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Opis: For the past 20 years, the Pierre Auger Observatory has collected the largest dataset of ultra-high-energy cosmic rays (UHECRs) ever achieved using a hybrid detector. The study of this dataset has led to numerous unexpected discoveries that enhance our understanding of the origins of UHECRs. One of the key points in this study is their mass composition. In this work, we will present the most recent results regarding the mass composition of UHECRs at the Pierre Auger Observatory. In particular, we will focus on the measurement of the depth of the maximum of air-shower profiles, denoted as Xmax . This determination has been achieved through both direct measurements from the Fluorescence Detector data and the application of machine learning for estimating Xmax on an event-by-event basis using the Surface Detector data. The latter has allowed us to extend the measurement to energies up to 100 EeV and indicates a correlation between changes in composition and three features of the energy spectrum (ankle, instep, steepening). Moreover, the results provide evidence of a heavy and nearly pure primary beam for energies greater than 50 EeV that is independent of the hadronic interaction model. The implications of these findings for astrophysics and for modelling hadronic interactions will be discussed.
Ključne besede: ultra-high-energy cosmic rays, Pierre Auger Observatory, extensive air showers, UHECR mass composition
Objavljeno v RUNG: 28.03.2025; Ogledov: 330; Prenosov: 8
Celotno besedilo (1,66 MB)
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Opis: The Pierre Auger Observatory has measured the spectrum of ultra-high-energy cosmic rays with unprecedented precision, as well as the distribution of the depths of the maximum of the shower development in the atmosphere, which provide a reliable estimator of the mass composition. The measurements above 10[sup]17.8 eV can be interpreted assuming two populations of uniformly distributed sources, one with a soft spectrum dominating the flux below few EeV, and another one with a very hard spectrum dominating above that energy. When considering the presence of intense extragalactic magnetic fields between our Galaxy and the closest sources and a high-energy population with low spatial density, a magnetic horizon appears, suppressing the cosmic ray's flux at low-energies, which could explain the very hard spectrum observed at Earth. The distribution of arrival directions, which at energies above 32 EeV shows indications of a correlation with a population of starburst galaxies or the radio galaxy Centaurus A (Cen A), are also important to constrain the sources. It is shown that adding a fractional contribution from these sources of about 20% on top of an homogeneous background leads to an improvement of the model likelihood.
Ključne besede: ultra-high-energy cosmic rays, UHECR energy spectrum, UHECR mass composition, UHECR anisotropies, UHECR propagation, UHECR data interpretation, extragalactic magnetic fields, starburst galaxies, Centaurus A, Pierre Auger Observatory
Objavljeno v RUNG: 24.03.2025; Ogledov: 287; Prenosov: 7
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Opis: We present photometric and spectroscopic observations of SN 2020xga and SN 2022xgc, two hydrogen-poor superluminous supernovae (SLSNe-I) at z = 0.4296 and z = 0.3103, respectively, which show an additional set of broad Mg II absorption lines, blueshifted by a few thousands kilometer second−1 with respect to the host galaxy absorption system. Previous work interpreted this as due to resonance line scattering of the SLSN continuum by rapidly expanding circumstellar material (CSM) expelled shortly before the explosion. The peak rest-frame g-band magnitude of SN 2020xga is −22.30 ± 0.04 mag and of SN 2022xgc is −21.97 ± 0.05 mag, placing them among the brightest SLSNe-I. We used high-quality spectra from ultraviolet to near-infrared wavelengths to model the Mg II line profiles and infer the properties of the CSM shells. We find that the CSM shell of SN 2020xga resides at ∼1.3 × 1016 cm, moving with a maximum velocity of 4275 km s−1, and the shell of SN 2022xgc is located at ∼0.8 × 1016 cm, reaching up to 4400 km s−1. These shells were expelled ∼11 and ∼5 months before the explosions of SN 2020xga and SN 2022xgc, respectively, possibly as a result of luminous-blue-variable-like eruptions or pulsational pair instability (PPI) mass loss. We also analyzed optical photometric data and modeled the light curves, considering powering from the magnetar spin-down mechanism. The results support very energetic magnetars, approaching the mass-shedding limit, powering these SNe with ejecta masses of ∼7 − 9 M⊙. The ejecta masses inferred from the magnetar modeling are not consistent with the PPI scenario pointing toward stars > 50 M⊙ He-core; hence, alternative scenarios such as fallback accretion and CSM interaction are discussed. Modeling the spectral energy distribution of the host galaxy of SN 2020xga reveals a host mass of 107.8 M⊙, a star formation rate of 0.96−0.26+0.47 M⊙ yr−1, and a metallicity of ∼0.2 Z⊙.
Ključne besede: eruptive mass, loss, supernovae
Objavljeno v RUNG: 04.03.2025; Ogledov: 540; Prenosov: 5
Celotno besedilo (33,61 MB)
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Opis: We report an investigation of the mass composition of cosmic rays with energies from 3 to 100 EeV (1 EeV = 10[sup]18 eV) using the distributions of the depth of shower maximum Xmax. The analysis relies on ∼50,000 events recorded by the surface detector of the Pierre Auger Observatory and a deep-learning-based reconstruction algorithm. Above energies of 5 EeV, the dataset offers a 10-fold increase in statistics with respect to fluorescence measurements at the Observatory. After cross-calibration using the fluorescence detector, this enables the first measurement of the evolution of the mean and the standard deviation of the Xmax distributions up to 100 EeV. Our findings are threefold: (i) The evolution of the mean logarithmic mass toward a heavier composition with increasing energy can be confirmed and is extended to 100 EeV. (ii) The evolution of the fluctuations of Xmax toward a heavier and purer composition with increasing energy can be confirmed with high statistics. We report a rather heavy composition and small fluctuations in Xmax at the highest energies. (iii) We find indications for a characteristic structure beyond a constant change in the mean logarithmic mass, featuring three breaks that are observed in proximity to the ankle, instep, and suppression features in the energy spectrum.
Ključne besede: ultra-high-energy cosmic rays, UHECRs, extensive air showers, Pierre Auger Observatory, UHECR mass composition, depth of shower maximum, fluorescence detector, surface detector, deep learning
Objavljeno v RUNG: 20.01.2025; Ogledov: 672; Prenosov: 8
Celotno besedilo (2,71 MB)
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Opis: In recent decades, there has been a growing interest in producing biofuels and biochemicals from renewable sources. Furfural stands as one of the ligno(hemi)cellulosic biomass derived platform chemical, which can be transformed into numerous value-added products. The goal of this PhD was to systematically study hydrotreatment reactions of furfural under varying operating conditions and to gain insights into the reaction mechanism and kinetics. An extensive experimental and computational study of hydrogenation, hydrodeoxygenation, oligomerisation and etherification of furfural in a three-phase batch reactor was performed. The goals were divided into three consecutive objectives. In the first part, hydrotreatment of furfural over Pd/C catalyst under various reaction conditions, including the solvent selection (solventless conditions, tetrahydrofuran, isopropanol), atmosphere (nitrogen, hydrogen), temperature (100–200 °C), pressure (25–75 bar) and stirring speed, was studied. A reaction pathway network and a micro-kinetic model were developed, incorporating thermodynamics (hydrogen solubility), mass transfer, adsorption, desorption, and surface reactions. These phenomena and their contribution to the surface coverages, TOF’s and global reaction rates were studied. The hydrogen presence on the catalyst surface was found to influence the main reaction pathway, leading to ring, aldehyde group or full hydrogenation. In the second part, various monometallic catalysts (Pd/C, Pt/C, Re/C, Ru/C, Rh/C, Ni/C, Cu/C) were tested at 100 -200 °C with 60 bar of hydrogen and tetrahydrofuran as solvent. A generalized reaction pathway network was developed. H2 temperature-programmed reduction (H2-TPR) and CO temperature-programmed desorption (CO-TPD) were conducted, and a regression analysis of the results was subsequently performed by numerical modelling and optimisation. The obtained adsorption and desorption kinetic parameters for active metallic sites were further used in a generalized micro-kinetic model, applicable to all tested catalysts. Pd/C exhibited high activity and non-selective hydrogenation of furfural, while other catalysts showed selective aldehyde group hydrogenation followed by deoxygenation, consistent with density functional theory (DFT) calculations. Ru/C uniquely produced 2 methyltetrahydrofuran and ring-opening products at 200 °C. In silico optimization of reaction conditions for promising catalysts ((Pd/C, Pt/C, Re/C, Ni/C) aimed to maximize the yield of the target product. In the third part, the influence of support on catalytic activity was studied. Hydrotreatment of furfural over Pd/Al2O3, Pd/SiO2, Ru/Al2O3, Ru/SiO2, Ni/Al2O3, and Ni/SiO2 was performed between 150 - 200 °C, using 60 bar of hydrogen and tetrahydrofuran as solvent. The strength and rate of adsorption and desorption to/from acidic, metallic and interface site structures were determined, using H2-TPR, CO-TPD and NH3-TPD and subsequent regression analysis of the results by numerical modelling and optimisation. The resulting parameters were sequentially used in the generalized micro-kinetic model to quantify the contribution of the active metal (Ni, Pd, or Ru), support (Al2O3 or SiO2), interphase sites and their relationship on catalyst activity and selectivity. Evaluation of morphological and structural characteristics, adsorption/desorption and intrinsic reaction kinetics has indicated that the coverage of acidic sites (on alumina or silica) facilitated yielding ring hydrogenation and inhibited deoxygenation, decarbonylation and cyclic compound opening. The rates for aromatics or aldehyde functional groups were, nonetheless, affected in a different order. The used and developed methods and findings of this PhD offer useful guidelines for transforming furfural into high-value chemicals through catalytic hydrotreatment, with significant implications for future research and industrial applications.
Ključne besede: lignocellulosic biomass, furfural, catalytic hydrogenation, micro-kinetic mass transfer model, reaction kinetics, first-principle methods, furfuryl alcohol, tetrahydrofurfuryl alcoholv, dissertations
Objavljeno v RUNG: 08.11.2024; Ogledov: 1091; Prenosov: 23
Celotno besedilo (9,22 MB)