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Title:Chemical Instability of an Interface between Silver and Bi2Se3 Topological Insulator at Room Temperature
Authors:ID Ferfolja, Katja, Materials Research Laboratory, University of Nova Gorica (Author)
ID Valant, Matjaž, Materials Research Laboratory, University of Nova Gorica, Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China (Author)
ID Mikulska, Iuliia, Diamond Light Source Ltd., Harwell Science and Innovation Campus (Author)
ID Gardonio, Sandra, Materials Research Laboratory, University of Nova Gorica (Author)
ID Fanetti, Mattia, Materials Research Laboratory, University of Nova Gorica (Author)
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Language:English
Work type:Not categorized
Typology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:Understanding an interaction at an interface between a topological insulator and a metal is of critical importance when designing electronic and spintronic devices or when such systems are used in catalysis. In this paper, we report on a chemical instability of the interface between Bi2Se3 and Ag studied by X-ray powder diffraction and electron microscopy. We present strong experimental evidence of a redox solid-state reaction occurring at the interface with kinetics that is significant already at room temperature. The reaction yields Ag2Se, AgBiSe2, and Bi. The unexpected room-temperature chemical instability of the interface should be considered for all future theoretical and applicative studies involving the interface between Bi2Se3 and Ag.
Keywords:topological insulators, Ag, thin metal films, interfaces, redox reaction
Year of publishing:2018
Number of pages:9980-9984
Numbering:122
PID:20.500.12556/RUNG-5565-77f7e224-58ac-e1ce-a83e-27b365f6f792 New window
COBISS.SI-ID:5205243 New window
DOI:10.1021/acs.jpcc.8b01543 New window
NUK URN:URN:SI:UNG:REP:MCWSSWH4
Publication date in RUNG:17.06.2020
Views:2882
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Record is a part of a journal

Title:The Journal of Physical Chemistry C
Shortened title:J. Phys. Chem. C
Year of publishing:2018

Licences

License:CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.
Licensing start date:15.06.2020

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