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Gases
Alojz Kodre, Iztok Arčon, Jana Padežnik Gomilšek, 2024, znanstveni sestavek v slovarju, enciklopediji, leksikonu

Opis: X-ray absorption spectroscopy of gases is seldom used for structural analysis, except in as much as the extended X-ray absorption fine-structure (EXAFS) signal is used to monitor some specific molecular process. Gas spectroscopy, however, has been the main tool in the systematic study of higher-order photoabsorption processes, multielectron photoexcitations (MEEs), which were introduced with an experiment at the K edge of argon. Along with noble gases, where MEEs are studied in the pure form, free of the structural signal, measurements have been extended to monatomic metal vapours, although at the cost of considerable experimental difficulties. Several types of absorption cells have been devised, among them the ceramic double cell and the heat-pipe cell for experiments in the low-energy region. In a high-temperature oven with considerable technical refinement, edge profiles of nonvolatile metals were measured up to 2500 K. Edge profiles and MEEs, which are strongly dependent on electron correlation, provide sensitive tests of the theory of atomic and molecular structure.
Ključne besede: X-ray absorption spectroscopy, absorption cells, gas and vapour samples, multielectron photoexcitation, effects of electron correlation
Objavljeno v RUNG: 05.09.2024; Ogledov: 564; Prenosov: 4
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Contributed talk at the European Astronomical Society Annual Meeting 2023 : The rise and fall of the iron-rich nuclear transient PS16dtm
Tanja Petrushevska, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: nuclear transients, photometry, spectroscopy, EAS
Objavljeno v RUNG: 19.07.2023; Ogledov: 1698; Prenosov: 3
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Voltage-dependent FTIR and 2D infrared spectroscopies within the electric double layer using a plasmonic and conductive electrode
Nan Yang, Matthew J. Ryan, Minjung Son, Andraž Mavrič, Martin Zanni, 2023, izvirni znanstveni članek

Opis: Strong electric fields exist between the electric double layer and charged surfaces. These fields impact molecular structures and chemistry at interfaces. We have developed a transparent electrode with infrared plasmonic enhancement sufficient to measure FTIR and two-dimensional infrared spectra at submonolayer coverages on the surface to which a voltage can be applied. Our device consists of an infrared transparent substrate, a 10–20 nm layer of conductive indium tin oxide (ITO), an electrically resistive layer of 3–5 nm Al2O3, and a 3 nm layer of nonconductive plasmonic gold. The materials and thicknesses are set to maximize the surface number density of the monolayer molecules, electrical conductivity, and plasmonic enhancement while minimizing background signals and avoiding Fano line shape distortions. The design was optimized by iteratively characterizing the material roughness and thickness with atomic force microscopy and electron microscopy and by monitoring the plasmon resonance enhancement with spectroscopy. The design is robust to repeated fabrication. This new electrode is tested on nitrile functional groups using a monolayer of 4-mercaptobenzonitrile as well as on CO and CC stretching modes using 4-mercaptobenzoic acid methyl ester. A voltage-dependent Stark shift is observed on both monolayers. We also observe that the transition dipole strength of the CN mode scales linearly with the applied voltage, providing a second way of measuring the surface electric field strength. We anticipate that this cell will enable many new voltage-dependent infrared experiments under applied voltages.
Ključne besede: two-dimensional infrared spectroscopy, infrared transparent substrate, voltage-dependent infrared experiments
Objavljeno v RUNG: 24.02.2023; Ogledov: 1964; Prenosov: 6
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Cationic polymer thin films for electrochemical detection of bacteria
Tina Škorjanc, 2022, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: sensors, electrochemical impedance spectroscopy, porous materials, E. coli
Objavljeno v RUNG: 06.12.2022; Ogledov: 2499; Prenosov: 7
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