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91.
Fractal and time-series analyses based rhonchi and bronchial auscultation: A machine learning approach
Mohanachandran Nair Sindhu Swapna, 2022, izvirni znanstveni članek

Opis: Objectives: The present work reports the study of 34 rhonchi (RB) and Bronchial Breath (BB) signals employing machine learning techniques, timefrequency, fractal, and non-linear time-series analyses. Methods: The timefrequency analyses and the complexity in the dynamics of airflow in BB and RB are studied using both Power Spectral Density (PSD) features and non-linear measures. For accurate prediction of these signals, PSD and nonlinear measures are fed as input attributes to various machine learning models. Findings: The spectral analyses reveal fewer, low-intensity frequency components along with its overtones in the intermittent and rapidly damping RB signal. The complexity in the dynamics of airflow in BB and RB is investigated through the fractal dimension, Hurst exponent, phase portrait, maximal Lyapunov exponent, and sample entropy values. The greater value of entropy for the RB signal provides an insight into the internal morphology of the airways containing mucous and other obstructions. The Principal Component Analysis (PCA) employs PSD features, and Linear Discriminant Analysis (LDA) along with Pattern Recognition Neural Network (PRNN) uses non-linear measures for predicting BB and RB. Signal classification based on phase portrait features evaluates the multidimensional aspects of signal intensities, whereas that based on PSD features considers mere signal intensities. The principal components in PCA cover about 86.5% of the overall variance of the data class, successfully distinguishing BB and RB signals. LDA and PRNN that use nonlinear time-series parameters identify and predict RB and BB signals with 100% accuracy, sensitivity, specificity, and precision. Novelty: The study divulges the potential of non-linear measures and PSD features in classifying these signals enabling its application to be extended for low-cost, non-invasive COVID-19 detection and real-time health monitoring.
Ključne besede: lung signal, fractal analysis, sample entropy, non­linear time­series, machine learning techniques
Objavljeno v RUNG: 30.06.2022; Ogledov: 1279; Prenosov: 0
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92.
Fractal and inertia moment analyses for thin film quality monitoring
Mohanachandran Nair Sindhu Swapna, 2022, izvirni znanstveni članek

Opis: The widespread applications of thin films in optronics demand innovative techniques for its characterizations. The work reported here proposes electronic speckle pattern interferometry and fractal-based methods for assessing the quality of thin films taking the industrially relevant molybdenum oxide (MoO3) incorporated niobium oxide (Nb2O5) films. The films with different levels of MoO3 incorporation (1, 2, 3, 5, and 10 wt. %) are prepared by radio frequency sputtering. The study reveals the structure modifications of Nb2O5 from the orthorhombic to monoclinic phases with an associated morphological variation revealed through atomic force microscopy and field-emission scanning electron microscopy analyses. The films’ specklegrams are recorded under thermal stress; the inertia moment (IM) and fractal analyses are computed and compared with the root-mean-square surface roughness of the films. The lacunarity analysis of the AFM films agrees well with the specklegrams. Thus, the lower IM and lacunarity values of the specklegrams can be regarded as indicators of the good quality of thin films.
Ključne besede: cross-correlation, fractal dimension, inertia moment, lacunarity, speckle, surface roughness.
Objavljeno v RUNG: 30.06.2022; Ogledov: 1168; Prenosov: 0
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93.
Fluorescent emission from a natural carbon matrix incorporating sodium
Mohanachandran Nair Sindhu Swapna, 2019, izvirni znanstveni članek

Opis: The process of functionalization of metals in natural carbon matrices has become an important area of research due to its improved properties and applications. Carbon materials possessing photoluminescence (PL) properties find a wide range of applications in photonics. Among the various carbon materials available in nature, cellulose has critical importance since it is the most abundant and wide-spread biopolymer on Earth, and also, the important component in plants’ skeleton. In the present work, the functionalized carbonaceous material is prepared by the hydrothermal treatment of natural cellulosic source Aloe Vera and the metallic element sodium is properly incorporated into it by adding sodium borohydride to observe the fluorescence emission changes. The incorporation of metal ions in the carbon matrix leads to structural modifications and properties as evidenced by field emission scanning electron microscopy, Energy dispersive spectroscopy, X-ray dot mapping, X-ray Photoelectron spectroscopy, and X-ray diffraction analysis. The optical emission characteristics are studied using Photoluminescence spectroscopy, CIE plot, power spectrum, color purity, and quantum yield. The excitation wavelength dependent photoluminescence emission mechanism shown by the carbon–metal incorporated products obtained from the cellulosic raw materials makes them suitable for biomedical and biosensing applications because of the non-toxic and eco-friendly nature.
Ključne besede: Fluorescent emission, sodium carbide, cellulose, carbon matrix
Objavljeno v RUNG: 30.06.2022; Ogledov: 1097; Prenosov: 0
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94.
Pharmacological application of thermal Lens technique - A thermal diffusivity study
Mohanachandran Nair Sindhu Swapna, 2018, izvirni znanstveni članek

Opis: The photothermal phenomenon has emerged as a potential tool for the nondestructive evaluation of thermal and optical properties of materials. Thermal analysis of drugs is an unavoidable part of preformulation study, as temperature variations can induce structural changes of the constituents of drugs. Techniques based on photothermal phenomena are highly sensitive, as only the absorbed radiation contributes to the signal. Periodic illumination and subsequent nonradiative de-excitation generate thermal lens signals of various types within and around the sample. Variation of thermal diffusivity with a concentration of the commonly used drug terbutaline is studied through the single-beam thermal lens technique. The ultraviolet–visible spectrum of the drug shows strong absorption around 500 nm, which suggests the possible wavelengths that can be used for the study. It is found that concentration of the drug in liquid form decides its thermal stability, as its thermal diffusivity varies with concentration. The study gives information about the optimum value for the concentration of the drug noted above for which the chance of thermal stability is high.
Ključne besede: thermal lens, thermal diffusivity, pharmacology, drug
Objavljeno v RUNG: 30.06.2022; Ogledov: 1067; Prenosov: 0
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95.
Fractal and spectroscopic analysis of soot from internal combustion engines
Mohanachandran Nair Sindhu Swapna, SARITHA DEVI H V, RAJ VIMAL, Sankararaman S, 2018, izvirni znanstveni članek

Opis: Today diesel engines are used worldwide for various applications and very importantly in transportation. Hydrocarbons are the most widespread precursors among carbon sources employed in the production of carbon nanotubes (CNTs). The aging of internal combustion engine is an important parameter in deciding the carbon emission and particulate matter due to incomplete combustion of fuel. In the present work, an attempt has been made for the effective utilization of the aged engines for potential applicationapplications in fuel cells and nanoelectronics. To analyze the impact of aging, the particulate matter rich in carbon content areis collected from diesel engines of different ages. The soot with CNTs is purified by the liquid phase oxidation method and analyzed by Field Emission Scanning Electron Microscopy, High-Resolution Transmission Electron Microscopy, Energy Dispersive Spectroscopy, UV-Visible spectroscopy, Raman spectroscopy and Thermogravimetric analysis. The SEM image contains self-similar patterns probing fractal analysis. The fractal dimensions of the samples are determined by the box counting method. We could find a greater amount of single-walled carbon nanotubes (SWCNTs) in the particulate matter emitted by aged diesel engines and thereby giving information about the combustion efficiency of the engine. The SWCNT rich sample finds a wide range of applications in nanoelectronics and thereby pointing a potential use of these aged engines.
Ključne besede: Fractals, internal combustion engine, efficiency, soot, carbon nanoparticle
Objavljeno v RUNG: 30.06.2022; Ogledov: 1200; Prenosov: 0
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96.
From futile to fruitful: Diesel soot as white light emitter
Mohanachandran Nair Sindhu Swapna, Sankararaman S, 2018, izvirni znanstveni članek

Opis: The present work describes a solution for the effective use of the hazardous particulate matter (diesel soot) from the internal combustion engines (ICEs) as a potential material emitting white light for white light emitting diodes (WLEDs). The washed soot samples are subjected to Field Emission Scanning Electron Microscopy (FESEM), High- Resolution Transmission Electron Microscopy (HR-TEM), Energy Dispersive Spectroscopy (EDS), UV-Visible, Photoluminescent (PL) Spectroscopy and quantum yield measurements. The CIE plot and Correlated Color Temperature (CCT) reveals the white fluorescence on photoexcitation. The sample on ultraviolet (UV) laser excitation, provides a visual confirmation of white light emission from the sample. The diesel soot collected from public transport buses of different years of manufacture invariably exhibit white fluorescence at an excitation of 350 nm. The sample show a quantum yield of 47.09%. The study is significant in the context of pollution and search for low-cost, rare-earth phosphor free material for white light emission and thereby turning the hazardous, futile material into a fruitful material that can be used for potential applications in photonics and electronics.
Ključne besede: White light emitter, Diesel soot, CIE plot, Quantum yield, Fluorescence
Objavljeno v RUNG: 30.06.2022; Ogledov: 1081; Prenosov: 0
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97.
Blue light emitting diesel soot for photonic applications
Mohanachandran Nair Sindhu Swapna, Sankararaman S, 2018, izvirni znanstveni članek

Opis: The present work is the first report of producing blue light emission from phosphor free and low-cost material—the diesel soot from the internal combustion engines (ICEs). The structural morphology is analyzed by field emission scanning electron microscopy and high-resolution transmission electron microscopy. The optical characterization is done by recording UV–visible spectrum and photoluminescent Spectrum. The CIE plot and the power spectrum for the sample show blue emission. This is further verified by collecting diesel soot from the ICE of different year of make. A visual confirmation of blue emission is obtained by exciting the sample with UV laser. The presence of various allotropic forms of carbon in the sample is identified by x-ray diffraction, Fourier transform infrared and Raman spectroscopic analysis.
Ključne besede: blue light emitter, diesel soot, photoluminescence, CIE plot
Objavljeno v RUNG: 30.06.2022; Ogledov: 1093; Prenosov: 0
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98.
Natural precursor based hydrothermal synthesis of sodium carbide for reactor applications
Mohanachandran Nair Sindhu Swapna, 2017, izvirni znanstveni članek

Opis: Carbides are a class of materials with high mechanical strength and refractory nature which finds a wide range of applications in industries and nuclear reactors. The existing synthesis methods of all types of carbides have problems in terms of use of toxic chemical precursors, high-cost, etc. Sodium carbide (Na2C2) which is an alkali metal carbide is the least explored one and also that there is no report of low-cost and low-temperature synthesis of sodium carbide using the eco-friendly, easily available natural precursors. In the present work, we report a simple low-cost, non-toxic hydrothermal synthesis of refractory sodium carbide using the natural precursor—Pandanus. The formation of sodium carbide along with boron carbide is evidenced by the structural and morphological characterizations. The sample thus synthesized is subjected to field emission scanning electron microscopy (FESEM), x-ray powder diffraction (XRD), ultraviolet (UV)—visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), Raman, and photoluminescent (PL) spectroscopic techniques.
Ključne besede: sodium carbide, pandanus, hydrothermal synthesis, porous materials
Objavljeno v RUNG: 30.06.2022; Ogledov: 1933; Prenosov: 0
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99.
Fractal analysis - a surrogate technique for material characterization
Mohanachandran Nair Sindhu Swapna, Sankararaman S, 2017, izvirni znanstveni članek

Opis: Fractal analysis has emerged as a potential analytical tool in almost all branches of science and technology. The paper is the first report of using fractal dimension as a surrogate technique for estimating particle size. A regression equation is set connecting the soot particle size and fractal dimension, after investigating the Field Emission Scanning Electron Microscopic (FESEM) images of carbonaceous soot from five different sources. Since the fractal dimension is an invariant property under the scale transformation, an ordinary photograph of the soot should also yield the same fractal dimension. This enables one to determine the average size of the soot particles, using the regression equation, by calculating the fractal dimension from the photograph. Hence, instead of frequent measurement of average particle size from FESEM, this technique of estimating the particle size from the fractal dimension of the soot photograph, is found to be a potentially cost-effective and non-contact method.
Ključne besede: fractals, FESEM, carbon nanoparticles, particle size, box-counting
Objavljeno v RUNG: 30.06.2022; Ogledov: 1165; Prenosov: 0
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100.
Camphor soot: A Tunable Light Emitter
Mohanachandran Nair Sindhu Swapna, SARITHA DEVI H V, Sankararaman S, 2018, izvirni znanstveni članek

Opis: The work in this paper is the first report on the green synthesis of the blue light emitter from waxy, flammable solid collected from Cinnamomum camphora by controlled combustion for photonic applications. Analysis with field emission scanning electron microscope and high-resolution transmission electron microscope provides the morphology, whereas the thermo-gravimetric analysis gives the thermal stability of the soot. The optical and structural characterizations are done by recording UV–Visible, Photoluminescent, and Raman Spectrum. The CIE plot and the power spectrum of the sample show a blue emission at an excitation of 350 nm at room temperature with a quantum yield of 46.15%. The dependence of luminescent behavior on temperature and excitation wavelength reveals that the material is a tunable blue emitter. This green synthesis of the blue light emitter is highly significant, when the world is in search of a simple, phosphor-free, non-toxic, cost-effective material with good quantum efficiency
Ključne besede: camphor, soot, blue light emitter
Objavljeno v RUNG: 30.06.2022; Ogledov: 996; Prenosov: 0
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