Evidence of enhanced photocurrent response in corannulene filmsNadya Patukhova
, Layla Martin Samos
, Egona Pavlica
, Gvido Bratina
, 2017, izvirni znanstveni članek
Opis: Photoconductivity spectra measured in non-crystalline corannulene thin layers are compared to optical absorption in solution phase and thin films. The unexpected enhanced photoconductivity is correlated with GW–BSE theoretical predictions of corannulene gas-phase excitonic spectra. Theoretical analysis reveals a consistent contribution involving transitions to Super Atomic Molecular Orbitals (SAMOs), a unique set of diffuse orbitals typical of curved conjugated constructs. Results suggest SAMO population via direct photoexcitation as a potential mechanism towards exploiting these diffuse orbitals as conducting channels in suitably assembled quantum nanostructures or solids.
Najdeno v: ključnih besedah
Povzetek najdenega: ... Coranulene, photoconductivity, thin layers, photoexcitation...
Ključne besede: Coranulene, photoconductivity, thin layers, photoexcitation
Objavljeno: 26.09.2017; Ogledov: 1969; Prenosov: 125
Polno besedilo (644,91 KB)