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1.
Designing new renewable nano-structured electrode and membrane materials for direct alkaline ethanol fuel cell
Egon Pavlica, Ahmed Kreta, Gvido Bratina, končno poročilo o rezultatih raziskav

Najdeno v: ključnih besedah
Povzetek najdenega: ...chitosan, polysaccharide, fuel cell, alkaline, ethanol, photoconductivity, ionic conductivity, mixed-conductor model...
Ključne besede: graphene, chitosan, polysaccharide, fuel cell, alkaline, ethanol, photoconductivity, ionic conductivity, mixed-conductor model
Objavljeno: 03.12.2020; Ogledov: 1682; Prenosov: 0
.pdf Polno besedilo (10,55 MB)

2.
Correlation between FeCl2 electrolyte conductivity and electrolysis efficiency
Luin Uroš, Valant Matjaz, Arčon Iztok, 2022, objavljeni povzetek znanstvenega prispevka na konferenci

Opis: The electrolysis efficiency is an important aspect of the Power-to-Solid energy storage technology (EST) based on the iron chloride electrochemical cycle [1]. This cycle employs an aqueous FeCl2 catholyte solution for the electro-reduction of iron. The metal iron deposits on the cathode. The energy is stored as a difference in the redox potential of iron species. Hydrogen, as an energy carrier, is released on demand over a fully controlled hydrogen evolution reaction between metallic Fe0 and HCl (aq) [1]. Due to these characteristics, the cycle is suitable for long-term high-capacity and high-power energy storage. In a previous work [2] we revealed that the electrolyte conductivity linearly increases with temperature. Contrary, the correlation between the electrolyte concentration and efficiency is not so straightforward. Unexpectedly small efficiency variations were found between 1 and 2.5 mol dm-3 FeCl2 (aq) followed by an abrupt efficiency drop at higher concentrations. To explain the behavior of the observed trends and elucidate the role of FeCl2 (aq) complex ionic species we performed in situ X-ray absorption studies. We made a dedicated experimental setup, consisting of a tubular oven and PMMA liquid absorption cell, and performed the measurements at the DESY synchrotron P65 beamline. The XAS investigation covered XANES and EXAFS analyses of FeCl2 (aq) at different concentrations (1 - 4 molL-1) and temperatures (25 - 80 °C). We found that at low temperature and low FeCl2 concentration the octahedral first coordination sphere around Fe is occupied by one Cl ion at a distance of 2.33 (±0.02) Å and five water molecules at a distance of 2.095 (±0.005) Å [3]. The structure of the ionic complex gradually changes with an increase in temperature and/or concentration. The apical water molecule is substituted by a chlorine ion to yield a neutral Fe[Cl2(H2O)4]0. The transition from the single charged Fe[Cl(H2O)5]+ to the neutral Fe[Cl2(H2O)4]0 causes a significant drop in the solution conductivity, which well correlates with the existing conductivity models [3]. [1] M. Valant, “Procedure for electric energy storage in solid matter. United States Patent and Trademark Office. Patent No. US20200308715,” Patent No. US20200308715, 2021. [2] U. Luin and M. Valant, “Electrolysis energy efficiency of highly concentrated FeCl2 solutions for power-to-solid energy storage technology,” J. Solid State Electrochem., vol. 26, no. 4, pp. 929–938, Apr. 2022, doi: 10.1007/S10008-022-05132-Y. [3] U. Luin, I. Arčon, and M. Valant, “Structure and Population of Complex Ionic Species in FeCl2 Aqueous Solution by X-ray Absorption Spectroscopy,” Molecules, vol. 27, no. 3, 2022, doi: 10.3390/molecules27030642.
Najdeno v: ključnih besedah
Povzetek najdenega: ...elucidate the role of FeCl2 (aq) complex ionic species we performed in situ X-ray absorption studies....
Ključne besede: Iron chloride electrochemical cycle, Power-to-Solid energy storage, XANES, EXAFS, electrical conductivity, electrolyte complex ionic species structure and population
Objavljeno: 26.09.2022; Ogledov: 310; Prenosov: 0
.pdf Polno besedilo (27,64 MB)

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