Opis: We present the chemical vapor deposition (CVD) approach to grow MoSe2 thin films using colloidal molybdenum nanoparticles (Mo NPs). The synthetic protocol of Mo NPs was achieved using a wet-chemical method. The obtained Mo NPs were spin-coated on graphite substrates and heat-treated in the presence of selenium vapors at several temperatures (≥750 °C). The electrocatalytic activities of heat-treated MoSe2 thin films were studied for hydrogen evolution reaction (HER) in 0.5 M sulfuric acid (H2SO4). The lowest recorded overpotential of 218 mV at 10 mA cm−2 vs. a reversible hydrogen electrode was achieved with MoSe2−800°C catalyst. In addition, electrochemical impedance spectroscopy (EIS) was performed to access the charge-transfer resistance of the MoSe2 films. The colloidal approach combined with CVD is a promising route to produce carbon supported MoSe2 electrocatalyst for HER.Ključne besede: MoSe2 thin films CVD HERObjavljeno v RUNG: 06.02.2023; Ogledov: 1056; Prenosov: 0Gradivo ima več datotek! Več...
Opis: Molybdenum diselenide (MoSe2) is an emerging alternative to platinum-group-metal electrocatalysts for the hydrogen evolution reaction (HER). Herein, the chemical vapor deposition (CVD) approach was demonstrated to be a successful route to grow MoSe2 thin films using colloidal molybdenum nanoparticles (Mo NPs). TKljučne besede: Water splitting, electrocatalyst, MoSe2Objavljeno v RUNG: 15.01.2021; Ogledov: 2304; Prenosov: 0Gradivo ima več datotek! Več...