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53. Giant magneto–electric coupling in 100 nm thick Co capped by ZnO nanorodsGiovanni Vinai, Barbara Ressel, Piero Torelli, Federico Loi, Benoit Gobaut, Regina Ciancio, Barbara Casarin, Antonio Caretta, Luca Capasso, Fulvio Parmigiani, Francesco Cugini, Massimo Solzi, Marco Malvestuto, Roberta Ciprian, 2018, izvirni znanstveni članek Ključne besede: ZnO nanorods, Cobalt, X-rays absorption near edge spectroscopy
Objavljeno v RUNG: 07.02.2018; Ogledov: 3905; Prenosov: 0
Gradivo ima več datotek! Več... |
54. Conclusively Addressing the CoPc Electronic Structure: A Joint Gas- Phase and Solid-State Photoemission and Absorption Spectroscopy StudyTeng Zhang, I.E. Brumboiu, Valeria Lanzillotto, J. Lüder, C. Grazioli, Erika Giangrisostomi, R. Ovsyannikov, Y. Sassatelli, Ieva Bidermane, Monica de Simone, Marcello Coreno, Barbara Ressel, Matija Stupar, Maddalena Pedio, Petra Rudolf, Barbara Brena, Carla Puglia, 2017, izvirni znanstveni članek Ključne besede: Cobalt Phtalocyanine, photoemission spectroscopy, gas phase, solid state
Objavljeno v RUNG: 07.02.2018; Ogledov: 4268; Prenosov: 0
Gradivo ima več datotek! Več... |
55. New strategy for magnetic gas sensingRoberta Ciprian, Piero Torelli, Angelo Giglia, B Gobaut, Barbara Ressel, Janez Štupar, Matija Stupar, Antonio Caretta, Giovanni De Ninno, Tommaso Pincelli, Barbara Casarin, Ganesh Adhikari, G Sberviglieri, C Baratto, Marco Malvestuto, 2016, izvirni znanstveni članek Ključne besede: hybrid nanostructures, sensor, absorption spectroscopy
Objavljeno v RUNG: 05.02.2018; Ogledov: 4012; Prenosov: 0
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57. Design of a highly photocatalytically active ZnO/CuWO4 nanocompositeSaim Emin, Matjaž Valant, 2017, objavljeni povzetek znanstvenega prispevka na konferenci (vabljeno predavanje) Opis: We report the synthesis, photocatalytic activity and mechanistic study of a novel heterostructure (HTS) with an efficient charge separation. A ZnO/CuWO4 HTS material is reported for the first time. The nanocomposite (NC) consists of CuWO4 nanoparticles (ca. 200-400 nm) decorated with ZnO nanorods (ca. 30 nm, 100 nm length) and is shown to be a highly active photocatalyst for decomposition of model contaminants including methyl orange and terephthalic acid. The ZnO/CuWO4 interface is shown to be the key for controlling the enhanced activity of the composite material. Transient absorption spectroscopy studies demonstrated that a photoinduced charge transfer across the ZnO/CuWO4 interface increased electron-hole lifetime by 3 orders of magnitude, from < 20 s in ZnO to 30 ms in the ZnO/CuWO4 NC sample. Our findings show that through interface design efficient HTS materials can be prepared for a wide range of photocatalytic applications.
Ključne besede: CuWO4, nanocomposite, transient absorption spectroscopy
Objavljeno v RUNG: 28.08.2017; Ogledov: 5083; Prenosov: 0
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58. Atomic-level mechanisms of magnesium oxidationSandra Gardonio, Mattia Fanetti, Matjaž Valant, Dmytro Orlov, 2016, objavljeni znanstveni prispevek na konferenci Opis: Magnesium has been recently becoming an increasingly popular material for various applications. However, excessive chemical reactivity, and oxidation rate in particular, is a major obstruction on the way of Mg to become widely adopted. A significant problem causing the lack of Mg reactivity control is insufficient understanding of mechanisms involved in the oxidation of magnesium surface. Herewith we present the investigation of atomic-level mechanisms of oxidation initiation and propagation in pure Mg. Namely, X-ray photoelectron spectroscopy at synchrotron Elettra was used as a surface sensitive direct method to determine the valence of Mg and O and the valence band states at the early stage of oxide formation over a principal, most densely packed, crystallographic plane (0001) in pure Mg. The mechanisms of oxygen adsorption on magnesium free surface followed by oxidation (i.e. initiation and kinetics of MgO formation) are clarified. Copyright © 2016 by The Minerals, Metals & Materials Society. All rights reserved.
Ključne besede: Magnesium, Oxidation, Synchrotron radiation, X-ray photoelectron spectroscopy
Objavljeno v RUNG: 25.08.2017; Ogledov: 5067; Prenosov: 0
Gradivo ima več datotek! Več... |
59. Extraction of Organochlorine Pesticides from Plastic Pellets and Plastic Type AnalysisMaryline Pflieger, Petra Makorič, Manca Kovač Viršek, Špela Koren, 2017, pregledni znanstveni članek Opis: Plastic resin pellets, categorized as microplastics (≤5 mm in diameter), are small granules that can be unintentionally released to the
environment during manufacturing and transport. Because of their environmental persistence, they are widely distributed in the oceans and
on beaches all over the world. They can act as a vector of potentially toxic organic compounds (e.g., polychlorinated biphenyls) and might
consequently negatively affect marine organisms. Their possible impacts along the food chain are not yet well understood. In order to assess the
hazards associated with the occurrence of plastic pellets in the marine environment, it is necessary to develop methodologies that allow for rapid
determination of associated organic contaminant levels. The present protocol describes the different steps required for sampling resin pellets,
analyzing adsorbed organochlorine pesticides (OCPs) and identifying the plastic type. The focus is on the extraction of OCPs from plastic pellets
by means of a pressurized fluid extractor (PFE) and on the polymer chemical analysis applying Fourier Transform-InfraRed (FT-IR) spectroscopy.
The developed methodology focuses on 11 OCPs and related compounds, including dichlorodiphenyltrichloroethane (DDT) and its two main
metabolites, lindane and two production isomers, as well as the two biologically active isomers of technical endosulfan. This protocol constitutes
a simple and rapid alternative to existing methodology for evaluating the concentration of organic contaminants adsorbed on plastic pieces.
Ključne besede: Environmental Sciences, Issue 125, Microplastics, resin pellets, pesticides, persistent organic pollutants, organochlorine pesticides, dichlorodiphenyltrichloroethane, endosulfan, hexachlorocyclohexane, lindane, Fourier transform infrared spectroscopy, pressurized fluid extractor
Objavljeno v RUNG: 10.07.2017; Ogledov: 4474; Prenosov: 0 |
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