Repozitorij Univerze v Novi Gorici

Iskanje po repozitoriju
A+ | A- | Pomoč | SLO | ENG

Iskalni niz: išči po
išči po
išči po
išči po
* po starem in bolonjskem študiju

Opcije:
  Ponastavi


1 - 10 / 15
Na začetekNa prejšnjo stran12Na naslednjo stranNa konec
1.
Gases
Alojz Kodre, Iztok Arčon, Jana Padežnik Gomilšek, 2024, znanstveni sestavek v slovarju, enciklopediji, leksikonu

Opis: X-ray absorption spectroscopy of gases is seldom used for structural analysis, except in as much as the extended X-ray absorption fine-structure (EXAFS) signal is used to monitor some specific molecular process. Gas spectroscopy, however, has been the main tool in the systematic study of higher-order photoabsorption processes, multielectron photoexcitations (MEEs), which were introduced with an experiment at the K edge of argon. Along with noble gases, where MEEs are studied in the pure form, free of the structural signal, measurements have been extended to monatomic metal vapours, although at the cost of considerable experimental difficulties. Several types of absorption cells have been devised, among them the ceramic double cell and the heat-pipe cell for experiments in the low-energy region. In a high-temperature oven with considerable technical refinement, edge profiles of nonvolatile metals were measured up to 2500 K. Edge profiles and MEEs, which are strongly dependent on electron correlation, provide sensitive tests of the theory of atomic and molecular structure.
Ključne besede: X-ray absorption spectroscopy, absorption cells, gas and vapour samples, multielectron photoexcitation, effects of electron correlation
Objavljeno v RUNG: 05.09.2024; Ogledov: 616; Prenosov: 4
URL Povezava na datoteko
Gradivo ima več datotek! Več...

2.
Photoexcitation processes in atoms
Alojz Kodre, Iztok Arčon, Jana Padežnik Gomilšek, 2021, samostojni znanstveni sestavek ali poglavje v monografski publikaciji

Opis: Photoelectric absorption is characterized by a smooth power-law decrease of the cross section with photon energy. Absorption edges reveal rich structure, which continues into the high-energy side. The quasiperiodic signal, superposed onto the smooth basis, due to scattering of the photoelectron on the neighbours of the target atom provides the basis for the structural (XAFS) analysis of the material. Irregular tiny resonances and edges that appear over the same general range as XAFS are recognized as intra-atomic effects: multielectron excitations (MEE) owing to correlated motion in the electronic cloud. The systematic study of MEE began on noble gases and metallic vapours, both of which are gases of free atoms. With some extremely strong MEE, mostly coexcitations of the subvalence d and f electrons, the structural XAFS analysis may be compromised; hence, there is a need to independently determine the MEE signal, the atomic absorption background (AAB) for the analyzed element, and remove it prior to analysis. In view of the scarcity of elements which can practically be prepared in a free-atom gas state, several approaches to approximate the AAB have been developed: analysis of disordered compounds, where the weak and simple XAFS signal can be modelled and removed, and correlation analysis of the absorption spectra of several independent samples, where the AAB is extracted in an iterative procedure.
Ključne besede: photoexcitation, XAFS, multielectron excitations, atomic absorption background
Objavljeno v RUNG: 15.12.2021; Ogledov: 2436; Prenosov: 0
Gradivo ima več datotek! Več...

3.
X-ray absorption spectroscopy set-up for unstable gases: A study of 5p Hydrides
Robert Hauko, Jana Padežnik Gomilšek, Alojz Kodre, Iztok Arčon, 2020, izvirni znanstveni članek

Opis: An absorption cell is constructed for x-ray absorption spectroscopy of reactive, unstable or hazardous gases at room temperature. In conjunction with in-situ micro-synthesis technique relying on handling the gas in syringes it enabled a first measurement of x-ray absorption spectra in the region of K and L edges for the series of hydrides of 5p elements (SnH4, SbH3, TeH2, HI). The signal-to-noise ratio above 103 was achieved, whereby fine detail is discerned in the spectra, in particular the small sharp features above each absorption edge, testifying of coexcitations of outer electrons in the core photoeffect.
Ključne besede: X-ray absorption spectroscopy Micro-synthesis absorption cell Gaseous hydrides Multielectron photoexcitations
Objavljeno v RUNG: 10.02.2020; Ogledov: 4477; Prenosov: 0
Gradivo ima več datotek! Več...

4.
Effects of the molecular potential on coexcitations of valence electrons in the K-shell photoeffect of 3p and 4p elements
Robert Hauko, Jana Padežnik Gomilšek, Alojz Kodre, Iztok Arčon, Giuliana Aquilanti, 2019, izvirni znanstveni članek

Opis: Photoabsorption spectra of gaseous hydrides of 3p (PH3, H2S, HCl) and 4p elements (GeH4, AsH3 , H2Se, HBr) are measured in the energy region within 50 eV above the K edge, to study coexcitations of valence electrons by photoeffect in the K shell. The analysis of the valence coexcitations is extended to Ar, Kr, and SiH4. Relative probabilities and energies of states in the individual coexcitation channels are recovered by modeling the spectral features with a minimal ansatz based on the features in the contiguous noble gas. The extracted parameters are compared to the results of theoretical calculations for molecules (ORCA code) and free atoms (Hartree-Fock code). The experimental results confirm that the valence coexcitations in the 3p and 4p hydride molecules can be satisfactorily described by a two-step process, with the shake of the outer electron following the excitation of the core electron. The total probability—relative to the K-edge jump—of the shake-up processes shows a steady decrease from 19% in Si to 14% in Cl, and from 15% in Ge to 12% in Br. The experimental values for Ar (12%) and Kr (10%) are in accord with the trend. The dominant contribution is the transition to quasiatomic orbitals, in contrast with the deeper coexcitation channels in hydride molecules where transition to molecular orbitals prevails.
Ključne besede: X-ray absorption spectra, gaseous hydrides, 3p K-edge spectra, DFT
Objavljeno v RUNG: 05.09.2019; Ogledov: 3710; Prenosov: 0
Gradivo ima več datotek! Več...

5.
K-edge absorption spectra of isoelectronic gaseous hydrides: a combination of atomic and molecular channels
Robert Hauko, Jana Padežnik Gomilšek, Alojz Kodre, Iztok Arčon, Giuliana Aquilanti, 2018, objavljeni povzetek znanstvenega prispevka na konferenci

Opis: The fine detail in the x-ray absorption spectra in the energy region of absorption edges provides the insight into the mechanism of inner-shell photoexcitation: in particular in spectra of free atoms or simple molecules, the simplest being gaseous hydrides [1-2]. Measured K edge absorption spectra of hydrides of 3p (PH3, H2S in HCl) and 4p (GeH4, AsH3, H2Se, HBr) elements, and published data of 2p hydrides (CH4, NH3, H2O, HF) as well as SiH4 [3-6] and the noble gases at the end of the isoelectronic series (Ne, Ar, Kr) are compared to the respective calculated spectra, obtained by atomic HF86, GRASP codes [7] and molecular DFT (Density functional theory) ORCA code [8]. For a clearer view of intraatomic processes, the weak and simple structural (XAFS) signal of the molecule is removed from the spectra. Among the spectral features below the continuum limit, those with the lowest energy belong to the transition of the core electron to the lowermost free orbitals with the molecular character. They are, as a rule, wider than the transitions to the higher orbitals with prevailing atomic character. The theoretical description with DFT code without specific adaptations is sufficient for a qualitative picture of the pre-edge structure. The fine structure immediately above the K edge stems from the coexcitation of valence electrons. We have proved that the coexcitations can be explained as a two-step process: the inner-shell photoeffect followed by the shake-up of a valence electron predominantly to a free atomic orbital. This process is markedly different from coexcitations of more tightly bound electrons [9]. In the collection of consecutive and homologous data, analyzed by a common procedure, the reaction channels can be identified with better precision and reliability than in analysis of individual spectra. Our analysis showed that the energies and probabilities of single-electron transitions into the molecular orbitals are strongly affected by the symmetry of the molecule, essentially in the same way in 3p and 4p homologues, but not in 2p homologues with a stronger influence of the core charge. In transitions to atomic orbitals the influence of the molecular field is negligible.
Ključne besede: hidridi, rentgenska spektroskopija, XAFS
Objavljeno v RUNG: 12.09.2018; Ogledov: 4800; Prenosov: 0
Gradivo ima več datotek! Več...

6.
K-edge absorption spectra of gaseous hydrides
Alojz Kodre, Robert Hauko, Jana Padežnik Gomilšek, Iztok Arčon, Giuliana Aquilanti, 2018, objavljeni povzetek znanstvenega prispevka na konferenci

Opis: X-ray absorption spectra in the energy region of absorption edges reveal fine details of the mechanism of inner-shell photoexcitation: in particular in spectra of free atoms or simple molecules, the simplest being gaseous hydrides [1-2]. In a collection of data from consecutive and homologous elements, analyzed by a common procedure, the reaction channels can be identified with better precision and reliability than in analysis of individual spectra. Absorption spectra of the hydrides of 3p elements (PH3, H2S in HCl) were measured at the XAFS beamline of the Elettra synchrotron in Trieste: a new type of adjustable absorption cell for measurement of noxious gases at room temperature and at low photon energies was developed for the purpose. For the analysis, data from an earlier experiment on 4p hydrides (GeH4, AsH3, H2Se, HBr), and published data of 2p hydrides (CH4, NH3, H2O, HF) [3-4] as well as SiH4 and the noble gases concluding the isoelectronic series (Ne, Ar, Kr) were adopted. The spectra are compared to respective calculated spectra, obtained by atomic HF86, GRASP codes and molecular DFT (Density functional theory) ORCA code [5]. Our analysis of the pre-edge structures showed that the energies and probabilities of singleelectron transitions into the lowermost orbitals with the molecular character were strongly affected by the symmetry of the molecule, essentially in the same way in 3p and 4p homologues, but not in 2p homologues with a stronger influence of the core charge. In transitions to higher orbitals with prevailing atomic character the influence of the molecular field is negligible. The fine structure immediately above the K edge stems from the coexcitation of valence electrons. These coexcitations can be explained as a two-step process: the inner-shell photoeffect followed by the shake-up of a valence electron predominantly to a free atomic orbital. The process is markedly different from coexcitations of more tightly bound electrons [3]. The results of relative shake-up probabilities can be compared to results of emission spectroscopies, the probabilities of double excitation to bound states show a correlation with the dissociation probability of the molecule.
Ključne besede: večelektronske vzbuditve, hidridi, rentgenska absorpcijska spektroskopija
Objavljeno v RUNG: 12.09.2018; Ogledov: 5167; Prenosov: 0
Gradivo ima več datotek! Več...

7.
Nickel coordination in hyperaccumulator plants studied by XANES and EXAFS
Jana Padežnik Gomilšek, Katarina Vogel-Mikuš, Alojz Kodre, Iztok Arčon, 2018, objavljeni povzetek znanstvenega prispevka na konferenci

Ključne besede: nickel, hyperaccumulator plants
Objavljeno v RUNG: 12.09.2018; Ogledov: 3875; Prenosov: 0
Gradivo ima več datotek! Več...

8.
Edge profiles in K shell photoabsorption spectra of gaseous hydrides of 3p elements and homologues
Robert Hauko, Jana Padežnik Gomilšek, Alojz Kodre, Iztok Arčon, Giuliana Aquilanti, izvirni znanstveni članek

Opis: Photoabsorption spectra of gaseous hydrides of 3p elements (PH3, H2S, HCl) are measured in the energy region of photoexcitations pertaining to K edge. The analysis of the edge profile is extended to hydrides of 4p series (GeH4, AsH3, H2Se, HBr) from an earlier experiment, and to published spectra of 2p hydrides (CH4, NH3, H2O, HF) and noble gases Ar, Kr and Ne and SiH4. The edge profiles are modelled with a linear combination of lorentzian components, describing excitations to individual bound states and to continuum. Transition energies and probabilities are also calculated in the non-relativistic molecular model of the ORCA code, in good agreement with the experiment. Edge profiles in the heavier homologues are closely similar, the symmetry of the molecule governs the transitions to the lowest unoccupied orbitals. In 2p series the effect of the strong nuclear potential prevails. Transitions to higher, atomic-like levels remain very much the same as in free atoms.
Ključne besede: X-ray absorption spectra, gaseous hydrides, 3p K-edge spectra, DFT
Objavljeno v RUNG: 23.08.2017; Ogledov: 4399; Prenosov: 0
Gradivo ima več datotek! Več...

9.
Atomic effects in EXAFS structural analysis of redox I[sup]-/I[sup]-[sub]3 solid state electrolites
Iztok Arčon, Jana Padežnik Gomilšek, Alojz Kodre, 2006, izvirni znanstveni članek

Opis: Atomic effects in EXAFS structural analysis of redox Isup-/Isup-sub3 solid state electrolites
Objavljeno v RUNG: 17.05.2016; Ogledov: 4866; Prenosov: 21
URL Povezava na celotno besedilo

10.
Specific EXAFS tools in analysis of MoSI nanowires
Anton Meden, Alojz Kodre, Iztok Arčon, Jana Padežnik Gomilšek, Dragan Mihailović, 2006, izvirni znanstveni članek

Opis: Specific EXAFS tools in analysis of MoSI nanowires
Ključne besede: EXAFS, MoSI, nanocevke, struktura
Objavljeno v RUNG: 17.05.2016; Ogledov: 5757; Prenosov: 21
URL Povezava na celotno besedilo

Iskanje izvedeno v 0.05 sek.
Na vrh