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Synthesis of helional by hydrodechlorination reaction in the presence of mono- and bimetallic catalysts supported on aluminaOreste Piccolo,
Iztok Arčon,
Das Gangadhar,
Giuliana Aquilanti,
Andrea Prai,
Stefano Paganelli,
Manuela Facchin,
Valentina Beghetto, 2024, izvirni znanstveni članek
Opis: Hydrodechlorination reaction of 3-(benzo-1,3-dioxol-5-yl)-3-chloro-2-methylacrylaldehyde in the presence of different low metal content heterogeneous mono- or bimetallic catalysts was tested for the synthesis of the fragrance Helional® (3-[3,4-methylendioxyphenyl]-2-methyl-propionaldehyde). In particular, mono Pd/Al2O3, Rh/Al2O3 or bimetallic Pd-Cu/Al2O3, Rh-Cu/Al2O3 catalysts were tested in different reaction conditions from which it emerged that mono-Rh/Al2O3 was the best performing catalyst, allowing achievement of 100% substrate conversion and 99% selectivity towards Helional® in 24 h at 80 °C, p(H2) 1.0 MPa in the presence of a base. To establish correlations between atomic structure and catalytic activity, catalysts were characterized by Cu, Rh and Pd K-edge XANES, EXAFS analysis. These characterizations allowed verification that the formation of Pd-Cu alloys and the presence of Cu oxide/hydroxide species on the surface of the Al2O3 support are responsible for the very low catalytic efficiency of bimetallic species tested.
Ključne besede: selective hydrodechlorination, heterogeneous catalysis, XANES analysis, EXAFS analysis
Objavljeno v RUNG: 25.04.2024; Ogledov: 206; Prenosov: 4
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