1. Atomic-level mechanisms of magnesium oxidationDmytro Orlov, Matjaž Valant, Sandra Gardonio, Mattia Fanetti, 2016, objavljeni znanstveni prispevek na konferenci Opis: Magnesium has been recently becoming an increasingly popular material for various applications. However, excessive chemical reactivity, and oxidation rate in particular, is a major obstruction on the way of Mg to become widely adopted. A significant problem causing the lack of Mg reactivity control is insufficient understanding of mechanisms involved in the oxidation of magnesium surface. Herewith we present the investigation of atomic-level mechanisms of oxidation initiation and propagation in pure Mg. Namely, X-ray photoelectron spectroscopy at synchrotron Elettra was used as a surface sensitive direct method to determine the valence of Mg and O and the valence band states at the early stage of oxide formation over a principal, most densely packed, crystallographic plane (0001) in pure Mg. The mechanisms of oxygen adsorption on magnesium free surface followed by oxidation (i.e. initiation and kinetics of MgO formation) are clarified. Copyright © 2016 by The Minerals, Metals & Materials Society. All rights reserved.
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Povzetek najdenega: ...and propagation in pure Mg. Namely, X-ray photoelectron spectroscopy at synchrotron Elettra was used as...
Ključne besede: Magnesium, Oxidation, Synchrotron radiation, X-ray photoelectron spectroscopy
Objavljeno: 25.08.2017; Ogledov: 3766; Prenosov: 0
 Polno besedilo (2,91 MB) |
2. Removal of copper from aqueous solutions with zeolites and possible treatment of exhaust materialsIztok Arčon, Janez Kovač, Margarita Popova, Nataša Zabukovec Logar, 2021, izvirni znanstveni članek Opis: The mechanism of Cu2+ loading into commercially available natural HEU-type and synthetic LTA-type zeolites for their
possible use in environmental processes, such as water and air treatment applications, was studied. Elemental analysis,
SEM/EDXS, XRD, XAS and XPS analyses revealed 4-fold coordination of Cu2+ cations with oxygen atoms in the pores, a
predominant location of copper atoms on the surface of crystallites and retained crystallinity of zeolites throughout the
processes. The post-treatment of Cu2+-loaded samples with HCl and/or NaCl solutions confirmed the predominantly
reversible sorption of copper on zeolites from aqueous solutions by ion-exchange mechanism and, therefore, excellent
regeneration possibilities for both types of zeolites. Furthermore, with the calcination of exhaust metal-loaded zeolites,
catalysts for total toluene oxidation reaction, as a model VOC pollutant, were obtained.
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Povzetek najdenega: ...Total toluene oxidation, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy,
Zeolite...
Ključne besede: Cu2+ ion exchange, Total toluene oxidation, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, Zeolite
Objavljeno: 03.06.2021; Ogledov: 1149; Prenosov: 61
 Polno besedilo (0,00 KB)
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3. Ultrafast relaxation of photoexcited superfluid He nanodropletsD.M. Neumark, A. Hernando, O. Gessner, C. Grazioli, P. Finetti, M. Drabbels, M. Di Fraia, M. Devetta, A. Demidovich, M. Coreno, C. Callegari, A. Ciavardini, P. O'Keeffe, M. Mudrich, A.C. LaForge, Y. Ovcharenko, P. Piseri, O. Plekan, K.C. Prince, R. Richter, M.P. Ziemkiewicz, T. Moller, J. Eloranta, M. Pi, M. Barranco, F. Stienkemeier, 2020, izvirni znanstveni članek Najdeno v: ključnih besedah
Povzetek najdenega: ...nanomaterial, density functional theory, dipole, excitation, ionization, photoelectron spectroscopy, photoexcitation, photon, simulation, ultraviolet radiation, ultra...
Ključne besede: helium, helium nanodroplet, nanomaterial, density functional theory, dipole, excitation, ionization, photoelectron spectroscopy, photoexcitation, photon, simulation, ultraviolet radiation, ultrafast photoemission, free electron laser, ultrafast spectrscopy
Objavljeno: 20.01.2022; Ogledov: 897; Prenosov: 0
Polno besedilo (2,39 MB) |
4. Experimental and Theoretical Photoemission Study of Indole and Its Derivatives in the Gas PhaseO. Plekan, H. Sa'adeh, A. Ciavardini, C. Callegari, G. Cautero, C. Dri, M. Di Fraia, K.C. Prince, R. Richter, R. Sergo, L. Stebel, M. Devetta, D. Faccialà, C. Vozzi, L. Avaldi, P. Bolognesi, M.C Castrovilli, D. Catone, M. Coreno, F. Zuccaro, E. Bernes, G. Fronzoni, D. Toffoli, 2020, izvirni znanstveni članek Najdeno v: ključnih besedah
Povzetek najdenega: ...Ionization of gases, Ionization potential, Molecular orbitals, Photoelectron spectroscopy, Photoelectrons, Photoemission, Photoionization, Photons, Polycycl...
Ključne besede: Binding energy, Calculations, Core levels, Electronic structure, Ionization of gases, Ionization potential, Molecular orbitals, Photoelectron spectroscopy, Photoelectrons, Photoemission, Photoionization, Photons, Polycyclic aromatic hydrocarbons, X rays
Objavljeno: 21.01.2022; Ogledov: 911; Prenosov: 0
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5. Electronic and chemical surface properties of Bi2Se3 derived compoundsZipporah Rini Benher, doktorska disertacija Najdeno v: ključnih besedah
Povzetek najdenega: ...method, X-ray powder diffraction, scanning electron microscopy, photoelectron spectroscopy...
Ključne besede: Bismuth selenide derived compounds, surface chemical and electronic properties, topological insulators, single crystals, phase separation, inorganic bulk heterostructures, ix
Bridgman method, X-ray powder diffraction, scanning electron microscopy, photoelectron spectroscopy
Objavljeno: 16.12.2022; Ogledov: 276; Prenosov: 6
Polno besedilo (9,56 MB) |
