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Opis: Discriminating the absorption coefficients of aerosol mineral dust and black carbon (BC) in different aerosol size fractions is a challenge because of BC's large mass absorption cross-section compared to dust. Ambient aerosol wavelength dependent absorption coefficients in supermicron and submicron size fractions were determined with a high time resolution. The measurements were performed simultaneously using identical systems at an urban and a regional background site in Qatar. At each site, measurements were taken by co-located Aethalometers, one with a virtual impactor (VI) and the other with a PM1 cyclone to respectively collect super-micron-enhanced and submicron fractions. The combined measurement of aerosol absorption and scattering coefficients enabled the particles to be classified based on their optical properties' wavelength dependence. The classification reveals the presence of BC internally/externally mixed with different aerosols. Helium ion microscopy images provided information concerning the extent of mineral dust in the submicron fraction. The determination of absorption coefficients during dust storms and non-dust periods was used to establish the absorption Ångström exponent for dust and BC. Non-parametric wind regression, potential source contribution function and back-trajectory analysis reveal major regional sources of desert dust associated with north-westerly winds and a minor local dust contribution. In contrast, major BC sources found locally were associated with south-westerly winds with a smaller contribution made by offshore emissions transported by north-easterly and easterly winds. The use of a pair of Aethalometers with VI and PM1 inlets separates contributions of BC and dust to the aerosol absorption coefficient.
Ključne besede: aerosol absorption, black carbon, mineral dust, desert dust, Arabian Peninsula
Objavljeno v RUNG: 29.02.2024; Ogledov: 1837; Prenosov: 11
Celotno besedilo (18,90 MB)
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Opis: The present invention belongs to the field of methods and devices for analysing materials by determining their chemical or physical properties by the use of thermos-optical means. The invention relates to a device and a method for complete carbonaceous aerosol analysis in real time, which is essentially a system combining two different instruments, wherein the first instrument measures total carbon (TC) using flash heating of collected aerosol samples and generation of CO2, while the second instrument performs an optical attenuation analysis at 7 wavelengths from near UV (370 nm) to near IR range (950 nm) in order to characterize a Black Carbon (BC/EC) aerosols accumulated on a glass-fiber/PTFE filter tape. The device, i.e., the system of said instruments, collects and processes collected data of both instruments, wherein said processing may be performed by any of the instruments or by a separate processing means, computer or computer application.
Ključne besede: carbonaceous aerosol, black carbon, total carbon, brown carbon
Objavljeno v RUNG: 02.02.2024; Ogledov: 1513; Prenosov: 12
Celotno besedilo (4,44 MB)
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Opis: Abstract. Recent years have seen an increase in the use of wood for energy production of over 30 %, and this trend is expected to continue due to the current energy crisis and geopolitical instability. At present, residential wood burning (RWB) is one of the most important sources of organic aerosols (OA) and black carbon (BC). While BC is recognized for its large light absorption cross-section, the role of OA in light absorption is still under evaluation due to their heterogeneous composition and source-dependent optical properties. Studies that characterize wood-burning aerosol emissions in Europe typically focus on urban and background sites and only cover BC properties. However, RWB is more prevalent in rural areas, and the present scenario indicates that an improved understanding of the RWB aerosol optical properties and their subsequent connection to climate impacts is necessary for rural areas. We have characterized atmospheric aerosol particles from a central European rural site during wintertime in the village of Retje in Loški Potok, Slovenia, from 01.12.2017 to 07.03.2018. The village experienced extremely high aerosol concentrations produced by RWB and near-ground temperature inversion. The isolated location of the site and the substantial local emissions made it an ideal laboratory-like place for characterizing RWB aerosols with low influence from non-RWB sources under ambient conditions. The mean mass concentrations of OA and BC were 34.8 µg m-3 (max = 271.8 µg m-3) and 3.1 µg m-3 (max = 24.3 µg m-3), respectively. The mean total particle number concentration (10–600 nm) was 9.9 x 103 particles cm-3 (max = 53.5 x 103 particles cm-3). The mean total light absorption coefficient at 370 nm and 880 nm measured by an Aethalometer AE33 were 122.8 Mm-1 and 15.3 Mm-1 and had maximum values of 1103.9 Mm-1 and 179.1 Mm-1, respectively. The aerosol concentrations and absorption coefficients measured during the campaign in Loški Potok were significantly larger than those reported values for several urban areas in the region with larger populations and extent of aerosol sources. Here, considerable contributions from brown carbon (BrC) to the total light absorption were identified, reaching up to 60 % and 48 % in the near UV (370 nm) and blue (470 nm) wavelengths. These contributions are up to three times higher than values reported for other sites impacted by wood-burning emissions. The calculated mass absorption cross-section and the absorption Ångström exponent for RWB OA were MACOA, 370 nm= 2.4 m2 g-1, and AAEBrC, 370–590 nm= 3.9, respectively. Simple forcing efficiency (SFE) calculations were performed as a sensitivity analysis to evaluate the climate impact of the RWB aerosols produced at the study site by integrating the optical properties measured during the campaign. The SFE results show a considerable forcing capacity from the local RWB aerosols, with a high sensitivity to OA absorption properties and a more substantial impact over bright surfaces like snow, typical during the coldest season with higher OA emissions from RWB. Our study's results are highly significant regarding air pollution, optical properties, and climate impact. The findings suggest that there may be an underestimation of RWB emissions in rural Europe and that further investigation is necessary.
Ključne besede: wood-burning aerosols, optical characterization, black carbon, rural areas
Objavljeno v RUNG: 10.01.2024; Ogledov: 1816; Prenosov: 11
Celotno besedilo (1,99 MB)
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Opis: Context. We present the results of the reverberation monitoring of the Mg II broad line and Fe II pseudocontinuum for the luminous quasar CTS C30.10 (z = 0.90052) with the Southern African Large Telescope in 2012–2021. Aims. We aimed at disentangling the Mg II and UV Fe II variability and the first measurement of UV Fe II time delay for a distant quasar. Methods. We used several methods for the time-delay measurements and determined the Fe II and Mg II time delays. We also performed a wavelength-resolved time delay study for a combination of Mg II and Fe II in the 2700–2900 Å rest-frame wavelength range. Results. We obtain a time delay for Mg II of 275.5−19.5+12.4 days in the rest frame, and we have two possible solutions of 270.0−25.3+13.8 days and 180.3−30.0+26.6 in the rest frame for Fe II. Combining this result with the old measurement of Fe II UV time delay for NGC 5548, we discuss for first time the radius-luminosity relation for UV Fe II with the slope consistent with 0.5 within the uncertainties. Conclusions. Because the Fe II time delay has a shorter time-delay component but the lines are narrower than Mg II, we propose that the line-delay measurement is biased toward the part of the broad line region (BLR) facing the observer. The bulk of the Fe II emission may arise from the more distant BLR region, however, the region that is shielded from the observer.
Ključne besede: accretion, accretion disks / quasars: emission lines / quasars: individual: CTS C30.10 / techniques: spectroscopic / techniques: photometric
Objavljeno v RUNG: 13.11.2023; Ogledov: 1794; Prenosov: 5
Celotno besedilo (3,50 MB)
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Objavljeno v RUNG: 19.09.2023; Ogledov: 1800; Prenosov: 9
Celotno besedilo (2,15 MB)
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