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101.
Highly Sensitive Determination of Pyoverdine in Cloud Water by HPLC-Thermal Lens Spectrometry
Leja Goljat, Mitja Martelanc, Virginie Vinatier, Anne-Marie Delort, Mladen Franko, 2016, objavljeni povzetek znanstvenega prispevka na konferenci

Opis: New method for pyoverdine and Fe(III)-pyoverdine detection was developed. Two isomers of pyoverdine and two isomers of Fe(III)-pyoverdine were separated isocraticaly on reversed-phase (RP)-C18 chromatograhic column and detected by DAD, FLD and TLS. HPLC-TLS method enables separation and determination of pyoverdine and Fe(III)-pyoverdine in a single run and excels in superior sensitivities when compared to conventional HPLC-DAD system.
Ključne besede: Pyoverdine, Fe(III)-pyoverdine, cloud water, high-performance liquid chromatography, thermal lens spectrometry
Objavljeno v RUNG: 04.07.2016; Ogledov: 5627; Prenosov: 0

102.
103.
Thermal Lens Spectrometry: Still a Technique on the Horizon
Mingqiang Liu, Mladen Franko, 2016, objavljeni znanstveni prispevek na konferenci

Opis: In this article the historical development of thermal lens spectrometry (TLS) is briefly reviewed for introduction. In continuation, the emphasis is on the recent progresses of TLS for measurements in ensembled sample cells and in microfluidic flow injection systems. Novel theories, instrumentations and their applications for high sample throughput environmental, chemical and biomedical analysis, particularly in micro space, are presented. Discussions are given on the limitations of present TLS systems, that open new horizons for future progress of this technique, which has already found place among routine techniques for chemical analysis. In the last part, proposals for the future development of TLS toward advanced applications in new research fields are presented.
Ključne besede: Thermal lens spectrometry, Microfluidic chip, Chemical analysis, Environmental monitoring, Biomedical assay
Objavljeno v RUNG: 17.05.2016; Ogledov: 5036; Prenosov: 0
Gradivo ima več datotek! Več...

104.
Thermal lens spectrometry - still a technique on the horizon?
Mladen Franko, 2015

Opis: In 1980’s thermal lens spectrometry (TLS) was still considered as a “spectrometric technique on the horizon” as one can also read from one of the textbooks on spectrochemical analysis of that time. Intensive development of thermal lens instrumentation and methods of chemical analysis and material characterisation has however resulted in substantial progress in this field, which is evident from important instrumental innovations and first commercial instruments (i.e. thermal lens microscopes -TLM) designed for lab-on-a-chip chemistry as well as from novel applications of TLS in various areas, where highly sensitive and rapid chemical analysis of complex samples is needed, including food safety and quality control, environmental analysis and biomedical diagnostics. This presentation is a review of most significant contributions and applications of thermal lens spectrometry, with emphasis on most recent achievements in instrumentation, which culminated into construction of novel optimized TLM instruments, capable of exploiting the tuneability of incoherent light sources and enabled novel applications particularly in micro-fluidics. Based on latest progress relying on bio-analytical assays and micro-fluidic flow injection with TLM detection we have also witnessed firs routine applications of TLS in analytical and diagnostic laboratories, which on wine side actually classifies TLS as a conventional and routine analytical tool, but at the same time opens new horizons for development and applications of this ultrasensitive and rapid spectrometric technique.
Ključne besede: Thermal lens spectrometry, applications, Liquid chromatography, flow injection analysis, bioanalytical methods
Objavljeno v RUNG: 29.03.2016; Ogledov: 6579; Prenosov: 0
Gradivo ima več datotek! Več...

105.
FERMI-LAT OBSERVATIONS OF HIGH-ENERGY γ-RAY EMISSION TOWARD THE GALACTIC CENTER
Gabrijela Zaharijas, B. L. Winer, 2016, izvirni znanstveni članek

Opis: The Fermi Large Area Telescope (LAT) has provided the most detailed view to date of the emission toward the Galactic center (GC) in high-energy γ-rays. This paper describes the analysis of data taken during the first 62 months of the mission in the energy range 1–100 GeV from a 15° × 15° region about the direction of the GC. Specialized interstellar emission models (IEMs) are constructed to enable the separation of the γ-ray emissions produced by cosmic ray particles interacting with the interstellar gas and radiation fields in the Milky Way into that from the inner ∼1 kpc surrounding the GC, and that from the rest of the Galaxy. A catalog of point sources for the 15° × 15° region is self-consistently constructed using these IEMs: the First Fermi-LAT Inner Galaxy Point Source Catalog (1FIG). The spatial locations, fluxes, and spectral properties of the 1FIG sources are presented, and compared with γ-ray point sources over the same region taken from existing catalogs. After subtracting the interstellar emission and point-source contributions a residual is found. If templates that peak toward the GC are used to model the positive residual the agreement with the data improves, but none of the additional templates tried account for all of its spatial structure. The spectrum of the positive residual modeled with these templates has a strong dependence on the choice of IEM.
Ključne besede: cosmic rays – Galaxy: center – gamma-rays: general – gamma-rays: ISM – radiation mechanisms: non-thermal
Objavljeno v RUNG: 02.03.2016; Ogledov: 5248; Prenosov: 290
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