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Pulling polymers : models and experiment
Knarik Yeritsyan, 2021, druge monografije in druga zaključena dela

Ključne besede: polymers, DNA pulling, worm-like chain
Objavljeno v RUNG: 19.08.2021; Ogledov: 1893; Prenosov: 47
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14.
Polymer-based nano-composites for thermal insulation
Alessandro Fraleoni-Morgera, Manisha Chhikara, 2019, pregledni znanstveni članek

Ključne besede: nano-composites, polymers, thermal insulation
Objavljeno v RUNG: 13.07.2021; Ogledov: 2308; Prenosov: 0

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Porous polycalix[n]arenes as environmental pollutant removers
Salma Abubakar, Tina Škorjanc, Dinesh Shetty, Ali Trabolsi, 2021, pregledni znanstveni članek

Opis: A new and innovative class of calixarene-based polymers emerged as adsorbents for a variety of compounds and ions in solution and vapor media. These materials take advantage of the modifiable rims and hydrophobic cavities of the calixarene monomers, in addition to the porous nature of the polymeric matrix. With main-chain calixarenes’ function as supramolecular hosts and the polymers’ high surface areas, polycalixarenes can effectively encapsulate target analytes. This feature is particularly useful for environmental remediation as dangerous and toxic molecules reversibly bind to the macrocyclic cavity, which facilitates their removal and enables repeated use of the polymeric sorbent. This Spotlight touches on the unique characteristics of the calixarene monomers and discusses the synthetic methods of our reported calixarene-based porous polymers, including Sonogashira–Hagihara coupling, and diazo and imine bond formation. It then discusses the promising applications of these materials in adsorbing dyes, micropollutants, iodine, mercury, paraquat, and perfluorooctanoic acid (PFOA) from water. In most cases, these reports cover materials that outperform others in terms of recyclability, rates of adsorption, or uptake capacities of specific pollutants. Finally, this Spotlight addresses the current challenges and future aspects of utilizing porous polymers in pollution treatment.
Ključne besede: calixarene, polycalixarenes, porous polymers, pollutant removal, water purification
Objavljeno v RUNG: 09.04.2021; Ogledov: 2598; Prenosov: 0
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17.
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks
Tina Škorjanc, Dinesh Shetty, Ali Trabolsi, 2021, pregledni znanstveni članek

Opis: Air, water, and soil pollution devastate countless ecosystems and deteriorate human health. Adsorption has commonly been used as a pollutant removal technique, but ongoing materials science research is still searching for more efficient, cheaper, and scalable sorbent materials. Herein, we discuss the synthesis and pollutant-capturing abilities of covalent polymeric structures, including covalent organic polymers and covalent organic frameworks that contain organic macrocycles in the backbone of their structures. These organic macrocycles (cyclodextrin, calixarene, cucurbituril, pillararene, and porphyrin) possess cavities and functional groups that can sequester pollutants by forming supramolecular interactions. The insolubility of these materials prominently aids in their regeneration and recyclability potentials. Following a discussion on the synthetic strategies used in the polymerization of each type of macrocycle, environmental applications of these materials are presented. Here, we focus on the removal of micropollutants, charged species, metal ions, oils and organic solvents, perfluorinated substances, iodine, and volatile organic compounds.
Ključne besede: supramolecular interactions, host-guest chemistry, organic macrocycles, covalent polymers, covalent organic frameworks, environmental remediation, adsorption
Objavljeno v RUNG: 09.04.2021; Ogledov: 2552; Prenosov: 65
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18.
Introduction of a Redox-Responsive Switch into calix[4]arene-based Covalent Organic Nanosheets for Environmental Applications
Tina Skorjanc, 2018, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: redox chemistry, viologen, covalent organic polymers, calixarene, dye adsorption, iodine adsorption
Objavljeno v RUNG: 11.09.2020; Ogledov: 2725; Prenosov: 0
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19.
Redox-Tunable Polycationic Polymers for Environmental Applications
Tina Skorjanc, Goinda Das, Selbi Nuryyeva, Thirumurugan Prakasam, Ali Trabolsi, 2017, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: covalent polymers, viologen, redox chemistry, pollutant removal, dye adsorption, iodine capture
Objavljeno v RUNG: 10.09.2020; Ogledov: 2785; Prenosov: 0
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20.
Covalent organic frameworks for biomedical and environmental applications
Tina Skorjanc, predavanje na tuji univerzi

Ključne besede: pollutant removal, covalent organic polymers, drug delivery, imaging
Objavljeno v RUNG: 03.09.2020; Ogledov: 2840; Prenosov: 0
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