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Title:Operando characterization of batteries using x-ray absorption spectroscopy: advances at the beamline XAFS at synchrotron Elettra
Authors:Aquilanti, Giuliana (Author)
Giorgetti, marco (Author)
Dominko, Robert (Author)
Stievano, Lorenzo (Author)
Arčon, Iztok (Author)
Novello, Nicola (Author)
Ivanc Olivieri, Luca (Author)
Files:This document has no files. This document may have a phisical copy in the library of the organization, check the status via COBISS. Link is opened in a new window
Work type:Not categorized (r6)
Tipology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:X-ray absorption spectroscopy is a synchrotron radiation based technique that is able to provide information on both local structure and electronic properties in a chemically selective manner. It can be used to characterize the dynamic processes that govern the electrochemical energy storage in batteries, and to shed light on the redox chemistry and changes in structure during galvanostatic cycling to design cathode materials with improved properties. Operando XAS studies have been performed at beamline XAFS at Elettra on different systems. For Li-ion batteries, a multiedge approach revealed the role of the different cathode components during the charge and discharge of the battery. In addition, Li-S batteries for automotive applications were studied. Operando sulfur K-edge XANES and EXAFS analysis was used to characterize the redox chemistry of sulfur, and to relate the electrochemical mechanism to its local structure.
Keywords:operando studies, x-ray absorption spectroscopy, Li-ion batteries, Li-S batteries
Year of publishing:2017
Number of pages:12
COBISS_ID:4706299 Link is opened in a new window
DOI:doi:10.1088/1361-6463/aa519a Link is opened in a new window
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Record is a part of a journal

Title:Journal of Physics D: Applied Physics
Shortened title:J. Phys. D: Appl. Phys.
Publisher:IOP Publishing: Hybrid Open Access
Year of publishing:2017