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Opis: Waste management is a global problem, as waste production continues to rise, and the methods used today, such as landfilling and incineration, can cause many environmental issues. Waste gasification, among other technologies, is a promising alternative since waste is turned into useful energy resources and reduces emissions with the formation of syngas. Thus, this thesis investigated the potential of waste gasification systems in sustainable waste management and circular economy. Focusing on its energy and economic potential, modeling methods were used to recreate real-world systems, with the goal of properly estimating the true sustainability potential of the waste gasification systems. Biomass gasification was evaluated through thorough thermodynamics and economic analysis. Although the initial calculations failed to provide positive results by showing the energy of 54 MJ, instead of the expected energy release, further analysis with the optimized conditions and different assumptions, provided more accurate results. By increasing the share of oxidized CO from 10% to 25%, and reducing the wet material from 35% to 10%, total released heat was estimated to be −148.9 MJ. With the right assumptions, the gasification process was proved to provide good energy values necessary for the sustainability of such a process. Additionally, the financial analysis produced a high Net Present Value (NPV) of EUR 3,434,411.46, Internal Rate of Return (IRR) of 21.81%, and a short payback period (PP) of 4.48 years, hence proving the strong economic potential and financial strength of such technology. Therefore, biomass waste gasification was concluded to be a positive investment opportunity with valuable long-term economic benefits, while still providing good energy balance.
Ključne besede: waste, gasification, energy, circular economy, emission
Objavljeno v RUNG: 18.12.2024; Ogledov: 269; Prenosov: 2
Celotno besedilo (2,16 MB)

Opis: We present results of the measurement of large-scale anisotropies in the arrival directions of ultra–high-energy cosmic rays detected at the Pierre Auger Observatory during 19 yr of operation, prior to AugerPrime, the upgrade of the observatory. The 3D dipole amplitude and direction are reconstructed above 4 EeV in four energy bins. Besides the established dipolar anisotropy in right ascension above 8 EeV, the Fourier amplitude of the 8–16 EeV energy bin is now also above the 5σ discovery level. No time variation of the dipole moment above 8 EeV is found, setting an upper limit to the rate of change of such variations of 0.3% per year at the 95% confidence level. Additionally, the results for the angular power spectrum are shown, demonstrating no other statistically significant multipoles. The results for the equatorial dipole component down to 0.03 EeV are presented, using for the first time a data set obtained with a trigger that has been optimized for lower energies. Finally, model predictions are discussed and compared with observations, based on two source emission scenarios obtained in the combined fit of spectrum and composition above 0.6 EeV.
Ključne besede: ultra–high-energy cosmic rays, UHECRs, UHECR anisotropies, Pierre Auger Observatory, dipolar anisotropy in right ascension, Fourier amplitude analysis, angular power spectrum, equatorial dipole component, UHECR source emission scenarios
Objavljeno v RUNG: 26.11.2024; Ogledov: 364; Prenosov: 0
Celotno besedilo (1,16 MB)
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Opis: Biomass combustion releases a complex array of Volatile Organic Compounds (VOCs) that pose significant challenges to air quality and human health. Although biomass burning has been extensively studied at ecosystem levels, understanding the atmospheric transformation and impact on air quality of emissions in urban environments remains challenging due to complex sources and burning materials. In this study, we investigate the VOC emission rates and atmospheric chemical processing of predominantly wood burning emissions in a small urban centre in Greece. Ioannina is situated in a valley within the Dinaric Alps and experiences intense atmospheric pollution accumulation during winter due to its topography and high wood burning activity. During pollution event days, the ambient mixing ratios of key VOC species were found to be similar to those reported for major urban centres worldwide. Positive matrix factorisation (PMF) analysis revealed that biomass burning was the dominant emission source (>50 %), representing two thirds of OH reactivity, which indicates a highly reactive atmospheric mixture. Calculated OH reactivity ranges from 5 s−1 to an unprecedented 278 s−1, and averages at 93 ± 66 s−1 at 9 PM, indicating the presence of exceptionally reactive VOCs. The highly pronounced photochemical formation of organic acids coincided with the formation of ozone, highlighting the significance of secondary formation of pollutants in poorly ventilated urban areas. Our findings underscore the pressing need to transition from wood burning to environmentally friendly sources of energy in poorly ventilated urban areas, in order to improve air quality and safeguard public health.
Ključne besede: biomass burning, urban air quality, VOCs, emission factors, source apportionment
Objavljeno v RUNG: 13.05.2024; Ogledov: 1111; Prenosov: 5
Celotno besedilo (8,93 MB)

Opis: One of the central scientific goals of the next-generation Cherenkov Telescope Array (CTA) is the detection and characterization of gamma-ray bursts (GRBs). CTA will be sensitive to gamma rays with energies from about 20 GeV, up to a few hundred TeV. The energy range below 1 TeV is particularly important for GRBs. CTA will allow exploration of this regime with a ground-based gamma-ray facility with unprecedented sensitivity. As such, it will be able to probe radiation and particle acceleration mechanisms at work in GRBs. In this contribution, we describe POSyTIVE, the POpulation Synthesis Theory Integrated project for very high-energy emission. The purpose of the project is to make realistic predictions for the detection rates of GRBs with CTA, to enable studies of individual simulated GRBs, and to perform preparatory studies for time-resolved spectral analyses. The mock GRB population used by POSyTIVE is calibrated using the entire 40-year dataset of multi-wavelength GRB observations. As part of this project we explore theoretical models for prompt and afterglow emission of long and short GRBs, and predict the expected radiative output. Subsequent analyses are performed in order to simulate the observations with CTA, using the publicly available ctools and Gammapy frameworks. We present preliminary results of the design and implementation of this project.
Ključne besede: very-high-energy gamma-ray astronomy, Cherenkov Telescope Array, CTA sensitivity, gamma-ray bursts, population Synthesis Theory, very high-energy emission
Objavljeno v RUNG: 04.12.2023; Ogledov: 2922; Prenosov: 3
Celotno besedilo (1,50 MB)
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Opis: Context. We present the wavelength-resolved reverberation mapping (RM) of combined Mg II and UV Fe II broad-line emissions for two intermediate-redshift (z ∼ 1), luminous quasars, HE 0413-4031 and HE 0435-4312, monitored by the Southern African Large Telescope (SALT) and 1m class telescopes between 2012 and 2022. Aims. Using a wavelength-resolved technique, we aim to disentangle the Mg II and Fe II emission regions and to build a radius–luminosity (R–L) relation for UV Fe II emission, which has so far remained unconstrained. Methods. We applied several time-delay methodologies to constrain the time delays for total Mg II and Fe II emissions. In addition, wavelength-resolved RM is performed to quantify the inflow or outflow of broad-line region (BLR) gas around the supermassive black hole and to disentangle the emission and the emitting regions based on lines produced in proximity to each other. Results. The mean total FeII time delay is nearly equal to the mean total MgII time delay for HE 0435-4312, suggesting the co-spatiality of their emission regions. However, in HE 0413-4031, the mean FeII time delay is found to be longer than the mean MgII time delay, suggesting that FeII emission is produced at greater distances from the black hole. The UV FeII R–L relation is updated with these two quasars (now four in total) and compared with the optical FeII relation (20 sources), which suggests that the optical FeII emission region is located further than the UV FeII region by a factor of 1.7–1.9, that is, RFeII-opt ∼ (1.7 − 1.9)RFeII-UV. Conclusion. Wavelength-resolved reverberation is an efficient way to constrain the geometry and structure of the BLR. We detected a weak pattern in the time delay versus wavelength relation, suggesting that the MgII broad line originates from a region slightly closer to the SMBH than the UV FeII pseudo continuum, although the difference is not very significant. Comparison of MgII, UV, and optical FeII R–L relations suggests that the difference may be greater for lower-luminosity sources, possibly with the MgII emission originating further from the SMBH. In the future, more RM data will be acquired, allowing better constraints on these trends, in particular the UV FeII R–L relation.
Ključne besede: accretion, accretion disks, emission lines, photometric, spectroscopic
Objavljeno v RUNG: 13.11.2023; Ogledov: 2190; Prenosov: 5
Celotno besedilo (2,92 MB)
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