 to 87 kJ/mol, indicating that light disrupts the energetically favorable pathway active in the dark. A linear correlation between irradiance and decreasing reaction rate suggests a photon-driven phenomenon. In situ diffuse reflectance infrared Fourier transform spectroscopy and TD-DFT analyses revealed that catalyst illumination causes significant, partly irreversible surface dehydroxylation, highlighting the importance of OH groups in the most favorable RWGS pathway. This study offers a novel approach to manipulate surface species and control activity in the RWGS reaction.
Keywords: light-assisted catalysis, reaction mechanism, in situ spectroscopy, hydroxyl, copper, RWGS
Published in RUNG: 07.01.2025; Views: 632; Downloads: 6
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2. Tailoring the thermal diffusivity of polyvinylidene fluoride via carbon source integration : a photothermal beam deflection studyMohanachandran Nair Sindhu Swapna, Dorota Korte, Sankaranarayana Iyer Sankararaman, 2023, original scientific article Keywords: cellulose, camphor soot, lignin, PVDF, photothermal techniques, beam deflection, hydroxyl groups
Published in RUNG: 21.08.2023; Views: 2427; Downloads: 19
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3. The role of hydroxyl ions in the evolution of optical nonlinearity of CuO : a Z scan studyRiya Sebastian, Mohanachandran Nair Sindhu Swapna, H. V. Saritha Devi, Vimal Raj, Misha Hari, Sankaranarayana Iyer Sankararaman, 2019, original scientific article Keywords: hydroxyl ions, optical nonlinearity, Z scan, copper oxide
Published in RUNG: 05.07.2022; Views: 2242; Downloads: 65
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4. Laser-induced thermal lens study of the role of morphology and hydroxyl group in the evolution of thermal diffusivity of copper oxideRiya Sebastian, Mohanachandran Nair Sindhu Swapna, Vimal Raj, Sankaranarayana Iyer Sankararaman, 2022, original scientific article Abstract: The paper explores the evolution of thermal behavior of the material by studying the variations in thermal diffusivity
using the single beam thermal lens (TL) technique. For this purpose, the decomposition of Cu(OH)2 into CuO is studied in a
time range up to 120 h, by subjecting the sample to morphological, structural, and spectroscopic characterizations. The time
evolution of thermal diffusivity can be divided into three regions for demonstrating the dynamics of the reaction. When the
reaction is complete, the thermal diffusivity is also found to be saturated. In addition to the morphological modifications,
from rods to flakes, the variations in the amount of hydroxyl group are attributed to be responsible for the enhancement
of base fluid’s thermal diffusivity by 165%. Thus the study unveils the role of hydroxyl groups in the thermal behavior of
CuO.
Keywords: thermal diffusivity, CuO, thermal lens, morphology, hydroxyl group
Published in RUNG: 04.07.2022; Views: 2505; Downloads: 0
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5. What effect does VOC sampling time have on derived OH reactivity?Hannah Sonderfeld, Iain R. White, Iain C A Goodall, James R Hopkins, Alistair C Lewis, Ralf Koppmann, Paul S Monks, 2016, original scientific article Abstract: State-of-the-art techniques allow for rapid measurements of total OH reactivity. Unknown sinks of OH and oxidation processes in the atmosphere have been attributed to what has been termed ĝ€missingĝ€ OH reactivity. Often overlooked are the differences in timescales over which the diverse measurement techniques operate. Volatile organic compounds (VOCs) acting as sinks of OH are often measured by gas chromatography (GC) methods which provide low-frequency measurements on a timescale of hours, while sampling times are generally only a few minutes. Here, the effect of the sampling time and thus the contribution of unmeasured VOC variability on OH reactivity is investigated. Measurements of VOC mixing ratios by proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) conducted during two field campaigns (ClearfLo and PARADE) in an urban and a semi-rural environment were used to calculate OH reactivity. VOCs were selected to represent variability for different compound classes. Data were averaged over different time intervals to simulate lower time resolutions and were then compared to the mean hourly OH reactivity. The results show deviations in the range of 1 to 25%. The observed impact of VOC variability is found to be greater for the semi-rural site.The selected compounds were scaled by the contribution of their compound class to the total OH reactivity from VOCs based on concurrent gas chromatography measurements conducted during the ClearfLo campaign. Prior to being scaled, the variable signal of aromatic compounds results in larger deviations in OH reactivity for short sampling intervals compared to oxygenated VOCs (OVOCs). However, once scaled with their lower share during the ClearfLo campaign, this effect was reduced. No seasonal effect on the OH reactivity distribution across different VOCs was observed at the urban site.
Keywords: Hydroxyl radical, Atmospheric chemistry, Box model
Published in RUNG: 18.07.2019; Views: 3989; Downloads: 0 |
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