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Opis: Organic aerosol (OA) data acquired by the Aerosol Mass Spectrometer (AMS) in 37 field campaigns were deconvolved into hydrocarbon-like OA (HOA) and several types of oxygenated OA (OOA) components. HOA has been linked to primary combustion emissions (mainly from fossil fuel) and other primary sources such as meat cooking. OOA is ubiquitous in various atmospheric environments, on average accounting for 64%, 83% and 95% of the total OA in urban, urban downwind, and rural/remote sites, respectively. A case study analysis of a rural site shows that the OOA concentration is much greater than the advected HOA, indicating that HOA oxidation is not an important source of OOA, and that OOA increases are mainly due to SOA. Most global models lack an explicit representation of SOA which may lead to significant biases in the magnitude, spatial and temporal distributions of OA, and in aerosol hygroscopic properties.
Najdeno v: ključnih besedah
Ključne besede: atmospheric aerosol, secondary organic aerosols, primary organic aerosols, aerodyne aerosol mass spectrometer
Objavljeno: 11.04.2021; Ogledov: 1285; Prenosov: 0
Polno besedilo (1,15 MB)

Opis: An Aerodyne Aerosol Mass Spectrometer (AMS) was deployed at the CENICA Supersite, during the Mexico City Metropolitan Area field study (MCMA-2003) from 31 March-4 May 2003 to investigate particle concentrations, sources, and processes. The AMS provides real time information on mass concentration and composition of the non-refractory species in particulate matter less than 1 mu m (NR-PM1) with high time and size-resolution. In order to account for the refractory material in the aerosol, we also present estimates of Black Carbon (BC) using an aethalometer and an estimate of the aerosol soil component obtained from Proton-Induced X-ray Emission Spectrometry (PIXE) analysis of impactor substrates. Comparisons of AMS + BC + soil mass concentration with other collocated particle instruments (a LASAIR Optical Particle Counter, a PM2.5 Tapered Element Oscillating Microbalance (TEOM), and a PM2.5 DustTrak Aerosol Monitor) show that the AMS + BC + soil mass concentration is consistent with the total PM2.5 mass concentration during MCMA-2003 within the combined uncertainties. In Mexico City, the organic fraction of the estimated PM2.5 at CENICA represents, on average, 54.6% (standard deviation sigma=10%) of the mass, with the rest consisting of inorganic compounds ( mainly ammonium nitrate and sulfate/ammonium salts), BC, and soil. Inorganic compounds represent 27.5% of PM2.5 (sigma=10%); BC mass concentration is about 11% (sigma=4%); while soil represents about 6.9% (sigma=4%). Size distributions are presented for the AMS species; they show an accumulation mode that contains mainly oxygenated organic and secondary inorganic compounds. The organic size distributions also contain a small organic particle mode that is likely indicative of fresh traffic emissions; small particle modes exist for the inorganic species as well. Evidence suggests that the organic and inorganic species are not always internally mixed, especially in the small modes. The aerosol seems to be neutralized most of the time; however, there were some periods when there was not enough ammonium to completely neutralize the nitrate, chloride and sulfate present. The diurnal cycle and size distributions of nitrate suggest local photochemical production. On the other hand, sulfate appears to be produced on a regional scale. There are indications of new particle formation and growth events when concentrations of SO2 were high. Although the sources of chloride are not clear, this species seems to condense as ammonium chloride early in the morning and to evaporate as the temperature increases and RH decreases. The total and speciated mass concentrations and diurnal cycles measured during MCMA-2003 are similar to measurements during a previous field campaign at a nearby location.
Najdeno v: ključnih besedah
Ključne besede: aerosol mass-spectrometer, atmospheric aerosol, atmospheric chemistry, atmospheric physics
Objavljeno: 12.04.2021; Ogledov: 1261; Prenosov: 0
Polno besedilo (2,53 MB)

Opis: Long-range transported free tropospheric aerosol was sampled at the PMO (38°28’15’’N, 28°24’14’’W; 2225 m amsl) on Pico Island of the Azores in the North Atlantic. Filter-collected aerosol during summer 2012 was analysed for organic and elemental carbon, and inorganic ions. The average aerosol ambient concentration was 0.9 µg m-3. Organic aerosol contributed the majority of mass (57%), followed by sulphate (21%) and nitrate (17%). Filter-collected aerosol was positively correlated with on-line aerosol measurements of black carbon, light scattering and number concentration. Water-soluble organic compounds (WSOC) from 9/24 and 9/25 samples collected during a pollution event were analysed with ultrahigh-resolution FT-ICR MS. FLEXPART analysis showed the air masses were very aged (>12 days). ~4000 molecular formulas were assigned to each of the mass spectra between m/z 100-1000. The majority of the assigned molecular formulas have unsaturated structures with CHO and CHNO elemental compositions. WSOC have an average O/C of ~0.45, relatively low compared to O/C of other aged aerosol, which might be the result of evaporation and fragmentation during long-range transport. The increase in aerosol loading during 9/24 was linked to biomass burning emissions from North America by FLEXPART and MODIS fire counts. This was confirmed with WSOC biomass burning markers and with the morphology and mixing state of particles as determined by SEM. The presence of markers characteristic of aqueous-phase reactions of biomass burning phenolic species suggests that the aerosol collected at Pico had undergone cloud processing. The air masses on 9/25 were more aged (~15 days) and influenced by marine emissions, as indicated by organosulphates and species characteristic for marine aerosol (e.g. fatty acids). The change in air masses for the two samples was corroborated by the changes in ozone, ethane, propane, morphology of particles, as well as by FLEXPART. In this presentation we will presents the first detailed molecular characterization of free tropospheric aged aerosol intercepted at the PMO.
Najdeno v: ključnih besedah
Ključne besede: Atmospheric aerosol, Free troposphere, Mass spectrometry, Pico mountain observatory
Objavljeno: 26.05.2021; Ogledov: 1280; Prenosov: 0
Polno besedilo (8,36 MB)

Opis: We analyze 11 years of Fermi-Large Area Telescope (LAT) data corresponding to the sky regions of seven dwarf irregular (dIrr) galaxies. DIrrs are dark matter (DM)-dominated systems, proposed as interesting targets for the indirect search of DM with gamma rays. The galaxies represent interesting cases with a strong disagreement between the density profiles (core versus cusp) inferred from observations and numerical simulations. In this work, we addressed the problem by considering two different DM profiles, based on both the fit to the rotation curve (in this case, a Burkert cored profile) and results from N-body cosmological simulations (i.e., Navarro-Frenk-White cuspy profile). We also include halo substructure in our analysis, which is expected to boost the DM signal by a factor of 10 in halos such as those of dIrrs. For each DM model and dIrr, we create a spatial template of the expected DM-induced gamma-ray signal to be used in the analysis of Fermi-LAT data. No significant emission is detected from any of the targets in our sample. Thus, we compute upper limits on the DM annihilation cross section versus mass parameter space. Among the seven dIrrs, we find IC10 and NGC6822 to yield the most stringent individual constraints, independently of the adopted DM profile. We also produce combined DM limits for all objects in the sample, which turn out to be dominated by IC10 for all DM models and annihilation channels, i.e., b¯b, τ+τ−, and W+W−. The strongest constraints are obtained for b¯b and are at the level of <σv>∼7×10−26 cm3 s−1 at mχ ∼ 6 GeV. Though these limits are a factor of ∼3 higher than the thermal relic cross section at low weakly interacting massive particles masses, they are independent from and complementary to those obtained by means of other targets.
Najdeno v: ključnih besedah
Ključne besede: Dark matter, gamma-ray astronomy, galaxies, astronomical masses and mass distributions
Objavljeno: 26.01.2023; Ogledov: 194; Prenosov: 0
Polno besedilo (1,74 MB)