Repozitorij Univerze v Novi Gorici

Izpis gradiva
A+ | A- | Pomoč | SLO | ENG

Naslov:Study of Li-S batteries by S K-edge RIXS spectroscopy
Avtorji:ID Kavčič, Matjaž (Lastnik avtorskih pravic)
ID Kavčič, Matjaž, Institut Jožef Stefan Ljubljana (Avtor)
ID Žitnik, Matjaž, Institut Jožef Stefan Ljubljana (Avtor)
ID Bučar, Klemen, Institut Jožef Stefan Ljubljana (Avtor)
ID Petrič, Marko, Institut Jožef Stefan Ljubljana (Avtor)
ID Arčon, Iztok, Univerza v Novi Gorici (Avtor)
ID Dominko, Robert, Kemijski inštitut, Ljubljana (Avtor)
ID Vižintin, Alen, Kemijski inštitut, Ljubljana (Avtor)
Datoteke: Gradivo nima datotek, ki so prostodostopne za javnost. Gradivo je morda fizično dosegljivo v knjižnici fakultete, zalogo lahko preverite v COBISS-u. Povezava se odpre v novem oknu
Jezik:Angleški jezik
Vrsta gradiva:Delo ni kategorizirano
Tipologija:1.12 - Objavljeni povzetek znanstvenega prispevka na konferenci
Organizacija:UNG - Univerza v Novi Gorici
Opis:Li-S batteries are considered as one of the most promising candidates for future batteries in applications where high energy density is required [1]. Despite that the general principle of operation is known for a long time [2], the lack of detailed understanding of relevant operation mechanisms has so far prevented their extensive use. A Li-S battery is composed of a lithium metal anode and a sulfur based cathode, separated by a porous separator wetted with electrolyte. During the battery cycle the reduction and oxidation of S to Li2S and back proceeds through a complicated equilibrium mixture of compounds that are typically dissolved in the electrolyte in the form of long and short chain polysulfides. In order to improve our understanding of polysulfide formation and its interactions within electrode, which are essential to achieve the long term cycling stability, development and application of new analytical tools is required. In this work sulfur K-edge resonant X-ray emission (RXES) measurements were performed on the Li-S battery in operando mode. The experiment was performed at the ID26 beamline at ESRF using the Johansson type tender x-ray emission spectrometer [3]. Full K-L RIXS maps were recorded on a set of chemically prepared Li2Sx sample standards characterized by different Li:S stoichiometric ratio, followed by the operando measurements on Li-S battery. Using the spectra recorded on Li2Sx standards two excitation energies were chosen and RXES spectra from the back of the battery cathode were sequentially acquired during one discharge cycle (C20). The relative amounts of each sulfur compound in the cathode during the discharge cycle were determined from the linear combination fit using measured reference standard spectra. Because of resonant excitation conditions the sensitivity for the polysulfide detection was significantly enhanced. Our work sets up S K-edge RIXS spectroscopy as an important analytical tool to study the mechanism of Li-polysulfide formation in the cathode and their interaction with the host matrix and electrolyte.
Ključne besede:RIXS, RXES, Li-S battery, operando, Sulphur K-edge XANES, Lithium polysulphides, Li2S
Status publikacije:Objavljeno
Leto izida:2016
Št. strani:1
PID:20.500.12556/RUNG-2469 Novo okno
COBISS.SI-ID:4416763 Novo okno
NUK URN:URN:SI:UNG:REP:TDJBW6AF
Datum objave v RUNG:28.06.2016
Število ogledov:5628
Število prenosov:0
Metapodatki:XML RDF-CHPDL DC-XML DC-RDF
:
Kopiraj citat
  
Skupna ocena:(0 glasov)
Vaša ocena:Ocenjevanje je dovoljeno samo prijavljenim uporabnikom.
Objavi na:Bookmark and Share


Postavite miškin kazalec na naslov za izpis povzetka. Klik na naslov izpiše podrobnosti ali sproži prenos.

Gradivo je del monografije

Naslov:EXRS2016 European Conference on X-ray Spectrometry : Book of abstracts
Uredniki:Johan Boman
Kraj izida:Gothenburg, Sweden
Založnik:University of Gothenborg
Leto izida:2016
Prireditelj konference:University of Gothenburg, Sweden

Nazaj