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Opis: Abstract In response to the EU's REPowerEU initiative (COM (2022) 108) which encourages an increase in biogas production by 20% in member states by 2030 to boost energy independence, it has become essential to identify sustainable alternatives to traditional feedstocks for biogas production, especially in the EU Member states where there is still high dependence on corn silage as the main raw material in biogas plants. While corn silage, predominantly used in the European biogas plants today, serves primarily for the livestock sector, alternative sources need to be explored. Therefore, this study aimed to evaluate the potential of Arundo donax, a perennial energy crop, as an alternative feedstock in a continuous anaerobic process. The biogas yield and its quality, characterized by CH4, CO2, H2S and O2 content, were determined during a continuous process with A. donax, compared with two mixed feedstocks of A. donax and corn silage over a 5‐month period in a continuous anaerobic digestion process. The results revealed that A. donax exhibits a biogas yield and methane content comparable to corn silage, indicating its potential as a viable and sustainable alternative feedstock for biogas production.
Ključne besede: Arundo donax L., biogas quality, continuous anaerobic digestion, corn silage, perennial energy crops, sustainable biogas production
Objavljeno v RUNG: 18.03.2025; Ogledov: 141; Prenosov: 0
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Opis: The Zimm-Bragg (ZB) model serves as a fundamental framework for elucidating conformational transitions in biopolymers, offering simplicity and efficacy in processing experimental data. This study provides a comprehensive review of the Zimm-Bragg model and its Hamiltonian formulation, with particular emphasis on incorporating water interactions and chain size effects into the computational framework. We propose a modified ZB model that accounts for water-polypeptide interactions, demonstrating its ability to describe phenomena such as cold denaturation and helix-coil transitions. In the realm of NanoBioTechnologies, the manipulation of short polypeptide chains is commonplace. Experimental investigation of these chains in vitro often relies on techniques like Circular Dichroism (CD) and timeresolved infrared spectroscopy. Determining interaction parameters necessitates processing the temperature dependence of the normalized degree of helicity through model fitting. Leveraging recent advancements in the Hamiltonian formulation of the Zimm and Bragg model, we explicitly incorporate chain length and solvent effects into the theoretical description. The resulting expression for helicity degree adeptly fits experimental data, yielding hydrogen bonding energies and nucleation parameter values consistent with field standards. Differential Scanning Calorimetry (DSC) stands as a potent tool for measuring the specific heat profile of materials, including proteins. However, relating the measured profile to microscopic properties requires a suitable model for fitting. We propose a novel algorithm for processing DSC experimental data based on the ZB theory of protein folding in water. This approach complements the classical two-state paradigm and provides insights into protein-water and intraprotein hydrogen bonding energies. An analytical expression for heat capacity, considering water interaction, is derived and successfully applied to fit numerous DSC experimental datasets reported in the literature. Additionally, we compare this approach with the classical two-state model, demonstrating its efficacy in fitting DSC data. Furthermore, we have developed and launched a free online tool for processing CD and DSC experimental data related to protein folding, aiming to support scientific research.
Ključne besede: Zimm-Bragg model, conformational transitions, helix-coil transitions, cold denaturation, circular dichroism, differential scanning calorimetry, protein folding, water-protein interaction, hydrogen bonding energy, degree of helicity, short polypeptide chains, protein heat capacity, protein data analysis, dissertations
Objavljeno v RUNG: 27.01.2025; Ogledov: 553; Prenosov: 11
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Opis: We present measurements of the atmospheric depth of the shower maximum Xmax, inferred for the first time on an event-by-event level using the Surface Detector of the Pierre Auger Observatory. Using deep learning, we were able to extend measurements of the Xmax distributions up to energies of 100 EeV (10[sup]20 eV), not yet revealed by current measurements, providing new insights into the mass composition of cosmic rays at extreme energies. Gaining a 10-fold increase in statistics compared to the Fluorescence Detector data, we find evidence that the rate of change of the average Xmax with the logarithm of energy features three breaks at 6.5 ± 0.6 (stat) ± 1 (sys) EeV, 11 ± 2 (stat) ± 1 (sys) EeV, and 31 ± 5 (stat) ± 3 (sys) EeV, in the vicinity to the three prominent features (ankle, instep, suppression) of the cosmic-ray flux. The energy evolution of the mean and standard deviation of the measured Xmax distributions indicates that the mass composition becomes increasingly heavier and purer, thus being incompatible with a large fraction of light nuclei between 50 EeV and 100 EeV.
Ključne besede: ultra-high-energy cosmic rays (UHECRs), extensive air showers, Pierre Auger Observatory, UHECR mass composition, depth of the shower maximum, fluorescence detector, surface detector, deep learning
Objavljeno v RUNG: 20.01.2025; Ogledov: 497; Prenosov: 5
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Opis: The discovery of gravitational waves, high-energy neutrinos or the very-high-energy counterpart of gamma-ray bursts has revolutionized the high-energy and transient astrophysics community. The development of new instruments and analysis techniques will allow the discovery and/or follow-up of new transient sources. We describe the prospects for the Cherenkov Telescope Array (CTA), the next-generation ground-based gamma-ray observatory, for multi-messenger and transient astrophysics in the decade ahead. CTA will explore the most extreme environments via very-high-energy observations of compact objects, stellar collapse events, mergers and cosmic-ray accelerators.
Ključne besede: multi-messenger astrophysics, gravitational waves, very-high-energy (VHE) gamma rays, cosmic rays, VHE neutrinos, transient astrophysical phenomena, Cherenkov Telescope Array Observatory
Objavljeno v RUNG: 13.01.2025; Ogledov: 439; Prenosov: 7
Celotno besedilo (6,21 MB)
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Opis: This white paper briefly summarizes the importance of the study of relativistic cosmic rays, both as a constituent of our Universe, and through their impact on stellar and galactic evolution. The focus is on what can be learned over the coming decade through ground-based gamma-ray observations over the 20 GeV to 300 TeV range. Submitted as input to ASTRONET Science Vision and Infrastructure roadmap on behalf of the CTA consortium.
Ključne besede: High Energy Astrophysical Phenomena, cosmic rays, supernova remnants, Cherenkov Telescope Array Observatory
Objavljeno v RUNG: 09.01.2025; Ogledov: 486; Prenosov: 8
Celotno besedilo (7,45 MB)
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