31. AleksandrinkeKatja Mihurko Poniž, Matej Kočevar, Gregor Kerševan, Narvika Bovcon, zaključena znanstvena zbirka podatkov ali korpus Opis: Zbirka podatkov in fotografij Aleksandrinke je nastala v okviru projekta programske sheme “Projektno delo z negospodarskim in neprofitnim sektorjem – Študentski inovativni projekti za družbeno korist 2016–2018”.
V interdisciplinarnem projektu so študenti in študentke ustvarili_e spletno stran s podatkovno zbirko o aleksandrinkah, vanjo so vpisali_e podatke o aleksandrinkah, ki jih je pridobilo Društvo za ohranjanje kulturne dediščine aleksandrink. Fotografirali_e so predmete, ki so pripadali aleksandrinkam, in digitalizirali_e del zbirke fotografij, ki jih hrani Društvo za ohranjanje kulturne dediščine aleksandrink. Najdeno v: osebi Ključne besede: aleksandrinke Objavljeno: 08.01.2019; Ogledov: 2446; Prenosov: 0 |
32. Effect of Na, Cs and Ca on propylene epoxidation selectivity over CuOx/SiO2 catalysts studied by catalytic tests, in-situ XAS and DFTJanvit Teržan, Matej Huš, Iztok Arčon, Blaž Likozar, Petar Djinović, 2020, izvirni znanstveni članek Opis: This research focuses on epoxidation of propylene over pristine, Na, Ca and Cs modified
CuOx/SiO2 catalysts using O2. The selectivity of the reaction is analyzed using a combination
of catalytic tests, in-situ XAS and DFT calculations. The initially present subnanometer CuO
clusters are present in all catalysts which re-disperse/flatten during reaction. During catalytic
reaction, the Cu1+ becomes the predominant oxidation state. There is no correlation between
propylene oxide (PO) selectivity and copper oxidation state. DFT analysis of the propylene
reaction pathway revealed that Na, Cs, and Ca addition decreases the bonding strength of
propylene to CuO and decreases the O2 activation barrier, while simultaneously increase the
exothermicity of O2 dissociation. The Na induced Cu-O bond modification decreases the
activation barrier from 0.87 to 0.71 eV for the oxametallacycle (OMC) ring closure (first step
in the reaction pathway favoring selectivity towards PO) compared to pristine 5Cu catalyst.
At the same time, we observed an increase (from 0.45 to 0.72 eV) of the barrier for the
abstraction of allylic hydrogen. The opposite effect is achieved by Ca addition: the activation
barrier for OMC ring closure increases to 1.08 eV and that for allylic hydrogen stripping
decreases to 0.16 eV. Najdeno v: osebi Ključne besede: Alkali modification, propylene epoxidation, reaction mechanism, copper oxide, activation barrier. Objavljeno: 05.06.2020; Ogledov: 2000; Prenosov: 0
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33. CO[sub]2 activation over nanoshaped CeO[sub]2 decorated with nickel for low-temperature methane dry reformingKristijan Lorber, Janez Zavašnik, Iztok Arčon, Matej Huš, Janvit Teržan, Blaž Likozar, Petar Djinović, izvirni znanstveni članek Opis: Dry reforming of methane (DRM) is a promising way to
convert methane and carbon dioxide into H2 and CO (syngas). CeO2
nanorods, nanocubes, and nanospheres were decorated with 1−4 wt % Ni.
The materials were structurally characterized using TEM and in situ
XANES/EXAFS. The CO2 activation was analyzed by DFT and
temperature-programmed techniques combined with MS-DRIFTS. Synthesized CeO2 morphologies expose {111} and {100} terminating facets,
varying the strength of the CO2 interaction and redox properties, which
influence the CO2 activation. Temperature-programmed CO2 DRIFTS
analysis revealed that under hydrogen-lean conditions mono- and bidentate
carbonates are hydrogenated to formate intermediates, which decompose
to H2O and CO. In excess hydrogen, methane is the preferred reaction
product. The CeO2 cubes favor the formation of a polydentate carbonate
species, which is an inert spectator during DRM at 500 °C. Polydentate covers a considerable fraction of ceria’s surface, resulting in
less-abundant surface sites for CO2 dissociation Najdeno v: osebi Ključne besede: surface carbonates, in situ characterization, Ni XANES, Ni EXAFS, spectator species, CeO2 nanoshapes, CO2 activation Objavljeno: 13.07.2022; Ogledov: 522; Prenosov: 0
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35. Hidden black carbon air pollution in hilly rural areas - a case study of Dinaric depressionKristina Glojek, Asta Gregorič, Griša Močnik, Andrea Cuesta-Mosquera, A. Wiedensohler, Luka Drinovec, Matej Ogrin, 2020, izvirni znanstveni članek Opis: Air pollution is not an exclusively urban problem as wood burning is a widespread practice in rural areas. As we lack information on the air quality situation in rural mountainous regions, our aim is to examine equivalent black carbon (eBC) pollution in a typical rural karst area in the settlement of Loški Potok (Slovenia). eBC mass concentrations were measured by Aethalometer (AE-33) at two sites in Retje karst depression. The rural village station was located at the bottom of the karst depression whereas the rural background station was positioned at the top of the hill. We showthe diurnal variation of equivalent black carbon mass concentrations for different seasons. In the populated karst depression, the major source of eBC pollution are households using wood as a heating fuel reaching the highest mass concentrations in winter. Diurnal pattern of eBC from biomass burning and traffic differ due to different source activity and it is influenced by typical formation of a cold air pool from late afternoon until late morning, restricting the dispersion of local emissions. The large difference in mass concentrations between the lowest part of the village (rural station) and the top of the hill (rural background station) indicates that in a vertically stratified and stable atmosphere local sources of black carbon have a major impact onair quality conditions in the area studied. Since in Alpine and Dinaric regions there are many similar inhabited areas, we can expect similar air quality conditions also in other rural hilly areas with limited self-cleaning air capacity. Najdeno v: osebi Ključne besede: air pollution, black carbon, hidden geographies, diurnal variation, biomass burning, relief depressions, Loški Potok, Slovenia Objavljeno: 04.01.2021; Ogledov: 1494; Prenosov: 0
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36. Actual and perceived wood combustion pollution – The case of a rural mountainous areaAlfred Wiedensohler, Hartmut Herrmann, Martina Ristorini, Matej Ogrin, Maik Merkel, Dominik van Pinxteren, Martin Rigler, Dejan Cigale, Thomas Müller, Kay Weinhold, Asta Gregorič, Luka Drinovec, Andrea Cuesta-Mosquera, Honey Dawn Alas, Griša Močnik, Kristina Glojek, 2022, objavljeni povzetek znanstvenega prispevka na konferenci Najdeno v: osebi Ključne besede: local air quality, aerosol measurements, perception, heating habits Objavljeno: 27.02.2023; Ogledov: 130; Prenosov: 0
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37. Analiza vinskega turizma kot priložnost za vinarje vinorodnega okoliša slovenska IstraMatej Zaro, 2021, diplomsko delo Opis: Vinski turizem je hitro rastoča ekonomska panoga, ki bi jo glede na geografske danosti slovenske regije in kakovost pridelanega vina bilo vredno ne samo izkoristiti, temveč tudi poglobiti. V diplomski nalogi predstavljamo in preučujemo vinarstvo ter vinogradništvo v povezavi s turizmom v Sloveniji, s poudarkom na okolišu slovenska Istra. Pod drobnogled vzamemo konzorcij Vin Istre in društvo Vinol, kjer izpostavljamo tako dobre prakse, kakor pomankljivosti. Osredotočimo se na vinske festivale, njihov pomen, s poudarkom na festival maceriranih belih vin Orange Wine Festival Izola. Dotaknemo se tudi svetovnih trendov vinske panoge ter kakšen je bil vpliv pandemije Covid-19 na vinski turizem. V diplomski nalogi predstavljamo podjetje Vina Zaro, njegove začetke in možnosti razvoja za prihodnost. Rdeča nit diplomske naloge je iskanje že delujočih dobrih praks in trendov, ki bodo pripomogle k spremembi odnosa do vinskega turizma in odkrivanju novih aktivnosti za razvoj le-tega. Zavedamo se potrebe po mednarodnosti in zgledovanju po tujih uveljavljenih praksah, vendar prepoznamo jedro razvoja tudi v odnosu do mednarodnih potrošnikov, v lokalnih sortah grozdja, reinterpretaciji tradicionalnih pridelovalnih tehnikah, vrednotenju lastne kulturne dediščine, razširitvi ekološke pridelave in spodbujanju interakcije med različni turističnimi panogami. Najdeno v: osebi Ključne besede: diplomske naloge, vinski turizem, slovenska Istra, vinski festivali, blagovne znamke, Slovenija, vinarstvo Zaro, udomačene sorte Objavljeno: 07.10.2021; Ogledov: 1236; Prenosov: 108
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39. The impact of temperature inversions on black carbon and particle mass concentrations in a mountainous areaMiha Markelj, Maja Remškar, Martin Rigler, Irena Ježek, Kay Weinhold, Matej Ogrin, Asta Gregorič, Luka Drinovec, Andrea Cuesta-Mosquera, Honey Dawn C. Alas, Kristina Glojek, Griša Močnik, 2022, izvirni znanstveni članek Opis: Residential wood combustion is a widespread practice in Europe with a serious impact on air quality, especially in mountainous areas. While there is a significant number of studies conducted in deep urbanized valleys and basins, little is known about the air pollution processes in rural shallow hollows, where around 30 % of the people in mountainous areas across Europe live. We aim to determine the influence of ground temperature inversions on wood combustion aerosol pollution in hilly, rural areas. The study uses Retje karst hollow (Loški Potok, Slovenia) as a representative site for mountainous and hilly rural areas in central and south-eastern Europe with residential wood combustion. Sampling with a mobile monitoring platform along the hollow was performed in December 2017 and January 2018. The backpack mobile monitoring platform was used for the determination of equivalent black carbon (eBC) and particulate matter (PM) mass concentrations along the hollow. To ensure high quality of mobile measurement data, intercomparisons of mobile instruments with reference instruments were performed at two air quality stations during every run. Our study showed that aerosol pollution events in the relief depression were associated with high local emission intensities originating almost entirely from residential wood burning and shallow temperature inversions (58 m on average). The eBC and PM mass concentrations showed stronger associations with the potential temperature gradient (R2=0.8) than with any other meteorological parameters taken into account (ambient temperature, relative humidity, wind speed, wind direction, and precipitation). The strong association between the potential temperature gradient and pollutant concentrations suggests that even a small number of emission sources (total 243 households in the studied hollow) in similar hilly and mountainous rural areas with frequent temperature inversions can significantly increase the levels of eBC and PM and deteriorate local air quality. During temperature inversions the measured mean eBC and PM2.5 mass concentrations in the whole hollow were as high as 4.5±2.6 and 48.0 ± 27.7 µg m−3, respectively, which is comparable to larger European urban centres. Najdeno v: osebi Ključne besede: air pollution, black carbon, sources, temperature inversion, mountainous area Objavljeno: 03.05.2022; Ogledov: 533; Prenosov: 0
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