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Designing atomic interface in ▫$Sb_2S_3/CdS$▫ heterojunction for efficient solar water splitting
Minji Yang, Zeyu Fan, Jinyan Du, Chao Feng, Ronghua Li, Beibei Zhang, Nadiia Pastukhova, Matjaž Valant, Matjaž Finšgar, Andraž Mavrič, Yanbo Li, 2024, izvirni znanstveni članek

Opis: In the emerging Sb2S3‐based solar energy conversion devices, a CdS buffer layer prepared by chemical bath deposition is commonly used to improve the separation of photogenerated electron‐hole pairs. However, the cation diffusion at the Sb2S3/CdS interface induces detrimental defects but is often overlooked. Designing a stable interface in the Sb2S3/CdS heterojunction is essential to achieve high solar energy conversion efficiency. As a proof of concept, this study reports that the modification of the Sb2S3/CdS heterojunction with an ultrathin Al2O3 interlayer effectively suppresses the interfacial defects by preventing the diffusion of Cd2+ cations into the Sb2S3 layer. As a result, a water‐splitting photocathode based on Ag:Sb2S3/Al2O3/CdS heterojunction achieves a significantly improved half‐cell solar‐to‐hydrogen efficiency of 2.78% in a neutral electrolyte, as compared to 1.66% for the control Ag:Sb2S3/CdS device. This work demonstrates the importance of designing atomic interfaces and may provide a guideline for the fabrication of high‐performance stibnite‐type semiconductor‐based solar energy conversion devices.
Ključne besede: alumina, defect passivation, interface engineering, photoelectrochemical water splitting
Objavljeno v RUNG: 11.03.2024; Ogledov: 508; Prenosov: 2
.pdf Celotno besedilo (4,59 MB)
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Infrared spectra in amorphous alumina
Luigi Giacomazzi, Nikita S Shcheblanov, Mikhail E Povarnitsyn, Yanbo Li, Andraž Mavrič, Barbara Zupančič, Jože Grdadolnik, Alfredo Pasquarello, zaključena znanstvena zbirka raziskovalnih podatkov

Opis: We present a combined study based on experimental measurements of infrared (IR) dielectric function and first-principles calculations of IR spectra and vibrational density of states (VDOS) of amorphous alumina (am-Al₂O₃). In particular, we show that the main features of the imaginary part of the dielectric function ε₂(ω) at ~380 and 630 cm-¹ are related to the motions of threefold coordinated oxygen atoms, which are the vast majority of oxygen atoms in am-Al₂O₃. Our analysis (involving three model structures) provides an alternative point of view with respect to an earlier suggested assignment of the vibrational modes, which relates them to the stretching and bending vibrational modes of AlOₙ (n = 4, 5, and 6) polyhedra. Our assignment is based on the additive decomposition of the VDOS and ε₂(ω) spectra, which shows that: (i) the band at ~380 cm-¹ features oxygen motions occurring in a direction normal to the plane defined by the three nearest-neighbor aluminum atoms, i.e. out-of-plane motions of oxygen atoms; (ii) Al-O stretching vibrations (i.e. in-plane motions of oxygen atoms) appear at frequencies above ~500 cm-¹, which characterize the vibrational modes underlying the band at ~630 cm-¹.
Ključne besede: amorphous alumina, infrared spectra, first-principles calculations
Objavljeno v RUNG: 15.09.2023; Ogledov: 931; Prenosov: 7
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Winning combination of Cu and Fe oxide clusters with an alumina support for low-temperature catalytic oxidation of volatile organic compounds
Tadej Žumbar, Iztok Arčon, Petar Djinović, Giuliana Aquilanti, Gregor Žerjav, Albin Pintar, Alenka Ristić, Goran Dražić, Janez Volavšek, Gregor Mali, Margarita Popova, Nataša Zabukovec Logar, Nataša Novak Tušar, 2023, izvirni znanstveni članek

Opis: A γ-alumina support functionalized with transition metals is one of the most widely used industrial catalysts for the total oxidation of volatile organic compounds (VOCs) as air pollutants at higher temperatures (280−450 °C). By rational design of a bimetal CuFe-γ-alumina catalyst, synthesized from a dawsonite alumina precursor, the activity in total oxidation of toluene as a model VOC at a lower temperature (200−380 °C) is achieved. A fundamental understanding of the catalyst and the reaction mechanism is elucidated by advanced microscopic and spectroscopic characterizations as well as by temperature-programmed surface techniques. The nature of the metal−support bonding and the optimal abundance between Cu−O−Al and Fe−O−Al species in the catalysts leads to synergistic catalytic activity promoted by small amounts of iron (Fe/Al = 0.005). The change in the metal oxide−cluster alumina interface is related to the nature of the surfaces to which the Cu atoms attach. In the most active catalyst, the CuO6 octahedra are attached to 4 Al atoms, while in the less active catalyst, they are attached to only 3 Al atoms. The oxidation of toluene occurs via the Langmuir−Hinshelwood mechanism. The presented material introduces a prospective family of low-cost and scalable oxidation catalysts with superior efficiency at lower temperatures.
Ključne besede: Iron oxide clusters, copper oxide clusters, alumina support, synergistic effect, low-temperature total catalytic oxidation, toluene, Cu, Fe XANES, EXAFS
Objavljeno v RUNG: 06.07.2023; Ogledov: 1260; Prenosov: 14
.pdf Celotno besedilo (11,05 MB)
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Amorphous alumina nanocomposite : the effect of surface, interface and bulk stress
Andraž Mavrič, Chunhua Cui, Matjaž Valant, 2019, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: alumina nanocomposite, surfaces
Objavljeno v RUNG: 10.02.2020; Ogledov: 3020; Prenosov: 0
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Efficient mineralization of greywater pollutants by photocatalytic ozonation: catalyst and reactor design
Urška Lavrenčič Štangar, Marko Kete, 2015, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: immobilized TiO2, silica binder, alumina monoliths
Objavljeno v RUNG: 01.02.2016; Ogledov: 5365; Prenosov: 1
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Towards efficient removal of contaminants from households grey waste water: Photocatalytic ozonation process
Marko Kete, Urška Lavrenčič Štangar, 2015, objavljeni povzetek znanstvenega prispevka na konferenci (vabljeno predavanje)

Ključne besede: compact reactor, immobilized TiO2, porous alumina monolith, LAS, PBIS, RB19
Objavljeno v RUNG: 01.02.2016; Ogledov: 5483; Prenosov: 0
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