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81.
82.
Trace Detection and Photothermal Spectral Characterization by a Tuneable Thermal Lens Spectrometer with White-Light Excitation
Humberto Cabrera, Dorota Korte, Mladen Franko, 2018, izvirni znanstveni članek

Opis: In the thermal lens experimental set-up we replaced the commonly employed pump laser by a halogen lamp, combined with an interference lter, providing a tuneable, nearly monochromatic pump source over the range of wavelengths 430–710 nm. Counter-propagating pump and probe beams are used and a 1 mm path-length sam- ple cell together with the interference lter makes an optical cavity, providing ampli cation of the thermal lens signal, which leads to enhancement of the measurement sensitivity, and enables detection of absorbances on the order of 5×10− 6. Ampli ed thermal lens signal allows us to replace the typical lock-in ampli er and digital os- cilloscope with a silicon photodetector, Arduino board, and a personal computer, offering the possibility for a compact, robust and portable device, useful for in- eld absorption measurements in low concentration or weakly absorbing species. The use of a white light source for optical pumping, an interference lter for wavelength selection and direct diagnostic of the thermal lens signal increase the versatility of the instrument and simpli- es substantially the experimental setup. Determination of Fe(II) concentrations at parts per billion levels was performed by the described white-light thermal lens spectrophotometer and the absorption spectrum for 50μg/ L Fe(II)-1,10-phenanthroline was well reproduced with an average measurement precision of 4%. The obtained limits of detection and quantitation of Fe(II) determination at 510nm are 3μgL− 1 and 11μgL− 1, respectively. The calibration curve was linear in the concentration range of LOQ-500μgL− 1 with reproducibility between 2% and 6%, con rming that this instrument provides good spectrometric capabilities such as high sensitivity, tune- ability and good reproducibility. In addition, the versatility of the instrument was demonstrated by recording the photothermal spectrum of gold nanostructured material and determination of excitation wavelength with most ef cient optical to thermal energy conversion, which differs considerably (cca 100 nm) from the absorption maximum of the investigated sample.
Ključne besede: thermal lens spectrometry, Fe(II) determination, photothermal technique, multi-wavelength excitation
Objavljeno v RUNG: 21.02.2018; Ogledov: 4033; Prenosov: 0
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83.
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85.
DETERMINATION OF Fe2+ IN LIQUID SAMPLES BY THE USE OF AMPLIEFIED THERMAL LENS SPECTROMETRY
Humberto Cabrera, Dorota Korte, Leja Goljat, Mladen Franko, 2017, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: AMPLIEFIED THERMAL LENS SPECTROMETRY, Fe2+
Objavljeno v RUNG: 30.08.2017; Ogledov: 4294; Prenosov: 0
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86.
PHOTOTHERMAL-DEFLECTION SPECTROSCOPY FOR THE DETERMINATION OF THERMAL DIFFUSIVITY OF SOILS AND SOIL AGGREGATES
Mikhail A. Proskurnin, Dorota Korte, O.B. Rogova, D.S. Volkov, Mladen Franko, 2017, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: PHOTOTHERMAL-DEFLECTION SPECTROSCOPY, THERMAL DIFFUSIVITY, soil, soil aggregates
Objavljeno v RUNG: 30.08.2017; Ogledov: 3963; Prenosov: 0
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87.
The comparison of anthocyanin and pyranoanthocyanin extraction efficiency in Pinot Noir wine using SPE
Jelena Topic, Dorota Korte, Branka Mozetič Vodopivec, 2017, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: Anthocyanins, wine, Pinot Noir, HPLC, solid-phase extraction
Objavljeno v RUNG: 05.07.2017; Ogledov: 5230; Prenosov: 0
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88.
Experimental sessions: Thermal lens microscopy
Dorota Korte, Muhammad Sulaiman Yousafzai, prispevek na konferenci brez natisa

Ključne besede: Thermal lens microscopy, photothermal effect
Objavljeno v RUNG: 14.03.2017; Ogledov: 5398; Prenosov: 0
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89.
Experimental sessions: digital lock-in photothermal shadowgraph method
Dorota Korte, Angel Cifuentes, vabljeno predavanje na konferenci brez natisa

Ključne besede: Photothermal beam deflection technique, photothermal shadowgraph method
Objavljeno v RUNG: 13.03.2017; Ogledov: 4545; Prenosov: 0
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90.
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