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14. Air-water interface-assisted synthesis and charge transport characterization of quasi-2d polyacetylene films with enhanced electron mobility via ring-opening polymerization of pyrroleKejun Liu, Nadiia Pastukhova, Egon Pavlica, Gvido Bratina, Xinliang Feng, 2024, other component parts Abstract: Water surfaces catalyze some organic reactions more effectively, making them unique for 2D organic material synthesis. This report introduces a new synthesis method via surfactant-monolayer-assisted interfacial synthesis on water surfaces for ring-opening polymerization of pyrrole, producing distinct polypyrrole derivatives with polyacetylene backbones and ionic substitutions. The synthesis result in quasi 2D polyacetylene (q2DPA) film with enhanced charge transport behavior. We employed time-of-flight photoconductivity (TOFP) measurements using pulsed laser light of tunable wavelength for photoexcitation of the charge carriers within the q2DPA film. The charge transport was measured in the lateral direction as a function of external bias voltage ranging from 0 V to 200 V. We observed high electron mobility ({\mu}) of q2DPA reaching values of 375 cm2 V-1 s-1 at bias voltage Vb = -20V and photon energy of 3.8 eV.
Keywords: air-water interface-assisted synthesis, time-of-flight photoconductivity, 2D polymers, quasi 2D polyacetylene, q2DPA
Published in RUNG: 09.04.2024; Views: 226; Downloads: 2
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15. "I've always spoke like this, you see" : preterite-to-participle leveling in American and British EnglishesAlicia Chatten, Kimberley Baxter, Erwanne Mas, Jailyn Peña, Guy Tabachnick, Daniel Duncan, Laurel MacKenzie, 2024, original scientific article Abstract: Some English verbs use distinct forms for the preterite (i.e., simple past; e.g., I broke the door) and the past participle (e.g., I’ve broken the door). These verbs may variably show use of the preterite form in place of the participle (e.g., I’ve broke the door), which the authors call participle leveling. This article contributes the first detailed variationist study of participle leveling by investigating the phenomenon in perfect constructions using data collected from three corpora of conversational speech: two of American English and one of British English. A striking degree of similarity is found between the three corpora in both the linguistic and the extralinguistic constraints on variation. Constraints on participle leveling include tense of the perfect construction, verb frequency, and phonological similarity between preterite and participle forms. The variable is stable in real time and socially stratified. The article relates the findings to theoretical linguistic treatments of the variation and to questions of its origin and spread in Englishes transatlantically.
Keywords: morphological variation, analogical leveling, American English, British English
Published in RUNG: 08.04.2024; Views: 223; Downloads: 2
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17. Aromatic characterization of Graševina wines from Slavonia and Podunavlje sub-regionsMitja Martelanc, Guillaume Antalick, Tatjana Radovanović, Branka Mozetič Vodopivec, Melita Sternad Lemut, Ahmad Hosseini, Valentina Obradović, Josip Mesić, Lorena Butinar, 2024, original scientific article Abstract: This study investigated the chemical aromatic profiles of 60 volatile organic compounds (VOCs), including 21 terpenes, 6 norisoprenoids, 6 volatile phenols, 4 C-6 alcohols, and 23 esters, in Graševina wines originating from Slavonia and Podunavlje sub-regions (Croatia). Headspace solid-phase microextraction gas chromatography coupled with mass spectrometric detection (HS-SPME-GCMS) was used to assess 60 VOCs, and a novel HS-SPME-GCMS method for the determination of terpenes and norisoprenoids was developed and validated. Statistical analysis also found no significant differences between VOCs present in Graševina wines and others wines (Chardonnay and Pinot gris); nonetheless, comparison of VOC fingerprints between different wines from the same producer showed that four terpenes (α-terpinene, γ-terpinene, 1,4-cineol, and 4-terpineol) were present in higher amounts in Graševina wines when compared to other wines. By exclusively examining VOCs within Graševina wines through the utilization of a heatmap and hierarchical clustering, a distinct visualization of samples and VOCs emerged, highlighting the vintage effect. Simultaneously, a partial least squares discriminant analysis model was developed with a confidence interval of 95%, demonstrating a noticeable distinction between samples originating from the western and eastern regions. Furthermore, by employing the heatmap using only VOCs from the terpene and norisoprenoidic groups, a clear separation of samples into two groups was observed based on geographical origin; namely, higher concentrations of norisoprenoids and terpenes were observed in the Slavonia sub-region. These results suggest that terpenes and norisoprenoids to a lower extent may be valuable aromatic markers for the regional typicality of Graševina wines.
Keywords: Graševina–Welschriesling, aromatic profiling, HS-SPME-GCMS, terpenes
Published in RUNG: 08.04.2024; Views: 233; Downloads: 5
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18. Sentence comprehension test for Russian : a tool to assess syntactic competenceDaria Chernova, Artem Novozhilov, Natalia Slioussar, 2023, review article Abstract: Although all healthy adults have advanced syntactic processing abilities in their native language, psycholinguistic studies report extensive variation among them. However, very few tests were developed to assess this variation, presumably, because when adult native speakers focus on syntactic processing, not being distracted by other tasks, they usually reach ceiling performance. We developed a Sentence Comprehension Test for the Russian language aimed to fill this gap. The test captures variation among participants and does not show ceiling effects. The Sentence Comprehension Test includes 60 unambiguous grammatically complex sentences and 40 control sentences that are of the same length, but are syntactically simpler. Every sentence is accompanied by a comprehension question targeting potential syntactic processing problems and interpretation errors associated with them. Grammatically complex sentences were selected on the basis of the previous literature and then tested in a pilot study. As a result, six constructions that trigger the largest number of errors were identified. For these constructions, we also analyzed which ones are associated with the longest word-by-word reading times, question answering times and the highest error rates. These differences point to different sources of syntactic processing difficulties and can be relied upon in subsequent studies. We conducted two experiments to validate the final version of the test. Getting similar results in two independent experiments, as well as in two presentation modes (reading and listening modes are compared in Experiment 2) confirms its reliability. In Experiment 1, we also showed that the results of the test correlate with the scores in the verbal working memory span test.
Keywords: syntax, comprehension, Russian language, psycholinguistics
Published in RUNG: 05.04.2024; Views: 281; Downloads: 3
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