ORR stability of Mn–Co/polypyrrole nanocomposite electrocatalysts studied by quasi in-situ identical-location photoelectron microspectroscopyMaya Kiskinova
, Claudio Mele
, Hikmet Sezen
, Benedetto Bozzini
, Mattia Fanetti
, Andrea Goldoni
, Luca Gregoratti
, Belen Aleman
, Matteo Amati
, Patrizia Bocchetta
, 2016, izvirni znanstveni članek
Opis: The stability of pyrolyzed Mn–Co/polypyrrole (PPy) nanocomposites towards the Oxygen Reduction Reaction (ORR)
in alkaline solution, was studied with a close-knit group of complementary microscopic and space-resolved spectroscopic
approaches: Atomic Force Microscopy (AFM), Scanning and High-Resolution Transmission Electron
Microscopy (SEM, HRTEM) and identical-location Scanning PhotoElectron Microscopy (SPEM). Tracking quasi-in
situ the morphochemical evolution of the Mn–Co/PPy catalyst upon electrochemical aging under ORR conditions
by this multi-technique approach, has allowed to clarify the key physico-chemical processes underlying
the dramatic impact of Co additions to stability improvement.
Najdeno v: ključnih besedah
Povzetek najdenega: ...Mixed manganese oxides, Polypyrrole, Oxygen reduction, Electrocatalysis, Nanocomposites, X-ray photoelectron microspectroscopy...
Ključne besede: Mixed manganese oxides, Polypyrrole, Oxygen reduction, Electrocatalysis, Nanocomposites, X-ray photoelectron microspectroscopy
Objavljeno: 25.07.2016; Ogledov: 4266; Prenosov: 0
Polno besedilo (1,36 MB)
Effect of the Morphology of the High-Surface-Area Support on the Performance of the Oxygen-Evolution Reaction for Iridium NanoparticlesLeonard Moriau
, Marjan Bele
, Živa Marinko
, Francisco Ruiz-Zepeda
, Gorazd Koderman
, Martin Šala
, Angelija Kjara Šurca
, Janez Kovač
, Iztok Arčon
, Primož Jovanovič
, Nejc Hodnik
, Luka Suhadolnik
, 2021, izvirni znanstveni članek
Opis: The development of affordable, low-iridium-loading,
scalable, active, and stable catalysts for the oxygen-evolution
reaction (OER) is a requirement for the commercialization of
proton-exchange membrane water electrolyzers (PEMWEs).
However, the synthesis of high-performance OER catalysts with
minimal use of the rare and expensive element Ir is very challenging
and requires the identification of electrically conductive and stable
high-surface-area support materials. We developed a synthesis
procedure for the production of large quantities of a nanocomposite
powder containing titanium oxynitride (TiONx) and Ir.
The catalysts were synthesized with an anodic oxidation process
followed by detachment, milling, thermal treatment, and the
deposition of Ir nanoparticles. The anodization time was varied to grow three different types of nanotubular structures exhibiting different lengths and wall thicknesses and thus a variety of properties. A comparison of milled samples with different degrees of nanotubular clustering and morphology retention, but with identical
chemical compositions and Ir nanoparticle size distributions and dispersions, revealed that the nanotubular support morphology is
the determining factor governing the catalyst’s OER activity and stability. Our study is supported by various state-of-the-art
materials’ characterization techniques, like X-ray photoelectron spectroscopy, scanning and transmission electron microscopies, Xray powder diffraction and absorption spectroscopy, and electrochemical cyclic voltammetry. Anodic oxidation proved to be a very suitable way to produce high-surface-area powder-type catalysts as the produced material greatly outperformed the IrO2 benchmarks
as well as the Ir-supported samples on morphologically different TiONx from previous studies. The highest activity was achieved for the sample prepared with 3 h of anodization, which had the most appropriate morphology for the effective removal of oxygen
Najdeno v: ključnih besedah
Povzetek najdenega: ... electrocatalysis, oxygen-evolution reaction, TiONx-Ir powder catalyst, iridium nanoparticles,...
Ključne besede: electrocatalysis, oxygen-evolution reaction, TiONx-Ir powder catalyst, iridium nanoparticles, anodic oxidation, morphology−activity correlation
Objavljeno: 04.01.2021; Ogledov: 1647; Prenosov: 0
Polno besedilo (6,36 MB)
Synthesis and application of transition metal phosphide nanomaterials as electrocatalysts for water splitting and chemical transformationsTakwa Chouki
, 2022, doktorska disertacija
Opis: In this thesis, we will focus on the solvothermal synthesis of iron phosphides (FeP, Fe2P) using triphenylphosphine (TPP) as an inexpensive and stable phosphorus source. The obtained iron phosphides were applied as electrocatalysts in hydrogen evolution reaction (HER), oxygen evolution reaction (OER), Rhodamine B (RhB) degradation, Escherichia coli (E. coli) inactivation,
nitrates reduction reaction (NO3RR) to ammonia (NH3), and as counter electrodes in dye-sensitized solar cells (DSSCs). Detailed characterizations of catalysts were carried out to investigate the correlations between the material structure and catalytic activity.
The first part of the thesis gives an introduction to the topic which cover overview of literature about the use of transition metal phosphide as efficient electrocatalysts in water splitting studies, NO3RR to NH3 and DSSCs.
The second part is a description of the experimental methods.
The third part discusses the solvothermal synthesis of FeP and Fe2P catalysts using TPP precursor. The phase conversion of iron phosphides at elevated temperatures under reductive atmosphere was reported. Structural characterizations of the obtained materials were achieved using multiple techniques. The electrocatalytic activities of heat-treated iron phosphide films for HER were studied in acidic environment.
The fourth part discusses the use of Fe2P nanoparticles (NPs) for OER.
The fifth part outlines the use of Fe2P precatalyst in water treatment studies. Using a thin film of Fe2P precatalyst, RhB degradation and E. coli inactivation in the presence of in-situ generated reactive chlorine species were reported. Characterization of Fe2P electrocatalysts before and after the test was carried out using different techniques.
The sixth part shows for the first time the use of FeP and Fe2P as a noble metal-free electrocatalysts for NO3RR to NH3. In this chapter we will emphasize the nitrate reaction pathways, which are highly complex and poorly understood.
The seventh part demonstrates the use of FeP and Fe2P catalysts as robust and efficient counter electrodes in DSSCs.
Najdeno v: ključnih besedah
Povzetek najdenega: ...solvothermal synthesis, iron phosphides, electrocatalysis, HER, OER, RhB degradation, E. coli inactivation,...
Ključne besede: solvothermal synthesis, iron phosphides, electrocatalysis, HER, OER, RhB degradation, E. coli inactivation, NO3RR to NH3, DSSCs, dissertations
Objavljeno: 29.08.2022; Ogledov: 483; Prenosov: 42
Polno besedilo (6,35 MB)
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