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1.
Variations in U concentrations and isotope signatures in two Canadian lakes impacted by U mining: A combination of anthropogenic and biogeochemical processes
Wei Wang, Duc Huy Dang, Breda Novotnik, R. Douglas Evans, Thai T. Phan, 2019, izvirni znanstveni članek

Opis: Temporal and vertical variations in uranium (U) concentrations and U isotope (δ238U, ‰) signatures were examined in sediment cores collected seven times over a one year period, from two lakes in Ontario, Canada, which are contaminated with U by historical mining activities. Bow Lake is holomictic, experiencing seasonal anoxia, while the sediments of meromictic Bentley Lake are permanently anoxic. Average annual peak concentrations of U in Bow Lake subsurface sediments were approximately 300 μg L−1 and 600 μg g−1 in porewater and bulk sediments, respectively. Similar ranges of concentrations (900 μg L−1 and 600 μg g−1, respectively) were observed in Bentley Lake sediments. The exceedingly high levels of U observed in the porewaters of both lakes, as well as the seasonal variability in U levels, challenge the traditional paradigm regarding U chemistry, i.e., that reduced U(IV) should be insoluble under anoxic conditions. The average annual δ238U ‰ values at the sediment-water interface of both lakes were similar (i.e., 0.47 ± 0.09‰ and 0.50 ± 0.16‰, relative to IRMM-184). The deep sediments in both Bentley Lake and Bow Lake record U isotope composition with a typical fractionation of 0.6‰ relative to the surface water, confirming authigenic U accumulation, i.e., negligible contribution of particulate material from the tailings. Also, the δ238U values in porewater have an average offset of ca. −0.1‰ relative to bulk sediments in anoxic zones and are reversed in the oxic sediment layer.
Najdeno v: ključnih besedah
Povzetek najdenega: ...Uranium Isotope composition Uranium tailings Biogeochemical cycling Redox chemistry... ...levels, challenge the traditional paradigm regarding U chemistry, i.e., that reduced U(IV) should be insoluble under...
Ključne besede: Uranium Isotope composition Uranium tailings Biogeochemical cycling Redox chemistry
Objavljeno: 09.10.2019; Ogledov: 1368; Prenosov: 0
.pdf Polno besedilo (3,89 MB)

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Immobilization of redox-responsive switches into calixarene-based covalent organic polymers for environmental applications
Ali Trabolsi, Ramesh Jagannathan, Sudhir Kumar Sharma, Dinesh Shetty, Tina Škorjanc, 2017, prispevek na konferenci brez natisa

Najdeno v: ključnih besedah
Povzetek najdenega: ...calixarene, covalent polymers, redox chemistry, chemical switches...
Ključne besede: calixarene, covalent polymers, redox chemistry, chemical switches
Objavljeno: 03.09.2020; Ogledov: 693; Prenosov: 0
.pdf Polno besedilo (373,43 KB)

4.
Redox-Tunable Polycationic Polymers for Environmental Applications
Tina Skorjanc, Goinda Das, Selbi Nuryyeva, Thirumurugan Prakasam, Ali Trabolsi, 2017, objavljeni povzetek znanstvenega prispevka na konferenci

Najdeno v: ključnih besedah
Povzetek najdenega: ...covalent polymers, viologen, redox chemistry, pollutant removal, dye adsorption, iodine capture...
Ključne besede: covalent polymers, viologen, redox chemistry, pollutant removal, dye adsorption, iodine capture
Objavljeno: 10.09.2020; Ogledov: 758; Prenosov: 0
Gradivo ima več datotek! Več...

5.
Introduction of a Redox-Responsive Switch into calix[4]arene-based Covalent Organic Nanosheets for Environmental Applications
Tina Skorjanc, 2018, objavljeni povzetek znanstvenega prispevka na konferenci

Najdeno v: ključnih besedah
Povzetek najdenega: ...redox chemistry, viologen, covalent organic polymers, calixarene, dye adsorption,...
Ključne besede: redox chemistry, viologen, covalent organic polymers, calixarene, dye adsorption, iodine adsorption
Objavljeno: 11.09.2020; Ogledov: 755; Prenosov: 0
.pdf Polno besedilo (2,11 MB)

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