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Opis: Carboxylic acids are known to assume a variety of configurations on metallic surfaces. In particular oxalic acid on the Cu(110) surface has been proposed to assume a number of upright configurations. Here we explore with DFT calculations the possible structures that oxalic acid can form on copper 110 at different protonation states, with particular attention at the possibility of forming structures composed of vertically standing molecules. In its fully protonated form it is capable of anchoring itself on the surface thanks to one of its hydrogen-free oxygens. We show the monodeprotonated upright molecule with two oxygens anchoring it on the surface to be the lowest energy conformation of a single oxalic molecules on the Cu(110) surface. We further show that it is possible for this configuration to form dense hexagonally arranged patterns in the unlikely scenario in which adatoms are not involved.
Ključne besede: oxalic acid, oxalate, cu(110), copper, surface, adsorption, density functional theory, DFT
Objavljeno v RUNG: 11.10.2016; Ogledov: 5860; Prenosov: 0
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Opis: The azimuthal asymmetry in the risetime of signals in Auger surface detector stations is a source of information on shower development. The azimuthal asymmetry is due to a combination of the longitudinal evolution of the shower and geometrical effects related to the angles of incidence of the particles into the detectors. The magnitude of the effect depends upon the zenith angle and state of development of the shower and thus provides a novel observable, (secθ)max, sensitive to the mass composition of cosmic rays above 3×1018  eV. By comparing measurements with predictions from shower simulations, we find for both of our adopted models of hadronic physics (QGSJETII-04 and EPOS-LHC) an indication that the mean cosmic-ray mass increases slowly with energy, as has been inferred from other studies. However, the mass estimates are dependent on the shower model and on the range of distance from the shower core selected. Thus the method has uncovered further deficiencies in our understanding of shower modeling that must be resolved before the mass composition can be inferred from (secθ)max.
Ključne besede: ultra-high energy cosmic rays (UHECR), UHECR mass composition, Pierre Auger Observatory, extensive air showers, Auger Surface Detector signals risetime, azimuthal symmetry
Objavljeno v RUNG: 15.04.2016; Ogledov: 6643; Prenosov: 0
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Opis: The Pierre Auger Observatory (Auger) in Mendoza, Argentina and the Telescope Array (TA) in Utah, USA aim at unraveling the origin and nature of Ultra-High Energy Cosmic Rays (UHECR). At present, there appear to be subtle differences between Auger and TA results and interpretations. Joint working groups have been established and have already reported preliminary findings. From an experimental standpoint, the Surface Detectors (SD) of both experiments make use of different detection processes not equally sensitive to the components of the extensive air showers making it to the ground. In particular, the muonic component of the shower measured at ground level can be traced back to the primary composition, which is critical for understanding the origin of UHECRs. In order to make direct comparisons between the SD detection techniques used by Auger and TA, a joint SD experimental research program is being developed. In the first phase, two Auger SD stations were deployed at the TA Central Laser Facility to compare station-level responses. This paper concentrates on the results obtained with the first Auger SD station (an “Auger North” design), which has been operating since October 2014. The second Auger SD station, identical to the ones being operated at Auger in Argentina (an “Auger South” design), was just deployed in June 2015. The second phase of this research program will be to co-locate six Auger North SD stations with TA stations in the field to compare event-level responses.
Ključne besede: Ultra-High Energy Cosmic Rays, Pierre Auger Observatory, Telescope Array, extensive air showers, secondary cosmic rays, muonic shower component, surface detectors
Objavljeno v RUNG: 08.03.2016; Ogledov: 5898; Prenosov: 191
Celotno besedilo (1,42 MB)

Opis: The azimuthal asymmetry in the risetime of signals in Auger surface detector stations is a source of information on shower development. The azimuthal asymmetry is due to a combination of the longitudinal evolution of the shower and geometrical effects related to the angles of incidence of the particles into the detectors. The magnitude of the effect depends upon the zenith angle and state of development of the shower and thus provides a novel observable sensitive to the mass composition of cosmic rays above 3 × 10[sup]18 eV. By comparing measurements with predictions from shower simulations, we find for both of our adopted models of hadronic physics (QGSJetII- 04 and Epos-LHC) an indication that the mean cosmic-ray mass increases with energy, as has been inferred from other studies. However the absolute values derived for the mass are dependent on the shower model and on the range of distance from the shower core selected. Thus the method has uncovered further deficiencies in our understanding of shower modelling that must be resolved before the mass composition can be inferred from (sec θ)max.
Ključne besede: Pierre Auger Observatory, Surface Detector, risetime of detector signal, azimuthal asymmetry, extensive air showers
Objavljeno v RUNG: 03.03.2016; Ogledov: 5864; Prenosov: 199
Celotno besedilo (243,04 KB)